ABSTRACT
Mg and its alloys evince strong candidature for biodegradable bone implants, cardiovascular stents, and wound closing devices. However, their rapid degradation rate causes premature implant failure, constraining clinical applications. Bio-functional surface coatings have emerged as the most competent strategy to fulfill the diverse clinical requirements, besides yielding effective corrosion resistance. This article reviews the progress of biodegradable and advanced surface coatings on Mg alloys investigated in recent years, aiming to build up a comprehensive knowledge framework of coating techniques, processing parameters, performance measures in terms of corrosion resistance, adhesion strength, and biocompatibility. Recently developed conversion and deposition type surface coatings are thoroughly discussed by reporting their essential therapeutic responses like osteogenesis, angiogenesis, cytocompatibility, hemocompatibility, anti-bacterial, and controlled drug release towards in-vitro and in-vivo study models. The challenges associated with metallic, ceramic and polymeric coatings along with merits and demerits of various coatings have been illustrated. The use of multilayered hybrid coating comprising a unique combination of organic and inorganic components has been emphasized with future perspectives to obtain diverse bio-functionalities in a facile single coating system for orthopedic implant applications.
ABSTRACT
Synthesis of a novel electrocatalyst for hydrogen evolution reaction (HER) is highly demanding for renewable energy production. This research reports the design and development of novel palladium based metallosurfactant (PdCPC(I)) that belongs to the unique class of inorganic-organic hybrid with striking structural features that are explored for the first time in the HER. The formation of the micelle, molecular orientation and surface characteristics of the metallosurfactant are calculated by conductivity and contact angle measurements. The reduction of palladium in metallomicelles during electrolysis accelerates the HER. Metallosurfactant makes the substrate hydrophilic, which in turn enhances the activity of the modified substrate. The 269 mV and 400 mV (vs RHE) overpotential is required to achieve the 10 mA cm-2 of current density for PdCPC(I) and CPC, respectively. Tafel slope of PdCPC(I) is 57 mV dec-1, which signifies that the reaction follows the Volmer- Heyrovsky mechanism in the presence of catalyst. The presence of the palladium in the core of the micelle is certified by ICPMS study. The present electrocatalyst also demonstrates 40 h of electrochemical durability. This work opens the doors toward the enhancement of HER, which fulfills the dreams for future energy resources.
ABSTRACT
The implementation of hydrogen evolution reaction (HER) is an essential requirement of a stable electrocatalyst that competes for the performance of noble metals (Pt, Pd), especially in acidic conditions. This research reports the design and development of affordable cobalt (Co) based metallosurfactant (CoCPC(I)) which performs under acidic medium (0.5 N H2SO4) for HER. Such a fabricated catalyst is able to lower the cathodic potentials efficiently and exhibits 130 mV onset potential and Tafel slope of 104 mVdec-1 that depicts the presence of Volmer-Heyrovsky mechanism. The results of the studies confirm that our synthesized metallosurfactant forms metallomicelles on the surface of electrode and surface remains stable even after the electrochemical cycle. Further, the surfactant protects the metal centre as an active site for a longer time via forming metallo-micelles which helps to sustain activity. These outcomes reveal the efficient mass and charge transfer capability of CoCPC(I) which results in faster charge transfer kinetics. Therefore, the utilization of Co based metallosurfactant can split water easily, cost-effectively, and without using hazardous chemicals. Our demonstrated technology seems suitable for industrial applications due to features of large-scale production possibilities.
