ABSTRACT
Ru@Pt core shell nanoparticles possess optimal catalytic properties that facilitate the anodic oxidation reaction of H2 with decreased Pt loading in hydrogen fuel cells. Moreover, since they preferentially oxidize CO, Pt poisoning is considerably reduced, which significantly improves the stability of the cell. The Ru cores used in this system are usually synthesized by dissolving a RuCl3*H2O precursor in an ethylene glycol-carbon black-NaOH mixture. However, the possibility that remnant Cl and Na from the synthesis process are present in the Ru nanoparticles has not been extensively studied. Therefore, due to the challenges in detecting impurities with traditional characterization methods, here correlative atom probe tomography (APT) with scanning transmission electron microscopy ((S)TEM) techniques were implemented. The capabilities of APT to obtain chemical information with high sensitivity at the nanoscale, in combination with the high spatial resolving power of (S)TEM, provide the necessary resolution to fully characterize the structure and chemical makeup of Ru nanoparticles.
ABSTRACT
Ru@Pt core-shell nanoparticles are currently being explored as carbon monoxide tolerant anode catalysts for proton exchange membrane fuel cells. However, little is known about their degradation under fuel cell conditions. In the present work, two types of Ru@Pt nanoparticles with nominal shell thicknesses of 1 (Ru@1Pt) and 2 (Ru@2Pt) Pt monolayers are studied as synthesized and after accelerated stress tests. These stress tests were designed to imitate the degradation occurring under fuel cell operating conditions. Our advanced (scanning) transmission electron microscopy characterization explains the superior initial electrochemical performance of Ru@1Pt. Moreover, the 3D reconstruction of the Pt shell by electron tomography reveals an incomplete shell for both samples, which results in a less stable Ru metal being exposed to an electrolyte. The degree of coverage of the Ru cores provides insights into the higher stability of Ru@2Pt during the accelerated stress tests. Our results explain how to maximize the initial performance of Ru@Pt-type catalysts, without compromising their stability under fuel cell conditions.
