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Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 9): m1165, 2012 Sep 01.
Article in English | MEDLINE | ID: mdl-22969462

ABSTRACT

In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar mol-ecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetra-coordinated, displaying a slightly distorted square-planar geometry. The main deviation from the ideal geometry is seen in the differences in the Cu-O [1.8833 (10) Å] and Cu-N [1.9405 (13) Å] bond lengths, while angular deviations are less than 3°. Intra-molecular O-H⋯O and inter-molecular Csp(2)-H⋯O hydrogen bonds form S(5) and R(2) (2)(8) ring motifs, respectively. The latter inter-action results in chains of mol-ecules along [100].

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