ABSTRACT
A super activated carbon (SAC) was produced by KOH-activation of a biomass waste for paracetamol (PCT) adsorption from aqueous solution and for adsorption-thermal regeneration cycles. The SAC and the regenerated SAC after five adsorption-regeneration cycles (RSAC-5th) were fully characterized by several techniques. The N2 physisorption showed that the SBET values of the SAC and RSAC-5th are remarkably different, being 2794 m² g-1 and 889 m² g-1, respectively. The XPS analysis demonstrated that the SAC surface is composed by oxygen containing-groups, whilst the RSAC-5th also presents nitrogen ones, provenient from the PCT molecules. The adsorption studies revealed that the maximum adsorption capacity (Qm) for the SAC (356.22 mg g-1) is higher than that for RSAC-5th (113.69 mg g-1). Also, the results demonstrated that the PCT adsorption is governed by both physisorption and chemisorption and the ab initio calculations showed the chemisorption mainly occurs in carboxylic groups.
Subject(s)
Acetaminophen/chemistry , Analgesics, Non-Narcotic/chemistry , Biomass , Carbon/chemistry , Hydroxides/chemistry , Potassium Compounds/chemistry , Adsorption , KineticsABSTRACT
The present work reports the preparation of CO2-activated carbon (AC) using Stevia rebaudiana (Bertoni) residue as a new carbon precursor. The experimental parameters were optimized via chemometrics tools to obtain an AC with high BET surface area (SBET). The found optimum condition was: activation temperature of 900⯰C, CO2 flow of 165â¯cm3 g-1 and activation time of 60â¯min, providing an ACop with SBET of 874â¯m2 g-1. The ACop was characterized from several analytical techniques, which showed that it has heterogeneous morphology features and different surface chemical groups, predominating the acidic character. The adsorption performance of ACop for triclosan (TCS) removal from solution was investigated by kinetic, equilibrium and thermodynamic studies. The results showed that TCS adsorption process onto ACop is spontaneous and endothermic, wherein the mechanism occurs by different steps, which equally play important roles. Additionally, the monolayer adsorption capacity (Qm) was found to be 117.00â¯mgâ¯g-1.
Subject(s)
Carbon Dioxide/chemistry , Charcoal/chemistry , Stevia/chemistry , Triclosan/chemistry , Adsorption , Carbon/chemistry , Diterpenes, Kaurane , Glucosides , Hydrogen-Ion Concentration , Kinetics , Surface Properties , Temperature , ThermodynamicsABSTRACT
The present work reports the development and application of bismuth-film electrode (BiFE), obtained by in situ method on the pencil-lead graphite surface, for simultaneous Cd(II) and Pb(II) determination at trace levels, as alternative to replace the mercury-film electrodes. Experimental factors, deposition time (t d ), deposition potential (E d ), and Bi(III) concentration (C Bi ), were investigated by applying a 23 factorial design using 0.10 mol/L acetate buffer solution (pH 4.5) as supporting electrolyte. The analysis conditions of the differential pulse technique were t d = 250 s, E d = -1.40 V, and C Bi = 250 mg L-1. The validation of the method employing BiFE was accomplished by determination of merit figures. The detection limits were of 11.0 µg L-1 for Cd(II) and 11.5 µg L-1 for Pb(II), confirming that proposed method is attractive and suitable for heavy metals determination. Additionally, the BiFE developed was successfully applied for the Cd(II) and Pb(II) determination in wastewater sample of battery industry.
