Post-Processing Effect on the Corrosion Resistance of Super Duplex Stainless Steel Produced by Laser Powder Bed Fusion.

This study examines the microstructural characteristics and corrosion resistance of super duplex stainless steel (SDSS) produced through laser powder bed fusion (LPBF). The analysis shows that the as-printed samples mainly exhibit a ferritic microstructure, which is due to the fast-cooling rates of the LPBF technique. X-ray and microstructure analyses reveal the presence of minor austenite phases in the ferritic matrix. The process of solution annealing led to a more balanced microstructure. Analyses of corrosion resistance, such as potentiodynamic polarization tests and EIS, indicate that heat treatment has a significant impact on the corrosion behavior of SDSS. Solution annealing and stress relieving at 400 °C for 1 h can improve corrosion resistance by increasing polarization resistance and favorable EIS parameters. However, stress relieving at 550 °C for 5 h may reduce the material's corrosion resistance due to the formation of chromium nitride. Therefore, stress relieving at 400 °C for 1 h is a practical method to significantly enhance the corrosion resistance of LPBF-printed SDSS. This method offers a balance between microstructural integrity and material performance.

The Biocompatibility and Self-Healing Effect of a Biopolymer's Coating on Zn Alloy for Biomedical Applications.

The objective of this study was to formulate dip coatings, incorporating casein, NaOH, and nanocrystalline hydroxyapatite (nanoHAp), with self-healing properties for application on ZnMg3.2 wt.% alloy in the field of biomedical applications. This study hypothesizes that the self-healing mechanism within the layer will impede substrate degradation by progressively filling defects where chlorides from simulated body fluids intervene. Furthermore, it aims to mitigate potential damage effects during the implantation process by the layer's self-healing capabilities. The research focused on the dip-coating process parameters and chemical composition of baths for producing casein coatings on Zn alloy surfaces. This study investigated the impact of casein and NaOH concentration, along with the immersion time of ZnMg3.2 wt.% samples in the coating bath, on the self-healing capability of the coating under simulated human body fluid conditions (Ringer's solution, temperature: 37 °C). Effective technology was developed by selecting specific chemical compositions and immersion times in the coating bath, enhancing the self-healing progress against coating damage in Ringer's solution at 37 °C. The most significant self-healing effect was observed when the ZnMg3.2 wt.% substrate underwent a 1 h immersion in a coating bath containing 2 g of casein, 4 g of NaOH, and 0.1 g of nanoHAp powder. Electrochemical tests were instrumental in determining the optimal casein concentration and immersion time of the Zn alloy in the coating bath.

Simulation of 316L Stainless Steel Produced the Laser Powder Bed Fusion Process.

Additive manufacturing is increasingly being used in the production of parts of simple as well as complex shapes designed for various areas of industry. Prevention of errors in the production process is currently enabled using simulation tools that have the function of predicting possible errors and, at the same time, providing a set of information about the behaviour of the material in the metal additive manufacturing process. This paper discusses the simulation processes of 316L stainless steel produced using the laser powder bed fusion (L-PBF) process. Simulation of the printing process in the Simufact Additive simulation program made it possible to predict possible deformations and errors that could occur in the process of producing test samples. After analysing the final distortion already with compensation, the simulation values of maximum deviation -0.01 mm and minimum -0.13 mm were achieved.

Investigation of the Properties of 316L Stainless Steel after AM and Heat Treatment.

Additive manufacturing, including laser powder bed fusion, offers possibilities for the production of materials with properties comparable to conventional technologies. The main aim of this paper is to describe the specific microstructure of 316L stainless steel prepared using additive manufacturing. The as-built state and the material after heat treatment (solution annealing at 1050 °C and 60 min soaking time, followed by artificial aging at 700 °C and 3000 min soaking time) were analyzed. A static tensile test at ambient temperature, 77 K, and 8 K was performed to evaluate the mechanical properties. The characteristics of the specific microstructure were examined using optical microscopy, scanning electron microscopy, and transmission electron microscopy. The stainless steel 316L prepared using laser powder bed fusion consisted of a hierarchical austenitic microstructure, with a grain size of 25 µm as-built up to 35 µm after heat treatment. The grains predominantly contained fine 300-700 nm subgrains with a cellular structure. It was concluded that after the selected heat treatment there was a significant reduction in dislocations. An increase in precipitates was observed after heat treatment, from the original amount of approximately 20 nm to 150 nm.

Evaluation of Powder Metallurgy Workpiece Prepared by Equal Channel Angular Rolling.

The aim of the article is to examine the workability of sintered powder material of aluminum alloy (Alumix 321) through severe plastic deformations under the conditions of the equal channel angular rolling (ECAR) process. Accordingly, the stress-strain analysis of the ECAR was carried out through a computer simulation using the finite element method (FEM) by Deform 3D software. Additionally, the formability of the ALUMIX 321 was investigated using the diametrical compression (DC) test, which was measured and analyzed by digital image correlation and finite element simulation. The relationship between failure mode and stress state in the ECAR process and the DC test was quantified using stress triaxiality and Lode angle parameter. It is concluded that the sintered powder material during the ECAR processing failure by a shearing fracture because in the fracture location the stress conditions were close to the pure shear (η and θ¯ ≈ 0). Moreover, the DC test revealed the potential role as the method of calibration of the fracture locus for stress conditions between the pure shear and the axial symmetry compression.

Impact of Blank Holding Force and Friction on Springback and Its Prediction of a Hat-Shaped Part Made of Dual-Phase Steel.

Formability and its prediction of high-strength steels is an important research subject for forming specialists and researchers in this field. Springback and its accurate prediction of high-strength steels are very common issues in metal forming processes. In this article, the impact of blank holding force and friction on the parts springback made of dual-phase steel was studied. Numerical predictions of the springback effect were conducted using nine combinations of yield criteria and hardening rules. Results from experiments were evaluated and compared with results from numerical simulations. The use of lower blank holding forces and PE foil can reduce springback by a significant amount. Numerical simulations where the Yoshida-Uemori hardening rule was applied produced more accurate springback prediction results compared to simulations that used Krupkowski and Hollomon's isotropic hardening rules in number of cases.

Experimental and Numerical Thickness Analysis of TRIP Steel under Various Degrees of Deformation in Bulge Test.

To design a reliable forming process it is necessary to determine the mechanical and formability properties of the processed material, which are used as input parameters for forming simulations. High-strength steel is irreplaceable as a material for producing the deformation zones of current automobiles. This type of steel can be processed by conventional or unconventional forming methods. In the sheet forming process, the material is usually under uniaxial and biaxial stress. The bulge test is utilized for determination of biaxial stress-strain curves, which are often used as input material data for forming simulations. In this work, numerical simulations of bulge tests using TRIP RAK 40/70 steel were performed to study the impact of yield criteria and hardening laws on the accuracy of thickness prediction of the deformed steel sheet. Additionally, the impact of different solvers and integration schemes on the thickness prediction was tested. Furthermore, the impact of various degrees of deformation (various dome heights) on thickness prediction accuracy was evaluated. Numerical results showed a good correlation with experimental data. When the Hill90 yield criterion was used, the software with implicit solver was more accurate in predicting thickness compared to software with explicit integration scheme, in most cases. In addition, the thickness prediction of parts with lower deformation was more accurate compared to parts with greater deformation (higher dome height).

MIG and TIG Joining of AA1070 Aluminium Sheets with Different Surface Preparations.

In this work, AA1070 aluminium alloy sheets are joined using TIG and MIG welding after three different edge preparations. Shearing, water jet and plasma-cut processes were used to cut sheets, subsequently welded using ER5356 and ER4043 filler metals for TIG and MIG, respectively. Mechanical properties of the obtained sheets were assessed through tensile tests obtaining a relation between sheet preparation and welding tightness. Micro-hardness measures were performed to evaluate the effects of both welding and cutting processes on the micro-hardness of the alloy, highlighting that TIG welding gives rise to inhomogeneous micro-hardness behaviour. After tensile tests, surface fractures were observed employing scanning electron microscopy to highlight the relation between tensile properties and edge preparations. Fractures show severe oxidation in the water jet cut specimens, ductile fractures and gas porosities.

Recent Advances in Multi-Functional Coatings for Soft Magnetic Composites.

During the past 50 years, the aim to reduce the eddy current losses in magnetic cores to a minimum led to the formulation of new materials starting from electrically insulated iron powders, today called Soft Magnetic Composites (SMC). Nowadays, this promising branch of materials is still held back by the mandatory tradeoff between energetic, electrical, magnetic, and mechanical performances. In most cases, the research activity focuses on the deposition of an insulating/binding layer, being one of the critical points in optimizing the final composite. This insulation usually is achieved by either inorganic or organic layer constituents. The main difference is the temperature limit since most inorganic materials typically withstand higher treatment temperatures. As a result, the literature shows many materials and process approaches, each one designed to meet a specific application. The present work summarizes the recent advances in state of the art, analyzing the relationship among material compositions and magnetic and mechanical properties. Each coating shows its own processing sets, which vary from simple mechanical mixing to advanced chemical methods to metallurgical treatments. From state of the art, Aluminum coatings are characterized by higher current losses and low mechanical properties. In contrast, higher mechanical properties are obtained by adopting Silicon coatings. The phosphates coatings show the best-balanced overall properties. Each coating type was thoroughly investigated and then compared with the literature background highlighting. The present paper thus represents a critical overview of the topic that could serve as a starting point for the design and development of new and high-performing coating solutions for SMCs. However, global research activity continuously refines the recipes, introducing new layer materials. The following steps and advances will determine whetherthese materials breakthrough in the market.

Overview of HSS Steel Grades Development and Study of Reheating Condition Effects on Austenite Grain Size Changes.

This review paper concerns the development of the chemical compositions and controlled processes of rolling and cooling steels to increase their mechanical properties and reduce weight and production costs. The paper analyzes the basic differences among high-strength steel (HSS), advanced high-strength steel (AHSS) and ultra-high-strength steel (UHSS) depending on differences in their final microstructural components, chemical composition, alloying elements and strengthening contributions to determine strength and mechanical properties. HSS is characterized by a final single-phase structure with reduced perlite content, while AHSS has a final structure of two-phase to multiphase. UHSS is characterized by a single-phase or multiphase structure. The yield strength of the steels have the following value intervals: HSS, 180-550 MPa; AHSS, 260-900 MPa; UHSS, 600-960 MPa. In addition to strength properties, the ductility of these steel grades is also an important parameter. AHSS steel has the best ductility, followed by HSS and UHSS. Within the HSS steel group, high-strength low-alloy (HSLA) steel represents a special subgroup characterized by the use of microalloying elements for special strength and plastic properties. An important parameter determining the strength properties of these steels is the grain-size diameter of the final structure, which depends on the processing conditions of the previous austenitic structure. The influence of reheating temperatures (TReh) and the holding time at the reheating temperature (tReh) of C-Mn-Nb-V HSLA steel was investigated in detail. Mathematical equations describing changes in the diameter of austenite grain size (dγ), depending on reheating temperature and holding time, were derived by the authors. The coordinates of the point where normal grain growth turned abnormal was determined. These coordinates for testing steel are the reheating conditions TReh = 1060 °C, tReh = 1800 s at the diameter of austenite grain size dγ = 100 µm.

Case Study of the Tensile Fracture Investigation of Additive Manufactured Austenitic Stainless Steels Treated at Cryogenic Conditions.

Additive manufacturing is a key enabling technology in the manufacture of highly complex shapes, having very few geometric limitations compared to traditional manufacturing processes. The present paper aims at investigating mechanical properties at cryogenic temperatures for a 316L austenitic stainless steel, due to the wide possible cryogenic applications such as liquid gas confinement or superconductors. The starting powders have been processed by laser powder bed fusion (LPBF) and tested in the as-built conditions and after stress relieving treatments. Mechanical properties at 298, 77 and 4.2 K from tensile testing are presented together with fracture surfaces investigated by field emission scanning electron microscopy. The results show that high tensile strength at cryogenic temperature is characteristic for all samples, with ultimate tensile strength as high as 1246 MPa at 4.2 K and 55% maximum total elongation at 77 K. This study can constitute a solid basis for investigating 316L components by LPBF for specific applications in cryogenic conditions.

Different Formation Routes of Pore Structure in Aluminum Powder Metallurgy Alloy.

In powder metallurgy (PM), severe plastic deformation (SPD) is a well-known technological solution to achieve interesting properties. However, the occurrence of pores in the final product may limit these properties. Also, for a given type of microstructure, the stereometric parameters of the pore structures, such as shape (represented by Aspect and Dcircle) and distribution (fshape, and fcircle), decisively affect the final properties. The influence of different processing routes (pressing, sintering and equal channel angular pressing (ECAP)) on pore structures in an aluminum PM alloy is discussed. The nature of porosity, porosity evolution and its behavior is explored. The correlation between pore size and morphology is also considered. The final pore structure parameters (Aspect, Dcircle, fshape, and fcircle) of studied aluminum alloys produced by different processing routes depends on the different formation routes.

Junction Characterization in a Functionally Graded Aluminum Part.

Aluminum alloys are widely used to produce automotive components, thanks to their great mechanical properties-to-density ratio. Engine components such as pistons are conventionally produced by casting of Al-Si eutectic alloys (Silumin alloys) such as EN AC 48000. Due to the harsh working conditions and the lower ductility if compared to aluminum-silicon alloys with lower silicon content, pistons made of this alloy are prone to fatigue failures in the skirt region. In order to overcome such limits, the use of a Functionally Graded Material (FGM) in the production of a piston is proposed. The adoption of a functionally graded architecture can maximize the properties of the component in specific areas. A higher level of thermal resistance in the crown of the piston can be achieved with EN AC 48000 (AlSi12CuNiMg), while higher elongation at rupture in the skirt region would be conferred by an EN AC 42100 (AlSi9Mg0.3). The FGM properties are strictly related to the metallurgical bonding between the alloys as well as to the presence of intermetallic phases in the alloys junction. In the present article, the characterization of gravity casted FGM samples based on Al-Si alloys with respect to microstructure and mechanical testing is presented, with a specific focus on the characterization by impact testing of the joint between the two alloys.