Biosourced Vanillin-Based Building Blocks for Organic Electronic Materials.

Forest biomass is viewed as a significant source of organic carbon and thus the ideal replacement of petroleum products. From the resources derived from biomass, lignocellulose is the most abundant biobased material on earth. One of the aromatic added value compounds obtained from the depolymerization of lignin is vanillin. Here, we report the preparation of new compounds having benzothiophene, indole, isatin, benzofuroxan, benzofurazan, benzothiadiazole, and phthalimide heteroaromatic ring structures. More precisely, our results show that vanillin can be used as a biosourced starting material for the preparation of a variety of aromatic dibrominated monomers. X-ray crystallography on single crystals was also performed to obtain meaningful information on their solid-state ordering. This work opens the way to new, sustainable, biosourced aromatic materials (small molecules or polymers) for organic electronics.

Study of bandwidth effects in monochromator-based spectral responsivity measurements.

The errors caused by monochromator bandwidth in spectral responsivity measurements with a monochromator-based apparatus are discussed. Bandwidth effects are not negligible in high-accuracy cryogenic radiometer-based calibrations. A simple numerical method is used to calculate bandwidth effects for different types of detectors, monochromator slit scattering functions, and monochromator output spectral distributions. The method uses low-order Lagrange polynomials fitted segmentwise to measured spectral responsivity and monochromator spectral distribution data in order to make the calculations. It is shown that the shape of the slit function has only a small influence on the bandwidth errors, whereas the output spectral distribution of the monochromator can strongly affect bandwidth errors. It is also shown that in most cases the magnitude of bandwidth effects will vary as the square of the bandwidth. Bandwidth error calculations are presented for various types of detectors (silicon, silicon trap, germanium, InGaAs), for a V(X) detector, and for a typical filter radiometer. A comparison is made between calculated and measured bandwidth effects to validate the method used. In general, calculations of bandwidth effects will be mostly useful for determining uncertainties associated with monochromator bandwidth in spectral responsivity measurements; however, in certain cases the calculations can be used to apply corrections for such effects.