Fast and ecofriendly triple sulfonamides mixture utilization using UV irradiation and spherical SnO2 nanoparticles with controllable parameters and antibacterial activity.

One of the solutions for the growing problem of water purification is photocatalytic degradation of the pollutants. Semiconductor nanoparticles are widely under study as a promising photocatalyst for this purpose. However, there is still lack of understanding of the relation between properties of nanoparticles, in their turn related with synthesis conditions, and photocatalytic efficiency, as well as of the other factors influencing the process. For the first time, a possibility to regulate photocatalytic activity of SnO2 nanoparticles under UV light via regulation of structural parameters is shown. A method for obtaining spherical nanoparticles with different parameters was developed. Obtained nanoparticles were fully characterized. Special attention was paid to the study of oxygen vacancies. With the help of quantum computational methods, it was shown, that the concentration of vacancies is around 1 per 32 tin atoms. Obtained data on oxygen vacancies were further used for the evaluation of pollutant-nanoparticle surface interaction to get closer to the calculations of real systems. On the example of methylene blue, it was shown that the greater is the amount of oxygen vacancies and the lower the amount of defects, the higher photocatalytic activity. The obtained dependence is confirmed by the fact that the photoresponse increases with a decrease of amount of defects in the sample. Degradation kinetics of sulfonamides mixture was studied, and its dependence on active complex formation was shown based on the quantum chemical calculation data. Degradation of antibiotics in water from Neva River reached more than 95% in 35 min, which indicates that developed photocatalyst efficiency is not affected by pollutants contained in open water in the centre of the metropolis. It was shown, that the use of nanoparticles allows to speed up the process of bacteria destruction under UV light, which indicates the antibacterial activity of obtained nanoparticles.

Synthesis of ZnFe2O4 Nanospheres with Tunable Morphology for Lithium Storage.

ZnFe2O4 (ZFO) nanospheres with complex structures have been synthesized by a one-step simple solvothermal method using two different types of precursors-metal chlorides and nitrates -and were fully characterized by XRD, SEM, XPS, and EDS. The ZFO nanospheres synthesized from chloride salts (ZFO_C) were loose with a size range of 100-200 nm, while the ZFO nanospheres synthesized from nitrate salts (ZFO_N) were dense with a size range of 300-500 nm but consisted of smaller nanoplates. The different morphologies may be caused by the different hydrolysis rates and different stabilizing effects of chloride and nitrate ions interacting with the facets of forming nanoparticles. Electrochemical tests of nitrate-based ZFO nanospheres as anode materials for lithium-ion batteries demonstrated their higher cyclic stability. The ZFO_C and ZFO_N samples have initial specific discharge/charge capacities of 1354/1020 and 1357/954 mAh∙g-1, respectively, with coulombic efficiencies of 75% and 71%. By the 100th cycle, ZFO_N has a capacity of 276 mAh∙g-1, and for ZFO_C, only 210 mAh∙g-1 remains after 100 cycles.

The strategy for organic dye and antibiotic photocatalytic removal for water remediation in an example of Co-SnO2 nanoparticles.

A challenging problem to create an efficient photocatalyst suitable for industrial water remediation, aiming to remove cyclic organic compounds attracts increasing attention. The current study aimed to clarify a few "dark spots" in the field, namely to find out if it is possible to make an efficient photocatalyst activated with visible light by using a simple and cheap strategy and what are the key factor impacting its efficiency. In this work, a new procedure to obtain spherical nanoparticles with the same average size but different amounts of oxygen vacancies and defects and dopant concentrations was developed. The approach based on hydrothermal treatment was suggested to obtain rod-shaped nanoparticles. The systematic study of photocatalytic behavior on the example of oxytetracycline and methylene blue degradation under visible light of widely available LED lamp was performed. Based on chemical and computational experiments the main factor affecting the process efficiency was determined.

Chemical and computational strategy for design of "switchable" sorbent based on hydroxyapatite nanoparticles for dispersive micro-solid phase extraction of tetracyclines.

A challenging task in analytical chemistry is an application of renewable and natural materials for isolation of hazardous substances such as antimicrobial drugs from environmental samples. The energy-efficient scalable hydrothermal procedure to fabricate the eco-friendly "switchable" sorbent based on hydroxyapatite nanoparticles with in situ modified surface using a small amount of capping agents was developed. Sorbents characterization including the surface composition investigation via quantum-chemical calculation based on the original approach was provided. The sorbents demonstrated well expressed controllable surface switching and high values of the sorption and elution efficiency for tetracycline, oxytetracycline, and chlortetracycline achieved by simple change of the medium pH. These processes were thoroughly discussed based on the results of chemical and computational experiments. A simple and universal strategy for choosing a suitable sorbent for solid phase extraction of target analytes was proposed for the first time. It was shown that the developed eco-friendly sample preparation procedure with use of biocompatible sorbents could be applied both for removal of target analytes from sample matrix (water samples) as well as for the quantitative analytes determination after elution step. It is believed that the presented research is significant for the determination of different amphoteric analytes in wide variety of samples.

Tin oxide nanoparticles modified by copper as novel catalysts for the luminol-H2O2 based chemiluminescence system.

In this study, SnO2 nanoparticles modified by copper were found to greatly enhance the chemiluminescence intensity of the luminol-H2O2 system for the first time. The developed approach was applied for the determination of H2O2 as a proof-of-concept example.

Superparamagnetism of magnetite nanoparticles: dependence on surface modification.

Superparamagnetic iron oxide nanoparticles (SPION) with an average particle diameter of 6 nm are prepared by controlled chemical coprecipitations. Colloidal suspensions of noninteracting SPION, where the surface has been modified with three different types of biocompatible substances, namely, starch, gold (Au), and methoxypoly(ethylene glycol) (MPEG) have been fabricated via three different techniques. Starch-coated SPION are prepared by coprecipitation in a polymeric matrix, Au-coated SPION are fabricated by the microemulsion method, and MPEG-coated SPION are prepared using the self-assembly approach. The magnetic nanoparticles form a core-shell structure, and the magnetic dipole-dipole interactions are screened by a layer of coating agents. The amounts of coating agents and SPION are indirectly calculated from the thermogravimetric analysis and superconducting quantum interference device measurements by assuming passive oxidation on the surface of the SPION, and the other conditions do not influence the measurements. The dependency of the spectral characteristics of Mössbauer spectroscopy as a function of an external magnetic field Hext is measured to investigate the effect of dipole-dipole screening of the different coating layers on the SPION. Uncoated SPION show a stable magnetic moment under Hext, and the superparamagnetic (SPM) fraction transforms to a ferrimagnetic state. Starch and Au-coated SPION retain the SPM fraction according to Mössbauer spectroscopy and magnetization measurements. MPEG-coated SPION show hyperfine magnetic structure without the quadrupole effect with increasing the value of the blocking temperature.