Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management.

Organic phosphoester (OPE) antioxidants are currently required due to their contribution to enhancing the quality of polymers, including polypropylene (PP). In this research, an integral methodology is presented for the efficient extraction of bis(2,4-dicumylphenyl) pentaerythritol diphosphite from industrial wastewater. Upon employing the solid-phase extraction (SPE) technique, the recovered compound is subjected to a comprehensive analysis of the recovered compound using high-performance liquid chromatography (HPLC), mass spectrometry (MS), thermal analysis (TGA), Fourier transforms infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC). Subsequently, purified Bis(2,4-dicumylphenyl) pentaerythritol diphosphite was evaluated as a thermo-oxidative stabilizer after incorporation into PP resins. The relative standard deviation (RSD), Error (Er), linearity (R2), and percentage (%) recovery were less than 2.6, 2.5, more significant than 0.9995, and greater than 96%, respectively, for the inter-day and intra-day tests of the chromatographic method and the SPE. Except for chloroform, which was necessary due to the solubility properties of the investigated analyte, the use of environmentally friendly solvents, such as methanol and acetonitrile, was considered during the development of this research. The OPE extracted from industrial wastewater was characterized by FTIR, UV-Vis, DSC, TGA, and MS, allowing the elucidation of the structure of Bis(2,4-dicumylphenyl) pentaerythritol diphosphite (BDPD). The recovered OPE was mixed with PP resins, allowing it to improve its thermal properties and minimize its thermo-oxidative degradation. Organophosphorus flame retardant (OPE)' concentration in wastewater is alarming, ranging from 1179.0 to 4709.6 mg L-1. These exceed toxicity thresholds for aquatic organisms, emphasizing global environmental risks. Using a validated solid-phase extraction (SPE) technique with over 94% recovery, the study addresses concerns by removing organic contaminants and supporting circular economy principles. The high economic and environmental significance of recovering BDPD underscores the need for urgent global attention and intervention.

High-energy picosecond pulses with a single spatial mode from a passively mode-locked, broad-area semiconductor laser.

We present a mode-locked semiconductor laser oscillator that emits few picosecond pulses (5-8ps at a repetition rate of 379MHz and wavelength of 1064nm) with record peak power (112W) and pulse energy (0.5nJ) directly out of the oscillator (with no amplifier). To achieve this high power performance we employ a high-current broad-area, spatially multi-mode diode amplifier (0.3×5mm), placed in an external cavity that enforces oscillation in a single spatial mode. Consequently, the brightness of the beam is near-ideal (M2 = 1.3). Mode locking is achieved by dividing the large diode chip (edge emitter) into two sections with independent electrical control: one large section for gain and another small section for a saturable absorber. Precise tuning of the reverse voltage on the absorber section allows to tune the saturation level and recovery time of the absorber, providing a convenient knob to optimize the mode-locking performance for various cavity conditions.

Passive symmetry breaking of the space-time propagation in cavity dissipative solitons.

Dissipative solitons are fundamental wave-pulses that preserve their form in the presence of periodic loss and gain. The canonical realization of dissipative solitons is Kerr-lens mode locking in lasers, which delicately balance nonlinear and linear propagation in both time and space to generate ultrashort optical pulses. This linear-nonlinear balance dictates a unique pulse energy, which cannot be increased (say by elevated pumping), indicating that excess energy is expected to be radiated in the form of dispersive or diffractive waves. Here we show that Kerr-lens mode-locked lasers can overcome this expectation. Specifically, by breaking the spatial symmetry between the forward and backward halves of the round-trip in a linear cavity, the laser can modify the soliton in space to incorporate the excess energy. Increasing the pump power leads therefore to a different soliton solution, rather than to dispersive/diffractive loss. We predict this symmetry breaking by a complete numerical simulation of the spatio-temporal dynamics in the cavity, and confirm it experimentally in a Kerr-lens mode-locked Ti:Sapphire laser with quantitative agreement to the simulation. The simulation opens a window to directly observe the nonlinear space-time dynamics that molds the soliton pulse, and possibly to optimize it.

Augmenting the Sensing Performance of Entangled Photon Pairs through Asymmetry.

We analyze theoretically and experimentally cases of asymmetric detection, stimulation, and loss within a quantum nonlinear interferometer of entangled pairs. We show that the visibility of the SU(1,1) interference directly discerns between loss on the measured mode (signal) and the conjugated mode (idler). This asymmetry also affects the phase sensitivity of the interferometer, where coherent seeding is shown to mitigate losses that are suffered by the conjugated mode; therefore increasing the maximum threshold of loss that permits sub-shot-noise phase detection. Our findings can improve the performance of setups that rely on direct detection of entangled pairs, such as quantum interferometry and imaging with undetected photons.

Diffractive saturable loss mechanism in Kerr-lens mode-locked lasers: direct observation and simulation.

Passive mode-locking relies critically on a saturable loss mechanism to form ultrashort pulses. However, in Kerr-lens mode-locking (KLM), no actual absorption takes place, but rather losses appear due to diffraction, and actual light must escape the cavity. The Kerr-lens effect works to generate through diffraction an effective instantaneous saturable absorber that depends delicately on the interplay between the spatial and temporal profiles of the pulse. Despite the importance of KLM as a technique for generating ultrafast pulses and the fundamental role of diffraction losses in its operation, these losses have never been observed directly. Here, we measure the light that leaks out due to diffraction losses in a hard-aperture Kerr-lens mode-locked Ti:sapphire laser, and compare the measured results with a numerical theory that explicitly calculates the spatiotemporal behavior of the pulse.

Can Nonlinear Parametric Oscillators Solve Random Ising Models?

We study large networks of parametric oscillators as heuristic solvers of random Ising models. In these networks, known as coherent Ising machines, the model to be solved is encoded in the coupling between the oscillators, and a solution is offered by the steady state of the network. This approach relies on the assumption that mode competition steers the network to the ground-state solution of the Ising model. By considering a broad family of frustrated Ising models, we show that the most efficient mode does not correspond generically to the ground state of the Ising model. We infer that networks of parametric oscillators close to threshold are intrinsically not Ising solvers. Nevertheless, the network can find the correct solution if the oscillators are driven sufficiently above threshold, in a regime where nonlinearities play a predominant role. We find that for all probed instances of the model, the network converges to the ground state of the Ising model with a finite probability.

Pairwise Mode Locking in Dynamically Coupled Parametric Oscillators.

Mode locking in lasers is a collective effect, where due to a weak coupling a large number of frequency modes lock their phases to oscillate in unison, forming an ultrashort pulse in time. We demonstrate an analogous collective effect in coupled parametric oscillators, which we term "pairwise mode locking," where many pairs of modes with twin frequencies (symmetric around the center carrier) oscillate simultaneously with a locked phase sum, while the phases of individual modes remain undefined. Thus, despite being broadband and multimode, the emission is not pulsed and lacks first-order coherence, while possessing a very high degree of second-order coherence. Our configuration comprises two coupled parametric oscillators within identical multimode cavities, where the coupling between the oscillators is modulated in time at the repetition rate of the cavity modes, with some analogy to active mode locking in lasers. We demonstrate pairwise mode locking in a radio-frequency experiment, covering over an octave of bandwidth with approximately 20 resonant mode-locked pairs, filling most of the available bandwidth between dc and the pump frequency. We accompany our experiment with an analytic model that accounts for the properties of the coupled parametric oscillators near threshold.

Risk factors associated with sexually transmitted infections and HIV among adolescents in a reference clinic in Madrid.

INTRODUCTION: Adolescents have a higher incidence of sexually transmitted infections (STIs) than persons of older age groups. The WHO emphasises the need to adopt specific and comprehensive prevention programmes aimed at this age group. The objective of this work was to analyse the prevalence of HIV/STIs among adolescents and to identify the sociodemographic, clinical and behavioural markers associated with these infections, in order to promote specific preventive strategies. METHODOLOGY: Retrospective descriptive study of adolescents, aged 10-19 years, who were attended to for the first consultation between 2016 and 2018 in a reference STI clinic in Madrid. All adolescents were given a structured epidemiological questionnaire where information on sociodemographic, clinical and behavioural characteristics was collected. They were screened for human inmmunodeficiency virus (HIV) and other sexually transmitted infections (STIs). The processing and analysis of the data was done using the STATA 15.0 statistical package. RESULTS: The frequency of HIV/STIs detected among all adolescents was: gonorrhoea 21.7%, chlamydia 17.1%, syphilis 4.8% and HIV 2.4%. After conducting a multivariate analysis, the independent and statistically significant variables related to the presence of an STI were having first sexual relations at a young age and having a history of STIs. Latin American origin was just below the level of statistical significance (p = 0.066). DISCUSSION/CONCLUSIONS: Adolescents who begin sexual relations at an early age or those who have a history of HIV/STIs are at higher risk of acquiring STIs. Comprehensive prevention programmes aimed specifically at adolescents should be implemented, especially before the age of 13 years.

Persistent Coherent Beating in Coupled Parametric Oscillators.

Coupled parametric oscillators were recently employed as simulators of artificial Ising networks, with the potential to solve computationally hard minimization problems. We demonstrate a new dynamical regime within the simplest network-two coupled parametric oscillators, where the oscillators never reach a steady state, but show persistent, full-scale, coherent beats, whose frequency reflects the coupling properties and strength. We present a detailed theoretical and experimental study and show that this new dynamical regime appears over a wide range of parameters near the oscillation threshold and depends on the nature of the coupling (dissipative or energy preserving). Thus, a system of coupled parametric oscillators transcends the Ising description and manifests unique coherent dynamics, which may have important implications for coherent computation machines.

Lifting the bandwidth limit of optical homodyne measurement with broadband parametric amplification.

Homodyne measurement is a corner-stone method of quantum optics that measures the quadratures of light-the quantum optical analog of the canonical position and momentum. Standard homodyne, however, suffers from a severe bandwidth limitation: while the bandwidth of optical states can span many THz, standard homodyne is inherently limited to the electronically accessible MHz-to-GHz range, leaving a dramatic gap between relevant optical phenomena and the measurement capability. We demonstrate a fully parallel optical homodyne measurement across an arbitrary optical bandwidth, effectively lifting this bandwidth limitation completely. Using optical parametric amplification, which amplifies one quadrature while attenuating the other, we measure quadrature squeezing of 1.7 dB simultaneously across 55 THz, using the pump as the only local oscillator. As opposed to standard homodyne, our measurement is robust to detection inefficiency, and was obtained with >50% detection loss. Broadband parametric homodyne opens a wide window for parallel processing of quantum information.