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1.
Chem Commun (Camb) ; 59(26): 3882-3885, 2023 Mar 28.
Article in English | MEDLINE | ID: mdl-36916636

ABSTRACT

We report a novel reaction of the recently discovered family of fullerene derivatives C1-C60Ar5Th' with thiophene derivatives Th''H yielding a previously unknown family of C1-C60Ar5Th'Th''H compounds with three different types of functional aromatic addends attached to the carbon cage. The discovered reaction paves a way to the synthesis of novel C60 fullerene derivatives with promising antioxidant and antiviral properties.

2.
Org Lett ; 23(18): 7226-7230, 2021 09 17.
Article in English | MEDLINE | ID: mdl-34468156

ABSTRACT

Here we report a reaction of the fullerene derivatives C60Ar5Cl, which enables the substitution of Cl with thiophene residues and the formation of the novel family of C1-symmetrical C60 fullerene derivatives with six functional addends C60Ar5Th. The discovered reaction provided a straightforward approach to the synthesis of previously inaccessible multifunctional water-soluble fullerene derivatives, including the compounds with antiviral activity against human immunodeficiency and influenza viruses.


Subject(s)
Antiviral Agents/chemistry , Fullerenes/chemistry , Thiophenes/chemistry , Antiviral Agents/pharmacology , Humans , Molecular Structure , Water/chemistry
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