EPR investigation of gamma-irradiated FAMOSER drug for DOSIMETRIC purposes.

Exposure to ionizing radiation can also lead to the formation of stable or unstable radicals in the structures of drugs, as in many materials. The concentrations of these radicals may show a linear dependence on the radiation dose exposed. Since drugs are materials that can be found next to or on radiation victims during a possible nuclear or radiological accident, it is very meaningful to determine the Electron Paramagnetic Resonance (EPR) dosimetric properties of stable radicals in their structures. In this study, the dosimetric properties of Famoser, which is one of the stomach-relieving drugs that people often have with them in their daily life, in the dose range of 10-800 Gy were investigated by EPR technique.

Paramagnetic characterization of fossil mollusc shells at eastern part of the old Konya lake: its importance for EPR dating.

Fossil mollusc shells are used for dating geological materials because they are well preserved throughout geological time. In this study, the radicals in the structure of fossil mollusc shells (Dreissena iconica, Valvata piscinalis, Bithynia tentaculate, Unio pictorum) collected from the Eastern Part of Old Konya Lake in Türkiye were investigated by EPR technique. For all fossil shells, microwave and temperature dependence of the signals were examined, and the signals suitable for dating are discussed. Characteristic features of intrinsic and impurity-related radicals were identified and the importance of paleontological evaluation of molluscs to get a reliable equivalent dose in EPR dating studies was emphasised.

RADIOLOGICAL ASSESSMENT OF NATURAL RADIOACTIVITY IN A URANIUM DEPOSIT AREA: KÖPRÜBASI, TÜRKIYE.

In this study, the results of environmental radioactivity studies conducted in Köprübasi, Manisa district, where Türkiye's uranium mineral exploration and processing studies were carried out, are shared. Because this is a populated area, there is a need for radio ecological dosimetry assessment to investigate the possible risk to the population. The region where radiological monitoring is carried out is discussed in two parts as the areas where uranium mineral exploration is performed and the settlements close to these areas. It was observed that 714-4714 nGy/h values were obtained in the outdoor absorbed dose rate in air measurements taken in the areas where mineral exploration was performed and this value reached up to 22 857 nGy/h in open field mining areas. In the residential areas, it was recorded that the outdoor absorbed dose rate in air values ranged between 142 and 242 nGy/h and the indoor values ranged between 171 and 400 nGy/h. The world absorbed dose rate in air average values is 57 nGy/h (outdoor) and 75 nGy/h (indoor). The high 226Ra values in the radioactivity analyses of the soil samples draw attention. The mean values of the activity concentrations of the radionuclides 226Ra, 232Th and 40K in the soil samples are 3169, 55 and 802 Bq/kg and the world averages of these values are 35, 30 and 400 Bq/kg, respectively. It was determined that high 226Ra value in the soil in the areas close to the open field uranium mining area was passed on to the agricultural products. Radioactivity measurement results of drinking water samples did not exceed World Health Organization guidelines. According to the radon gas measurement results of 44 houses in Köprübasi villages, the average radon concentrations in winter, spring, summer and autumn seasons were 72, 61, 50 and 55 Bq/m3, and the annual average value was 60 Bq/m3, respectively. Although these values are greater than the world average of 46 Bq/m3, they are below the recommended limit value (100 Bq/m3). By evaluating the data obtained, the total annual effective equivalent dose values (originating from outdoor-indoor absorbed dose in air, drinking water and indoor radon gas concentration) to which the people in the region are exposed were calculated as a 3.12 mSv.

Environmental radioactivity and high incidence rates of stomach and esophagus cancer in the Van Lake region: a causal relationship?

This study examined the incidence rates of cancer cases (averages for 2006-2010) and relationships with environmental radioactivity levels. Soil and water samples were collected from provincial and district centers of Van city and the outdoor gamma doses were determined using a portable gamma scintillation detector. Gross alpha and beta, (226)Ra, (232)Th, and (40)K activities were measured in both tap water and soil samples. Although high rates of stomach and esophagus cancers have been reported previously in Van the underlying reasons have not hitherto been defined. Incidences of cancers were highest in the Gurpinar (326.0) and Ozalp (377.1) counties (p<0.001). As to the results of the gross alpha and gross beta radioactivity measurements in the drinking water, these two counties also had high beta radionuclide levels: Gurpinar (140 mBq/dm3) and Ozalp (206 mBq/dm3). Even if within the normal range, a relation between the higher rate of the incidence of stomach and esophagus cancers with that of the higher rate of beta radionuclide activity was clear. On Spearman correlation analysis, the relation between higher beta radionuclide levels and cancer incidence was found to be statistically significant (p<0.01). According to the results of the analysis, Van residents receive an average 1.86 mSv/y annual dose from outdoor gamma radiation, ingestion of radionuclides in the drinking water, and indoor 222Rn activity. Moreover, gross alpha and beta activities were found to be extremely high in all of the lakes around the city of Van, Turkey. Further investigations with long-term detailed environmental radiation measurements are needed regarding the relationship between cancer cases and environmental radioactivity in the city of Van.

An EPR study on tea: identification of paramagnetic species, effect of heat and sweeteners.

Tea (Camellia Sinensis) is the most widely consumed beverage in the world, and is known to be having therapeutic, antioxidant and nutritional effects. Electron paramagnetic resonance (EPR) spectral studies made on the tea cultivated along the shore of Black Sea, Turkey, show Mn(2+) and Fe(3+) centers in green tea leaves and in black tea extract. Dry black tea flakes and dry extract show additional sharp line attributed to semiquinone radical. The origins of the paramagnetic species in black tea are defined and discussed. Effect of humidity and heat are investigated. It is observed that dry extract of black tea melts at 100 degrees C and the semiquinone radical lives up to 140 degrees C while Mn(2+) sextet disappears just above 100 degrees C in tea extract. Natural and synthetics sweeteners have different effects on the paramagnetic centers. White sugar (sucrose) quenches the Mn(2+) and semiquinone lines in black tea EPR spectrum, and glucose, fructose, lactose and maltose quench Fe(3+) line while synthetic sweeteners acesulfam potassium, aspartame and sodium saccharine do not have any effect on paramagnetic species in tea.

EPR spectra of Cu(2+) in KH(2)PO(4) single crystals.

Cu(2+) doped single crystals of KH(2)PO(4) were investigated using EPR technique at room temperature. The spectra of the complex contains large number of overlapping lines. Five sites are resolved and four of them are compatible with the tetragonal symmetry, and the fifth one belongs to an interstitial site. The results are discussed and compared with previous studies. Detailed investigation of the EPR spectra indicate that Cu(2+) substitute with K(+) ions. The principal values of the g and hyperfine tensors and the ground state wave function of Cu(2+) ions are obtained.