1.
RSC Adv
; 12(53): 34496-34502, 2022 Nov 29.
Article
in English
| MEDLINE
| ID: mdl-36545628
ABSTRACT
We report herein the synthesis of primary and secondary ß-chalcogen amines through the regioselective ring-opening reaction of non-activated 2-oxazolidinones promoted by in situ generated chalcogenolate anions. The developed one-step protocol enabled the preparation of ß-selenoamines, ß-telluroamines and ß-thioamines with appreciable structural diversity and in yields of up to 95%.