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Bioresour Technol ; 135: 644-51, 2013 May.
Article in English | MEDLINE | ID: mdl-23375765

ABSTRACT

A raw bio-oil from pine sawdust, the liquid product from its thermal conditioning and a synthetic bio-oil composed by eight model compounds representing the main chemical groups in bio-oils, were converted thermally and over a commercial equilibrium FCC catalyst. The experiments were performed in a fixed bed reactor at 500 °C. The highest hydrocarbon yield (53.5 wt.%) was obtained with the conditioned liquid. The coke yields were significant in all the cases, from 9 to 14 wt.%. The synthetic bio-oil produced lesser hydrocarbons and more oxygenated compounds and coke than the authentic feedstocks from biomass. The previous thermal treatment of the raw bio-oil had the positive effects of increasing 25% the yield of hydrocarbons, decreasing 55% the yield of oxygenated compounds and decreasing 20% the yield of coke, particularly the more condensed coke.


Subject(s)
Biofuels/analysis , Oils/analysis , Pinus/chemistry , Temperature , Catalysis , Coke/analysis , Hydrocarbons/analysis , Oxygen/analysis
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