Pilot-scale hybrid system combining hydrodynamic cavitation and sedimentation for the decolorization of industrial inks and printing ink wastewater.

A pilot-scale hydrodynamic cavitation (HC) system followed by sedimentation (SED) was used for the decolorization of 5 industrial-grade inks, a fluid containing a mixture of the five industrial grade inks (MIX) and printing ink wastewater (PIW). The pilot scale HC reactor combines a Venturi tube with a 31 holes orifice plate accommodated in the vena-contracta of Venturi. The study aimed to define optimal operating conditions, i.e., hydrogen peroxide concentration (H2O2), pH and combined HC/SED treatment time, to achieve decolorization and reduce HC operation time. Under the optimal conditions at the proposed HC/SED system, color removal reached 92%, 91%, 90%,98% and 90%, for black, red, yellow, cyan, and green ink respectively (at pH 8 without H2O2 addition). In the same system, color removal for PIW was 92%, whereas for MIX decolorization reached more than 90% for all the wavelengths in the selected spectrum 300-700 nm at HC/SED system (at pH 8 and 1 g L-1 hydrogen peroxide). The suspended particles were characterized by measurements of the particle size distribution and of the respective zeta potential. The equivalent cavitation yields, electric energy consumption and operating costs were calculated. The present work's results suggested that HC combined with sedimentation has a great potential for real applications and is superior compared to other technologies (i.e., H2O2 alone, sedimentation alone or even HC with or without H2O).

Treatment of real industrial-grade dye solutions and printing ink wastewater using a novel pilot-scale hydrodynamic cavitation reactor.

A novel pilot-scale hydrodynamic cavitation (HC) reactor was used to decolorize industrial-grade dye solutions and printing ink wastewater (PIW). The effect of the orifice plate geometry (1 hole plate of 1 mm and 2 mm in diameter, 31 holes of 1 mm and 2 mm in diameter, 62 holes of 1 mm and 2 mm in diameter), inlet pressure (4, 5 bar), initial dye concentration (0.3 and 0.6 OD), and the synergistic effect of HC and hydrogen peroxide concentration (0.0, 0.5, 1.0, 2.0 g/L) were investigated. The results showed that the highest color removal was obtained using 31 holes orifice plate of 2 mm holes' diameter, at 4 bar inlet pressure. Furthermore, although HC could not degrade completely all the industrial-grade dyes, efficiency was enhanced in the presence of H2O2. The optimum concentration of hydrogen peroxide was 1.0 g/L regardless of the initial concentration of the dyes studied. Under optimum operating conditions, color removal reached up to 68% for black, 39% for red, 43% for yellow, 55% for green, and 51% for cyan dye, while color removal in the PIW reached only 15%. The black dye solution presented almost 100% COD removal, while 38%, 25%, 67%, and 78% COD removal values were obtained for the red, yellow, cyan and green dyes, respectively. 55% COD removal was recorded from the PIW. Concerning cavitation yields, black, red, yellow, green, cyan dye yields reached 2.5E(-7), 1.1E(-7), 1.5E(-7), 2.0E(-7), 1.7E(-7) OD⋅L/J, respectively, while PIW yield was 6.3E(-8) OD⋅L/J. The present study demonstrates that HC combined with green oxidants such as hydrogen peroxide could be an alternative treatment approach for real industrial wastewater streams. However, a combination with a post-treatment method should be applied to maximize both color and COD removal.