ABSTRACT
The Joint Research Centre Institute for Reference Materials and Measurements (JRC-IRMM) participated in a research project initiated by the International Atomic Energy Agency (IAEA) to upgrade some of its existing reference materials (RMs). The aim of the work described in this article was to determine the activity concentration of a series of radionuclides in the IAEA-375 soil RM with values traceable to the SI units. The radionuclides (40)K, (134)Cs, (137)Cs, (212)Pb, (212)Bi, (214)Pb and (214)Bi were measured by γ-ray spectrometry after drying the sample and placing it in a suitable container. The (90)Sr was assessed by liquid scintillation counting after dissolution of the soil by wet digestion and chemical separation of Sr by extraction chromatography. This soil RM was used later as basis for the 2010 EC Interlaboratory Comparison on Radionuclides in Soil.
ABSTRACT
The Institute for Reference Materials and Measurements (IRMM) participated in a research project initiated by the International Atomic Energy Agency (IAEA) to upgrade some of its existing reference materials (RMs). The aim of the project is to improve the RM metrological status by establishing traceability of their assigned values to SI units. The purpose of the work described in this article was to establish traceability to the International System of Units (SI) of the activity concentrations of the radionuclides (134)Cs, (137)Cs, (40)K, and (90)Sr in the IAEA-152 milk powder RM. The choice of the particular RM was based on the concern about radioactivity levels in foodstuff. The sample preparation and the assaying of the activity concentrations in the milk powder, the methods used to achieve instrument calibrations and measurements traceable to the SI units, the data reduction and analysis, and finally, the results obtained are presented.
Subject(s)
Food Analysis/standards , Guidelines as Topic , Milk/chemistry , Milk/standards , Radioisotopes/analysis , Radioisotopes/standards , Radiometry/standards , Animals , Cattle , International System of Units , Internationality , Powders , Radiation Dosage , Reference Standards , Reference Values , Reproducibility of Results , Sensitivity and SpecificityABSTRACT
In the frame of the re-certification measurements of the IAEA-375 soil reference material the activity concentration of four actinoids (U, Th, Pu and Am) was determined. The method is based on microwave digestion or aqua regia leaching, separation by extraction chromatography and alpha-particle counting source preparation by co-precipitation or electro-deposition. This article describes some of the problems encountered during the validation of the sample preparation method and their solutions.
Subject(s)
Actinoid Series Elements/standards , Soil Pollutants, Radioactive/analysis , Specimen Handling/methods , Specimen Handling/standards , Spectrum Analysis/methods , Spectrum Analysis/standards , Actinoid Series Elements/analysis , Chromatography/methods , Chromatography/standards , Environmental Monitoring/methods , Environmental Monitoring/standards , European Union , Reference Standards , Reproducibility of Results , Sensitivity and Specificity , Soil Pollutants, Radioactive/standardsABSTRACT
The Institute for Reference Materials and Measurements participates in an IAEA co-ordinated project to upgrade Analytical Quality Control Services intercomparison materials to reference materials. The principal objective is to ensure that assigned property values are traceable to the International System of Units. General principles and practical mechanisms for achieving this traceability are described.
