ABSTRACT
Activated carbon (AC) made of single-substrate agricultural wastes is considered to be a suitable raw material for the production of low-cost adsorbents; however, the large-scale application of these materials is highly limited by their low efficiency, seasonal scarcity, poor stability, low surface area, and limited CO2 adsorption performance. In this study, composite activated carbon (CAC) was prepared via controlled carbonization followed by chemical activation of four wastes (i.e., peanut shell, coffee husk, corn cob, and banana peel) at an appropriate weight ratio. The Na2CO3-activated CAC showed a higher surface area and valuable textural properties for CO2 adsorption as compared with KOH- and NaOH-activated CAC. The CAC production parameters, including impregnation ratio, impregnation time, carbonization temperature, and time, were optimized in detail. The as-prepared CACs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Raman spectroscopy, N2 adsorption-desorption isotherm, and iodine number analysis. The CAC produced at optimal conditions exhibited the highest CO2 removal efficiency and adsorption capacity of 96.2% and 8.86 wt %, respectively, compared with the single-biomass-derived activated carbon. The enhanced CO2 adsorption performance is due to the large surface area, a considerable extent of mesopores, and suitable pore width. The adsorbent in this study reveals a promising strategy for mitigating the CO2 emission problems instead of more expensive and ineffective materials.
ABSTRACT
BACKGROUND: The existence of heavy metals and coliform bacteria contaminants in aquatic system of Akaki river basin, a sub city of Addis Ababa, Ethiopia has become a public concern as human population increases and land development continues. Hence, it is the right time to design treatment technologies that can handle multiple pollutants. RESULTS: In this study, we prepared a synthetic zeolites and copper doped zeolite composite adsorbents as cost effective and simple approach to simultaneously remove heavy metals and total coliforms from wastewater of Akaki river. The synthesized copper-zeolite X composite was obtained by ion exchange method of copper ions into zeolites frameworks. Iodine test, XRD, FTIR and autosorb IQ automated gas sorption analyzer were used to characterize the adsorbents. The mean concentrations of Cd, Cr, and Pb in untreated sample were 0.795, 0.654 and 0.7025 mg/L respectively. These concentrations decreased to Cd (0.005 mg/L), Cr (0.052 mg/L) and Pb (bellow detection limit, BDL) for sample treated with bare zeolite X while a further decrease in concentration of Cd (0.005 mg/L), Cr (BDL) and Pb (BDL) was observed for the sample treated with copper-zeolite composite. Zeolite X and copper-modified zeolite X showed complete elimination of total coliforms after 90 and 50 min contact time respectively. CONCLUSION: The results obtained in this study showed high antimicrobial disinfection and heavy metal removal efficiencies of the synthesized adsorbents. Furthermore, these sorbents are efficient in significantly reducing physical parameters such as electrical conductivity, turbidity, BOD and COD.
