ABSTRACT
This work aims to removing anionic food dyes, Acid Red18 (E124) and Quinoline Yellow WS (E104), from their aqueous solutions. The Emulsion Liquid Membrane (ELM) technique was used. ELM consists of diluent (kerosene), nonionic surfactant (0.5 wt. % Triton X-45), Aliquat 336 as an extractant. Sulfuric acid (H2SO4) solution was used as an internal aqueous phase. The key parameters impacting the stability of liquid membrane and the efficiency of dye removal were investigated; Almost 98% of E124 at 50 mg/L are successfully extracted under optimum conditions. The extraction of a mixture of the two dyes at equal concentrations (25 mg/L) was conducted and their extraction showed more than 95% of efficiency. The experimental results of dye mixture (E124, E104) extraction were expressed by the following three quantities: The concentration of Triton X-45, the concentration of Aliquat 336, and the internal phase concentration of H2SO4, represented on three dimensional plots using the Box-Behnken design and the response surface methodology. For each of the parameters, the values of which were determined by experimental design, these results were subjected to empirical smoothing. The values, thus calculated, are consistent with the measurements.
Subject(s)
Coloring Agents , Research Design , Emulsions , Octoxynol , Water , Surface-Active AgentsABSTRACT
The present work deals with the extraction and pre-concentration of nickel (II) ions using emulsified liquid membrane (ELM) in the presence of di- (2-ethylhexyl) phosphoric acid (D2EHPA) as an extractant. The emulsion stability was achieved by the biodegradable surfactants Triton X-100 addition diluted in kerosene. Influence of operating conditions that affect ELM performance were investigated. A comparative study between the optimization parameters of this process was carried out both experimentally and with the Response Surface Methodology (RSM), in accordance with the Box-Behnken matrix. The following parameters were investegated: D2EHPA / Triton X-100 ratio between 0.5 and 3.5, initial concentration of the feed phase between 200 and 500â ppm and pH of the feed phase from 2.5-10. The transport of Ni (II) ions was evaluated according to the extraction yield as an analytical response and the optimal conditions were determined. It was found that the calculated values being in good agreement with experimental data that under the optimized conditions ([Ni] = 350â¯ppm, Vagitation = 200â¯rpm, t = 20â¯min and pH = 6.6), Ni (II) ions extraction was recorded more than 94% of efficiency.
Subject(s)
Research Design , Surface-Active Agents , Ions , Polyethylene GlycolsABSTRACT
In this report, indium-tin-oxide (ITO)-layer extraction from end-of-life (EOL) Liquid Crystal Displays (LCDs) was discussed by sulfuric acid leaching with simultaneous application of ultrasonication on the ITO-side of glass/ITO panels, exhibiting various dimensions. Applying this technique presents several advantages compared to the traditional leaching process such as fast and controllable kinetics, high extraction yield of indium and tin, selective recovery of these two metals possible, and the opportunity to recycle the neat glass separately avoiding additional separation processes. ITO-dissolution kinetics from EOL LCD panels were investigated as function of leaching time and acidity of sulfuric acid. At a temperature of 60°C, a nearly quantitative indium yield was obtained using an acid concentration of 18mol/L by simultaneous application of ultrasonication, whereas only 70% were recovered in the absence of ultrasound. Results from ICP-AES agreed well with SEM/BSE observations demonstrating the high efficiency of the ultrasound assisted process since only 3-4min were required to obtain maximum ITO recovery.