Transparent Molecular Adhesive Enabling Mechanically Stable ITO Thin Films.

With rapid advances in flexible electronics, transparent conductive electrodes (TCEs) have also been significantly developed as alternatives to the conventional indium tin oxide (ITO)-based material systems that exhibit low mechanical flexibility. Nanomaterial-based alternating materials, such as graphene, nanowire, and nanomesh, exhibit remarkable properties for TCE-based applications, such as high electrical conductivity, high optical transparency, and high mechanical stability. However, these nanomaterial-based systems lack scalability, which is a key requirement for practical applications, and exhibit a size-dependent property variation and inhomogeneous surface uniformity that limit reliable properties over a large area. Here, we exploited a conventional ITO-based material platform; however, we incorporated a transparent molecular adhesive, 4-aminopyridine (4-AP), to improve mechanical flexibility. While the presence of 4-AP barely affected optical transmittance and sheet resistance, it improved interfacial adhesion between the substrate and ITO as well as formed a wavy surface, which could improve the mechanical flexibility. Under various mechanical tests, ITO/4-AP/poly(ethylene terephthalate) (PET) exhibited remarkably improved mechanical flexibility as compared with that of ITO/PET. Furthermore, ITO/4-AP/PET was utilized for a flexible Joule heater application having spatial uniformity of heat generation, voltage-dependent temperature control, and mechanical flexibility under repeated bending tests. This molecular adhesive could overcome the current limitations of material systems for flexible electronics.

Five-minute synthesis of silver nanowires and their roll-to-roll processing for large-area organic light emitting diodes.

Silver (Ag) nanowires (NWs) are promising building blocks for flexible transparent electrodes, which are key components in fabricating soft electronic devices such as flexible organic light emitting diodes (OLEDs). Typically, Ag NWs have been synthesized using a polyol method, but it still remains a challenge to produce high-aspect-ratio Ag NWs via a simple and rapid process. In this work, we developed a modified polyol method and newly found that the addition of propylene glycol to ethylene glycol-based polyol synthesis facilitated the growth of Ag NWs, allowing the rapid production of long Ag NWs with high aspect ratios of about 2000 in a high yield (∼90%) within 5 min. Transparent electrodes fabricated with our Ag NWs exhibited performance comparable to that of an indium tin oxide-based electrode. With these Ag NWs, we successfully demonstrated the fabrication of a large-area flexible OLED with dimensions of 30 cm × 15 cm using a roll-to-roll process.

Curving silver nanowires using liquid droplets for highly stretchable and durable percolation networks.

Silver (Ag) nanowires (NWs) are promising building blocks for the fabrication of stretchable electrodes, but they may undergo mechanical fracture at low tensile strains, which leads to degradation in electrical performance of Ag NW-based stretchable electrodes. Here we report on a simple route to create the percolation networks of Ag NW rings via a conventional spray coating process. We discovered that Ag NWs can be bent into curved shapes within micrometer-sized liquid droplets generated during the spraying process due to elasto-capillary interaction. This curving phenomenon allowed the deposition of Ag NW rings directly on a desired substrate without the need for any complicated process. The network of Ag NW rings effectively releases the applied tensile strains thanks to curved shapes of the constituent NWs, enabling the achievement of excellent electromechanical stability as well as high stretchability. Our approach not only provides a simple, low cost, and scalable route to the fabrication of high-performance Ag NW-based stretchable electrodes, but also opens a new and useful way of engineering the structure of NWs for various applications.

Organic-Stabilizer-Free Polyol Synthesis of Silver Nanowires for Electrode Applications.

The polyol reduction of a Ag precursor in the presence of an organic stabilizer, such as poly(vinylpyrrolidone), is a widely used method for the production of Ag nanowires (NWs). However, organic capping molecules introduce insulating layers around each NW. Herein we demonstrate that Ag NWs can be produced in high yield without any organic stabilizers simply by introducing trace amounts of NaCl and Fe(NO3 )3 during low-temperature polyol synthesis. The heterogeneous nucleation and growth of Ag NWs on initially formed AgCl particles, combined with oxidative etching of unwanted Ag nanoparticles, resulted in the selective formation of long NWs with an average length of about 40 µm in the absence of a capping or stabilizing effect provided by surface-adsorbing molecules. These organic-stabilizer-free Ag NWs were directly used for the fabrication of high-performance transparent or stretchable electrodes without a complicated process for the removal of capping molecules from the NW surface.