Scaling Description of Frictionless Dense Suspensions under Inhomogeneous Flow.

Predicting the rheology of dense suspensions under inhomogeneous flow is crucial in many industrial and geophysical applications, yet the conventional "µ(J)" framework is limited to homogeneous conditions in which the shear rate and solids fraction are spatially invariant. To address this shortcoming, we use particle-based simulations of frictionless dense suspensions to derive new constitutive laws that unify the rheological response under both homogeneous and inhomogeneous conditions. By defining a new dimensionless number associated with particle velocity fluctuations and combining it with the viscous number, the macroscopic friction, and the solids fraction, we obtain scaling relations that collapse data from homogeneous and inhomogeneous simulations. The relations allow prediction of the steady state velocity, stress, and volume fraction fields using only knowledge of the applied driving force.

Soft pinning: Experimental validation of static correlations in supercooled molecular glass-forming liquids.

Enormous enhancement in the viscosity of a liquid near its glass transition is a hallmark of glass transition. Within a class of theoretical frameworks, it is connected to growing many-body static correlations near the transition, often called "amorphous ordering." At the same time, some theories do not invoke the existence of such a static length scale in the problem. Thus, proving the existence and possible estimation of the static length scales of amorphous order in different glass-forming liquids is very important to validate or falsify the predictions of these theories and unravel the true physics of glass formation. Experiments on molecular glass-forming liquids become pivotal in this scenario as the viscosity grows several folds (∼1014), and simulations or colloidal glass experiments fail to access these required long-time scales. Here we design an experiment to extract the static length scales in molecular liquids using dilute amounts of another large molecule as a pinning site. Results from dielectric relaxation experiments on supercooled Glycerol with different pinning concentrations of Sorbitol and Glucose, as well as the simulations on a few model glass-forming liquids with pinning sites, indicate the versatility of the proposed method, opening possible new avenues to study the physics of glass transition in other molecular liquids.

Creep failure of amorphous solids under tensile stress.

Applying constant tensile stress to a piece of amorphous solid results in a slow extension, followed by an eventual rapid mechanical collapse. This "creep" process is of paramount engineering concern, and as such was the subject of study in a variety of materials, for more than a century. Predictive theories for τ_{w}, the expected time of collapse, are incomplete, mainly due to its dependence on a bewildering variety of parameters, including temperature, system size, tensile force, but also the detailed microscopic interactions between constituents. The complex dependence of the collapse time on all the parameters is discussed below, using simulations of strip of amorphous material. Different scenarios are observed for ductile and brittle materials, resulting in serious difficulties in creating an all-encompassing theory that could offer safety measures for given conditions. A central aim of this paper is to employ scaling concepts, to achieve data collapse for the probability distribution function (pdf) of lnτ_{w}. The scaling ideas result in a universal function which provides a prediction of the pdf of lnτ_{w} for out-of-sample systems, from measurements at other values of these parameters. The predictive power of the scaling theory is demonstrated for both ductile and brittle systems. Finally, we present a derivation of universal scaling function for brittle materials. The ductile case appears to be due to a plastic necking instability and is left for future research.

Direct measurement of dipoles in anomalous elasticity of amorphous solids.

Recent progress in studying the physics of amorphous solids has revealed that mechanical strains can be strongly screened by the formation of plastic events that are typically quadrupolar in nature. The theory stipulates that gradients in the density of the quadrupoles act as emergent dipole sources, leading to strong screening and to qualitative changes in the mechanical response, as seen, for example, in the displacement field. In this Letter we first offer direct measurements of the dipole field, independently of any theoretical assumptions, and second we demonstrate detailed agreement with the recently proposed theory. These two goals are achieved by using data from both simulations and experiments. Finally, we show how measurements of the dipole fields pinpoint the theory parameters that determine the profile of the displacement field.

Scaling theory for Wöhler plots in amorphous solids under cyclic forcing.

In mechanical engineering Wöhler plots serve to measure the average number of load cycles before materials break, as a function of the maximal stress in each cycle. Although such plots have been prevalent in engineering for more than 150 years, their theoretical understanding is lacking. Recently a scaling theory of Wöhler plots in the context of cyclic bending was offered [Bhowmik, arXiv:2103.03040 (2021)]. Here we elaborate further on cyclic bending and extend the considerations to cyclic tensile loads on an amorphous strip of material; the scaling theory applies to both types of cyclic loading equally well. On the basis of atomistic simulations we conclude that the crucial quantities to focus on are the accumulated damage and the average damage per cycle. The dependence of these quantities on the loading determines the statistics of the number of cycles to failure. Finally, we consider the probability distribution functions of the number of cycles to failure and demonstrate that the scaling theory allows prediction of these distributions at one value of the forcing amplitude from measurements and another value.

Thermodynamic equivalence of cyclic shear and deep cooling in glass formers.

The extreme slowing down associated with glass formation in experiments and in simulations results in serious difficulties to prepare deeply quenched, well annealed, glassy material. Recently, methods to achieve such deep quenching were proposed, including vapor deposition on the experimental side and "swap Monte Carlo" and oscillatory shearing on the simulation side. The relation between the resulting glasses under different protocols remains unclear. Here we show that oscillatory shear and swap Monte Carlo result in thermodynamically equivalent glasses sharing the same statistical mechanics and similar mechanical responses under external strain.

Particle pinning suppresses spinodal criticality in the shear-banding instability.

Strained amorphous solids often fail mechanically by creating a shear band. It had been understood that the shear-banding instability is usefully described as crossing a spinodal point (with disorder) in an appropriate thermodynamic description. It remained contested, however, whether the spinodal is critical (with divergent correlation length) or not. Here we offer evidence for critical spinodal by using particle pinning. For a finite concentration of pinned particles the correlation length is bounded by the average distance between pinned particles, but without pinning it is bounded by the system size.

Effect of Pinning on the Yielding Transition of Amorphous Solids.

Using numerical simulations, we have studied the yielding response, in the athermal quasistatic limit, of a model amorphous material having inclusions in the form of randomly pinned particles. We show that, with increasing pinning concentration, the plastic activity becomes more spatially localized, resulting in smaller stress drops, and a corresponding increase in the magnitude of strain where yielding occurs. We demonstrate that, unlike the spatially heterogeneous and avalanche led yielding in the case of the unpinned glass, for the case of large pinning concentration, yielding takes place via a spatially homogeneous proliferation of localized events.

Non-Gaussianity of the van Hove function and dynamic-heterogeneity length scale.

Non-Gaussian nature of the probability distribution of particles' displacements in the supercooled temperature regime in glass-forming liquids are believed to be one of the major hallmarks of glass transition. It has already been established that this probability distribution, which is also known as the van Hove function, shows universal exponential tail. The origin of such an exponential tail in the distribution function is attributed to the hopping motion of particles observed in the supercooled regime. The non-Gaussian nature can also be explained if one assumes that the system has heterogeneous dynamics in space and time. Thus exponential tail is the manifestation of dynamic heterogeneity. In this work we directly show that non-Gaussianity of the distribution of particles' displacements occur over the dynamic heterogeneity length scale and the dynamical behavior course grained over this length scale becomes homogeneous. We study the non-Gaussianity of the van Hove function by systematically coarse graining at different length scales and extract the length scale of dynamic heterogeneity at which the shape of the van Hove function crosses over from non-Gaussian to Gaussian. The obtained dynamic heterogeneity scale is found to be in very good agreement with the scale obtained from other conventional methods.