ABSTRACT
Ni-Mn-based Heusler alloys are known to demonstrate magnetic shape memory and giant magnetocaloric effect (MCE). These effects depend on the phases, crystallographic and magnetic phase transitions, and the crystallographic texture characteristics. These structural characteristics, in turn, are a function of the processing parameters. In the current work, Ni55.5Mn18.8Ga24Si1.7 Heusler alloy was processed by melt-spinning under a helium atmosphere. This process results in a fine microstructure. The ribbon that was produced with a narrower nozzle width, faster wheel speed, and higher cast temperature, indicating a faster cooling rate, had double the magnetic entropy change close to room temperature. However, the other ribbon demonstrated a large entropy change over a broader temperature range, extending its usability. The effect of the melt-spinning process parameters on the developing microstructure, crystallographic structure and texture, transformation temperatures, and the magnetic entropy change were studied to explain the difference in magnetocaloric behavior.
ABSTRACT
Ti2NiCu exhibits outstanding properties, such as superelasticity. Recently, its functional properties were also demonstrated on the nanoscale, a fact that makes it the preferred choice for numerous applications. Its properties strongly depend on the manufacturing route. In this work, phase analysis, inhomogeneity, and texture of melt-spun Ti2NiCu ribbons were investigated using X-ray diffraction. Initially, the ribbons are amorphous. Passing an electric current result in controlled crystallization. Ribbons with 0%, 60%, and 96% crystallinity were studied. Both B2 austenite and B19 martensite phases were observed. Using grazing incidence X-ray diffraction, the inhomogeneity across the thickness was investigated and found to be substantial. At the free surface, a small presence of titanium dioxide may be present. Pole figures of 60% and 96% crystallinity revealed mostly strong fiber <100>B2 texture in the thickness direction. These observations may be inferred from the manufacturing route. This texture is beneficial. The inhomogeneity across the thickness has to be considered when designing devices.
