ZIF-67 blended PVDF membrane for improved Congo red removal and antifouling properties: A correlation establishment between morphological features and ultra-filtration parameters.

Dye effluents from various sectors have constantly imperilled the environment and ecosystem. Nano-composite membrane technology incorporating metal-organic frameworks (MOFs) has shown tremendous potential for toxic pollutant remediation. This study details the impact of ZIF-67 MOF nanoparticles on the structural properties of polyvinylidene fluoride (PVDF) ultrafiltration membrane during the non-solvent induced phase separation (NIPS) process. In order to outline the properties that determine the performance parameters in a MOF-modified mixed matrix membrane, the corresponding changes in mean pore size (MPS), surface porosity, solvent viscosity, and hydrophilicity have been discussed with appropriate surface characterization analysis. The suitability of ZIF-67 as filler nanoparticles were established based on polymer compatibility, dispersibility, and water stability studies. The ZIF-67 incorporated PVDF mixed matrix membranes (MMM) showed 99.5% CR dye removal with 2.6 times DI water permeability than the neat. The flux recovery ratio (FRR) improved by 1.9 times and the membranes were found suitable for up to 5 filtration cycles. Based on the overall results, a correlation analysis between the MMM surface properties and membrane performance parameters were established to determine the key performance parameters. It was observed that in comparison to MPS, surface porosity was more correlated to Jd/Jw (r = 0.96) and FRR (r = 0.95).

Facile monomer interlayered MOF based thin film nanocomposite for efficient arsenic separation.

The thin film nanocomposites (TFN) based membranes are sensitive to the synergy between the polymer and nanoparticles. TFN incorporating metal-organic frameworks (MOFs) have shown tremendous enhancement in permeability. This study investigates alternate MOF positioning during TFC fabrication for a highly selective membrane. Co-Zn-based mixed metal-organic framework (mMOF) was interlayered between m-phenylenediamine (MPD) and trimesoyl chloride (TMC) to form a polyamide (PA) selective layer. The practiced method conveniently allowed exact loading of mMOF and thus prevented the loss. Owing to the mMOF's placement between MPD and TMC, an increase in PA cross-linking was observed. The mMOF-MPD monomer compatibility allowed homogeneous distribution and formation of a defect-free PA layer. The surface morphology showed a more pronounced formation of leaves-like features due to interfacial degassing. Neutral solute-based filtration tests determined mean pore size, probability distribution, and MWCO. The incorporation of mMOF led to formation of additional nanochannels in the membrane surface. The perm-selectivity studies performed on a dead-end filtration unit resulted in 94% As5+ retention with 2.5 times higher permeance than the control. The current study pronounced the viability of the monomer interlayer method to form a highly selective TFN for water separation and related applications.

Forward Osmosis in Wastewater Treatment Processes.

In recent years, membrane technology has been widely used in wastewater treatment and water purification. Membrane technology is simple to operate and produces very high quality water for human consumption and industrial purposes. One of the promising technologies for water and wastewater treatment is the application of forward osmosis. Essentially, forward osmosis is a process in which water is driven through a semipermeable membrane from a feed solution to a draw solution due to the osmotic pressure gradient across the membrane. The immediate advantage over existing pressure driven membrane technologies is that the forward osmosis process per se eliminates the need for operation with high hydraulic pressure and forward osmosis has low fouling tendency. Hence, it provides an opportunity for saving energy and membrane replacement cost. However, there are many limitations that still need to be addressed. Here we briefly review some of the applications within water purification and new developments in forward osmosis membrane fabrication.

High strength distillery wastewater treatment by a PAC-MBR with low PAC dosage.

Augmentation of membrane bioreactors (MBRs) with activated carbon is established to offer several operational advantages. This work investigates the influence of low dosing (2 g/L) of powdered activated carbons (PACs) with different characteristics on the performance of MBR treating high strength molasses distillery wastewater containing difficult-to-biodegrade recalcitrant components. Two MBRs, augmented with different PACs, were operated in parallel over a period of 240 days and their performance monitored in terms of biomass growth, reduction in chemical oxygen demand (COD), sludge properties like extracellular polymeric substances content, filterability, and morphology. Removal of organics and coloring matter by adsorption, biodegradation and membrane filtration was estimated. Although adsorptive removal of color and COD is influenced by the properties of the PAC used, the performance of the PAC-MBRs was independent of PAC properties. Both PACs preferentially adsorbed the low molecular weight components in distillery wastewater. Retention by the membrane filter with the secondary cake layer contributed to reduction in color and COD of treated effluent. The findings indicate that low dosing with PAC adsorbing low molecular weight organics has a limited role in PAC-MBR treating distillery wastewater.

Covalently Immobilized Laccase for Decolourization of Glucose-Glycine Maillard Products as Colourant of Distillery Wastewater.

Maillard reaction products like melanoidins are recalcitrant, high-molecular-weight compounds responsible for colour in sugarcane molasses distillery wastewater. Conventional biological treatment is unable to break down melanoidins, but extracellular laccase and manganese peroxidase of microbial origin can degrade these complex molecules. In this work, laccase was covalently immobilized on alumina pellets activated with aminopropyltriethoxysilane (APTES). The immobilization yield was 50-60 %, and the enzyme activity (886 U/L) was 5-fold higher compared to the soluble enzyme (176 U/L). The immobilized enzyme also showed higher tolerance to pH (4-6) and temperature (35-60 °C), as well as improved storage stability (49 days) and operational stability (10 cycles). Degradation of glucose-glycine Maillard products using immobilized laccase led to 47 % decolourization in 6 h at pH 4.5 and 28 °C. A comprehensive treatment scheme integrating enzymatic, microbial and membrane filtration steps resulted in 90 % decolourization.

Integrated treatment of molasses distillery wastewater using microfiltration (MF).

To achieve zero-liquid discharge, high pressure reverse osmosis (RO) of effluent is being employed by molasses based alcohol distilleries. Low pressure and thus less energy intensive microfiltration (MF) is well established for particulate separation but is not suitable for removal of dissolved organics and color. This work investigates two schemes incorporating MF for molasses distillery wastewater (a) chemical coagulation followed by treatment in a membrane bioreactor (MBR) using MF and (b) electrocoagulation followed by MF. The performance was assessed in terms of COD and color reduction; the conversion of the generated sludge into a zeolite desiccant was also examined. A comparison of the schemes indicates electrocoagulation followed by MF through a 0.1 µm membrane to be most effective. By hydrothermal treatment, electrocoagulated sludge can be transformed into a porous NaX zeolite with a surface area of 86 m(2)/g, which is comparable to commercial desiccants.

Treatment of nitrate-rich water in a baffled membrane bioreactor (BMBR) employing waste derived materials.

Nitrate removal in submerged membrane bioreactors (MBRs) is limited as intensive aeration (for maintaining adequate dissolved oxygen levels and for membrane scouring) deters the formation of anoxic zones essential for biological denitrification. The present study employs baffled membrane bioreactor (BMBR) to overcome this constraint. Treatment of nitrate rich water (synthetic and real groundwater) was investigated. Sludge separation was achieved using ceramic membrane filters prepared from waste sugarcane bagasse ash. A complex external carbon source (leachate from anaerobic digestion of food waste) was used to maintain an appropriate C/N ratio. Over 90% COD and 95% NO3-N reduction was obtained. The bagasse ash filters produced a clear permeate, free of suspended solids. Sludge aggregates were observed in the reactor and were linked to the high extracellular polymeric substances (EPS) content. Lower sludge volume index (40 mL/g compared to 150 mL/g for seed sludge), higher settling velocity (47 m/h compared to 10 m/h for seed sludge) and sludge aggregates (0.7 mm aggregates compared to <0.2 mm for seed sludge) was observed. The results demonstrate the potential of waste-derived materials viz. food waste leachate and bagasse ash filters in water treatment.

Prolong Restoration of the Water Quality of River Ganga Effect of Heavy Metals and Radioactive Elements.

The genesis of the present research was the belief since ages and the observations made through some studies that the water of river Ganga has unique characteristics, which allows storage of water quality even on prolong storage. Very few systematic studies have been conducted to support the contention that the Ganga water indeed has some special composition that could be attributed to its unique storage capacity. It was postulated that prolong restoration of water quality depends on the ability to arrest microbial activity that is generally responsible for deterioration in water quality on prolong storage. Hence, attempt has been made to identify the parameters that are likely to influence the prolong storage of river water. Along with Ganga river water, other three major rivers, viz. Yamuna, Godavari and Narmada, were selected for comparison. Emphasis was made on estimation of heavy metals, radioactive elements, dissolved carbon and other physicochemical parameters such as temperature, pH, alkalinity, hardness and dissolved organic carbon. Based on the available information regarding the impact of heavy metals, radioactive elements vis-à-vis the chemical composition of water on microorganisms in the aquatic environment, an overall impact score for the waters of the four Indian rivers selected in the study has been assigned.

Membrane-based technologies for biogas separations.

Over the past two decades, membrane processes have gained a lot of attention for the separation of gases. They have been found to be very suitable for wide scale applications owing to their reasonable cost, good selectivity and easily engineered modules. This critical review primarily focuses on the various aspects of membrane processes related to the separation of biogas, more in specific CO(2) and H(2)S removal from CH(4) and H(2) streams. Considering the limitations of inorganic materials for membranes, the present review will only focus on work done with polymeric materials. An overview on the performance of commercial membranes and lab-made membranes highlighting the problems associated with their applications will be given first. The development studies carried out to enhance the performance of membranes for gas separation will be discussed in the subsequent section. This review has been broadly divided into three sections (i) performance of commercial polymeric membranes (ii) performance of lab-made polymeric membranes and (iii) performance of mixed matrix membranes (MMMs) for gas separations. It will include structural modifications at polymer level, polymer blending, as well as synthesis of mixed matrix membranes, for which addition of silane-coupling agents and selection of suitable fillers will receive special attention. Apart from an overview of the different membrane materials, the study will also highlight the effects of different operating conditions that eventually decide the performance and longevity of membrane applications in gas separations. The discussion will be largely restricted to the studies carried out on polyimide (PI), cellulose acetate (CA), polysulfone (PSf) and polydimethyl siloxane (PDMS) membranes, as these membrane materials have been most widely used for commercial applications. Finally, the most important strategies that would ensure new commercial applications will be discussed (156 references).