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1.
J Phys Chem B ; 122(27): 6995-7001, 2018 07 12.
Article in English | MEDLINE | ID: mdl-29890076

ABSTRACT

The formation of permanent structures upon mild red laser illumination in transparent polydiene solutions is examined in the case of gem-dichlorocyclopropanated polybutadiene ( gDCC-PB) polymers bearing 15% functional units of the dichlorocyclopropane groups. The response was found to be distinct from the precursor PB. Whereas fiber-like patterns were clearly observed in both precursor and gDCC-PB solutions in cyclohexane, these were absent in the case of gDCC-PB/chloroform but were present in the precursor PB/chloroform solutions. The involved mechanical stresses were not sufficient for the gDCC activation to be detected by NMR spectroscopy. Remarkably, addition of even 10 wt % gDCC-PB into the latter solution sufficed to suppress the light-induced patterning. The importance of the chemical environment on the response to light irradiation was further checked and confirmed by use of other PB copolymers. Different diameter patterns and kinetics were observed. The strong solvent and comonomer mediated effect was reflected neither in solvency nor in optical polarizability differences of the polymers solvent couples.

2.
Opt Express ; 25(4): 3252-3258, 2017 Feb 20.
Article in English | MEDLINE | ID: mdl-28241541

ABSTRACT

We report a nonlinear signal processing system based on a SiGe waveguide suitable for high spectral efficiency data signals. Four-wave-mixing (FWM)-based wavelength conversion of 10-Gbaud 16-Quadrature amplitude modulated (QAM) and 64-QAM signals is demonstrated with less than -10-dB conversion efficiency (CE), 36-dB idler optical signal-to-noise ratio (OSNR), negligible bit error ratio (BER) penalty and a 3-dB conversion bandwidth exceeding 30nm. The SiGe device was CW-pumped and operated in a passive scheme without giving rise to any two-photon absorption (TPA) effects.

3.
Opt Lett ; 35(2): 199-201, 2010 Jan 15.
Article in English | MEDLINE | ID: mdl-20081967

ABSTRACT

Data streams with bit rates of up to 1 Gbit/s have been applied though the subcarrier modulation technique in an experimentally deployed optical communication system based on chaos data encryption and have been recovered efficiently. By shifting the spectral components of the encrypted data in regions where the chaotic carrier is powerful, a more efficient encryption and final message recovery is recorded with respect to the baseband modulation technique, improving the up-to-date performance of analogous systems.

4.
Phys Rev Lett ; 100(19): 194101, 2008 May 16.
Article in English | MEDLINE | ID: mdl-18518451

ABSTRACT

A novel photonic monolithic integrated device consisting of a distributed feedback laser, a passive resonator, and active elements that control the optical feedback properties has been designed, fabricated, and evaluated as a compact potential chaotic emitter in optical communications. Under diverse operating parameters, the device behaves in different modes providing stable solutions, periodic states, and broadband chaotic dynamics. Chaos data analysis is performed in order to quantify the complexity and chaoticity of the experimental reconstructed attractors by applying nonlinear noise filtering.

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