ABSTRACT
In this study, bare and ionic liquid-modified ZnO nanoparticles have been fabricated using microwave irradiation method. The fabricated nanoparticles were characterized by different techniques, viz. XRD, FT-IR, FESEM, and UV-Visible spectroscopy, and were explored as adsorbent for effective sequestration of azo dye (Brilliant Blue R-250) from aqueous media. Various factors affecting the adsorption efficiency of synthesized nanoparticles (bare/ionic liquid-modified) such as concentration of dye, pH of reaction media, dose of nanoparticles, and reaction time were thoroughly investigated with varying experimental conditions; on a magnetic stirrer and in a sonicator. The results exhibited a high adsorption efficiency of ionic liquid-modified nanoparticles for removal of dye as compared to the bare one. Also, an enhanced adsorption was observed via sonication in comparison with magnetic stirring. Different isotherms such as Langmuir, Freundlich, and Tempkin were elaborated. Evaluation of adsorption kinetics showed a linear pseudo-second-order equation for adsorption process. The exothermic and spontaneous nature of adsorption was further confirmed by thermodynamic investigations. As per the results obtained, it is suggested that the fabricated ionic liquid-modified ZnO nanoparticles could successfully remediate the toxic anionic dye from aqueous media. Hence, this system can be utilized for large-scale industrial applications.
ABSTRACT
In India, Indo-Gangetic Plains (IGP) is becoming the hotspot of air pollution due to increasing anthropogenic activities such as rapid industrial growth, infrastructure development, transportation activities, and seasonal practice of crop residue burning. In the current study, seasonal variation in ambient air quality for 14 parameters, i.e., particulate matter (PM), trace gases, and volatile organic compounds (VOCs), along with meteorological parameters, was studied in 21 districts of the Haryana state for year 2019, situated in IGP. To analyze spatial variation of pollutants, ambient air quality data of 23 continuous ambient air quality monitoring stations were divided into three zones based on ecology and cropping pattern. All the zones showed annual mean PM10 and PM2.5 concentrations much higher than national ambient air quality standards. Annual mean PM10 concentration (±standard deviation) in Zones-1, 2, and 3 was 156±86, 174±93, and 143±74 µg m-3, whereas for PM2.5 was 71±44, 85±54, and 78±47 µg m-3. The results showed a considerable seasonal variation in the concentration of all pollutants. Most of the pollutants peak in the post-monsoon season, followed by winters in which crop residue burning predominates in many parts of the Haryana. PM10 concentrations increased by 65-112% and PM2.5 concentrations increased by 131-147% in the post-monsoon season compared to monsoons. The post-monsoon season showed the highest concentration of PM10, NO, and toluene (Zone-1); and PM2.5, NH3, CO, and benzene (Zone-2); whereas in winters, SO2 (Zone-1); ethylbenzene, m,p-xylene, and xylene (Zone-2); and NO2 and NOx (Zone-3) showed the maximum pollution levels. The O3 concentration was highest in the pre-monsoon season (Zone-1). The satellite-based fire counts and PCA results show a significant influence of crop residue burning in the post-monsoon season and solid biomass burning in winters on Haryana's air quality. The study could help to understand seasonal variation in ambient air quality and the influence of factors such as crop residue burning in the IGP region, which could help to formulate season-specific control measures to improve regional air quality.
