Hydrochemistry and weathering at Pardo River basin, São Paulo State, Brazil.

This work was conducted at the Pardo River hydrographic basin, which is a federal watershed belonging to the Paranapanema River hydrographic basin (PRHB) in Brazil (São Paulo State and Paraná State). The aim was to realize an integrated hydrochemical and radiometric (U-isotopes and 210Po) approach, highlighting the water/soil-rock and surface water/groundwater interactions, with implications to the weathering processes occurring there. The study area has been often considered one of the best preserved/unpolluted river in São Paulo State, contributing to the water supply of several cities distributed along its banks. However, the results reported here suggest possible lead diffuse pollution caused by the use of phosphate fertilizers in agricultural activities taking place in the basin. The analyzed groundwaters and surface waters tend to be neutral to slightly alkaline (pH of 6.8-7.7), possessing low mineral concentration (total dissolved solids up to 500 mg/L). SiO2 is the major dissolved constituent in the waters, while bicarbonate is the dominant anion, and calcium is the preponderant cation. The effects of the weathering of silicates to control the dissolution of constituents in the liquid phase have been identified from some diagrams often utilized in hydrogeochemical studies. Chemical weathering rates have been estimated from hydrochemical data associated to analytical results of the natural uranium isotopes 238U and 234U concerning to samples of rainwater and Pardo River waters. The fluxes in this watershed are permitted to obtain the following rates: 11.43 t/km2 year (sodium), 2.76 t/km2 year (calcium), 3.17 t/km2 year (magnesium), 0.77 t/km2 year (iron), and 8.64 t/km2 year (uranium). This new dataset constitutes valuable information for people engaged on the management of the Pardo River watershed, as well as to researchers interested on comparative studies considering the available data from other basins worldwide.

Comparative analysis of gamma ray spectrometers applied to Irati Formation, Paraná basin, São Paulo State, Brazil.

This paper describes the use of gamma ray spectrometry in the study of rock samples from the Irati Formation, Paraná sedimentary basin, São Paulo State, Brazil. This technique allowed to measure the natural radiation emitted by 40K, as well the radionuclides belonging to the decay series of 238U (eU = 226Ra = 214Bi) and 232Th (eTh = 228Th = 208Tl) which occur in the analyzed samples. Four gamma ray spectrometers have been utilized for comparing the results obtained: a portable sodium iodide [NaI(Tl)] scintillation detector (Digidart), a handheld bismuth germanate oxide (BGO) detector and two bench NaI(Tl) crystals, differing in their geometry (Planar and Well types). This study involved the calibration of the spectrometers, except in the case of the BGO that is factory calibrated. Afterwards, gamma ray analysis was done for 122 rock samples colleted at Partecal Quarry located at Assistência District, Rio Claro city, which have been of interest for the oil and gas sector. For comparison purposes, the obtained datasets were subjected to different statistical tests, including the analysis of variance (ANOVA) that proved to be of great value for checking the differences of the mean concentration values of eU, eTh and K. The results pointed out several factors that affect the gamma ray analysis for the natural radioelements uranium, thorium, and potassium such as the samples size, shape and geometry, detector type, shielding and counting time. These factors are of difficult control in order to get reliable radiometric measurements by this technique.

U-isotopes and weathering rates in watersheds of Araxá city, Minas Gerais State, Brazil.

This work was conducted at Araxá city, Minas Gerais State, Brazil. The aim was to characterize by different approaches weathering rates at six watersheds occurring there. The study area is well-known in the country due to economic and touristic reasons. Beginning in the 1960's and 1970's, nowadays huge mining activities for niobium and phosphate fertilizer exploitation by different companies are taking place there along with the use of natural mineral waters for health treatment, following a tradition that started in the 19th century for tuberculosis treatment. The dataset utilized in this investigation comprised results obtained in the analysis of distinct geochemical compartments, i.e. rocks, soils, bottom sediments, rainwater and surface waters from small hydrographic basins. The waters of three catchments are extensively used by water-supply systems of Araxá city in order to meet the demand of this resource as a possible supply of drinking water for the local community. Hydrochemical (major and trace constituents) and radionuclides (238U, 234U, and 210Po) analyses of rainwater and water bodies samples allowed estimates of the fluxes in each drainage. These fluxes were subtracted from rainfall deposition, yielding positive net values only for bicarbonate and U-isotopes as natural tracers in all watersheds, which allowed to calculate chemical weathering rates of 2.6-38.9 ton/km2yr (bicarbonate) and 0.09-19.8 ton/km2yr (U-isotopes). Physical weathering rates were obtained from 210Pb data in bottom sediments and exceeded 200 to 1.3 × 105 times the chemical weathering rates evaluated by the U-isotopes approach, a finding compatible with others reported in literature but adopting a diverse conceptual framework. Thus, the development of all analytical protocols along this investigation permitted an integrated appraisal of distinct approaches applied to the same selected site, as well as a comparison of weathering rates with other values reported in the literature, improving the knowledge about this subject in Araxá city watersheds. The novel dataset reported in this paper constitutes an aid to the already existing number of weathering rates elsewhere, helping modellers engaged on predicting future landscape changes.

Sedimentation rates by the 210Pb chronological method in Itanhaém river watershed, southeast Brazil.

The historical variation of sedimentation rate was investigated in five cores collected from the Itanhaém watershed main rivers, the second largest coastal watershed of the São Paulo state, Brazil, using the lead-210 radioisotope as a geochronometer. The main characteristics of the rivers' waters and sediments were determined in order to support the geochronological analysis results and associate sediments with possible source areas. In this context, the fluvial waters' general classification indicated the facies sulfated or chlorinated sodium in the winter and summer seasons, except for the Branco river waters in summer, which were classified as calcium or magnesium bicarbonate. A longitudinal salinity gradient was found in the downstream river courses, under greater marine influence, with the ions Cl-, Na+, SO42+, Mg2+, Ca2+, and K+ being most common in the waters. Silica is the predominant constituent in the sediment cores and is inversely related to the organic matter (OM) presence. Inverse correlations were also found between silica and other constituents. The watershed sedimentation rates were determined in the range of 0.31 up to 3.97 g/cm2/year and 0.30 up to 3.40 cm/year, highlighting the core extracted from Branco river, which showed the highest sedimentation rate. The profiles corresponding to Preto and Aguapeú rivers presented discontinuities in the sedimentation rates. The discontinuities were dated and would probably be related to the anthropic activities, which intensified in the municipality of Itanhaém around the middle of the twentieth century.

Tracking pollutants in selected Brazilian drainages from araxá city.

Sediments geochemical data from Araxá city, Minas Gerais State, Brazil, have provided new insights on the pollutants inputs in different drainage systems of Araxá city, Minas Gerais State, Brazil. The sediments profiles (6) provided from a lake (Grand Hotel) and streams (Sal, Areia, Fundo, and Feio). The local municipality uses some waters (Areia, Fundo, and Feio streams) in water-supply systems. Because of the Brazilian environmental agency does not establish concentration guidelines for several heavy metals occurring in freshwater sediments, the values reported in this paper were compared with limits proposed elsewhere. Enrichment Factor (EF) values of 20-40 (very high enrichment) and EF > 40 (extremely high enrichment) were found for Ba (in two sediment core), Nb (in three sediment core) and Se (in four sediment core). The 210Pb chronological method was useful for tracking some major events that occurred in the history of Araxá city, showing concentration peaks around 1962 and 1993 for BaO, Nb2O5, Fe2O3, P2O5, SO3, SrO and CeO2 and around 1972 and 1999 for SeO2.

Nitrate-dependent Uranium mobilisation in groundwater.

Nitrate is a critical substance that determines the prevailing redox conditions in groundwater, and in turn the behaviour of Uranium (U). Therefore, the excessive use of nitrate-fertiliser in agricultural catchments could exert a significant influence on U mobilisation. This is a significant issue in catchments, where groundwater resources are increasingly being exploited for drinking water production. Past studies on U mobility in groundwater have considered individual hydro-geochemical factors influencing U concentrations, rather than as a single system with multiple factors. This research study investigated nitrate-dependent U mobility within a catchment in Brazil, where a range of intensive agricultural activities are undertaken and the giant Guarani aquifer is located. The study used direct measurements of groundwater redox conditions and other hydro-geochemical parameters. The research outcomes indicated that U could have two hydro-geochemical systems based on positive and negative redox potential of groundwater. The pH, HCO3- and temperature pose the largest influence, respectively, on U mobilisation, and these impacts are greater in agricultural lands than urban areas. Acidic and less reducing (positive redox) groundwater across the aquifer and basic and highly reducing (negative redox) groundwater in agricultural areas make U more mobile. The alkalinity increases U mobility in less reducing groundwater across the aquifer and in highly reducing groundwater in agricultural areas. Further, U can be mobile in hot and less reducing groundwater across the aquifer, but hot and highly reducing groundwater in agricultural areas can limit U mobility. More importantly, the study revealed that U can be mobile under high NO3- concentrations in reducing groundwater in non-agricultural areas. However, anthropogenic inputs of NO3- are expected to be lower than natural NO3- inputs in areas where the groundwater is highly reducing. Hence, fertiliser use in agricultural lands is less likely to increase U mobility in highly reducing groundwater.

Gross alpha/beta radioactivity and radiation dose in thermal and non-thermal spas groundwaters.

Gross alpha and gross beta activities have been determined in thermal and non-thermal spas groundwaters (75) occurring at São Paulo and Minas Gerais states in Brazil as they are ingested in public places, bottled and used for bathing purposes, among other. The samples provided from springs and pumped tubular wells drilled at different aquifer systems inserted in Paraná and Southeastern Shield hydrogeological provinces. The WHO guideline reference value proposed in 2011 for the drinking water quality was never reached for the gross alpha activity (0.5 Bq/L) but it was exceeded in 13 groundwater samples for the gross beta activity (1 Bq/L). Available activity concentration data of the natural radionuclides 40K, 228Ra (232Th-daughter), 238U and descendants (234U, 226Ra, 222Rn, 210Pb, 210Po) allowed calculate the total Committed Effective Dose (CED) based on a drinking water ingestion rate of 2 L/day. The WHO reference level of 0.1 mSv per year for the CED was surpassed in a high number of water sources (62 (83%) or 41 (55%), disregarding radon), denoting the relevance of the radiological surveys detailing as much as possible the dissolved radionuclides present in potable waters, despite the analytical difficulties and costs involved.

Assessing mercury pollution in Amazon River tributaries using a Bayesian Network approach.

Mercury pollution of water bodies exerts significant human and ecosystem health impacts due to high toxicity. Relatively high levels of mercury have been detected in the Amazon River and its tributaries and associated lakes. The study employed a Bayesian Network approach to investigate the contribution from geogenic sources to mercury pollution of lakes in the Madeira River basin, which is the largest tributary of the Amazon River. It was found that the source indicators of naturally occurring mercury have both, positive and negative relationships with mercury in lake sediments. Although the positive relationships indicated the influence of geological and soil formations, the negative relationships implied that the use of mercury amalgam for gold extraction in artisanal and small-scale mining (ASM), which is the primary anthropogenic source of mercury, also contribute to mercury in Amazon tributaries. This was further evident as mercury concentrations in lake sediments were found to be significantly higher than those in the surrounding rocks. However, potential anthropogenic mercury was attributed to historical inputs from gold mining due to the recent decline of ASM mining practice in the region.

The application of U-isotopes to assess weathering in contrasted soil-water regime in Brazil.

This paper presents the use of U-series radionuclides 238U and 234U to evaluate the biogeochemical disequilibrium in soil cover under a contrasted soil-water regime. The approach was applied in three profiles located in distinct topographical positions, from upslope ferralitic to downslope hydromorphic domain. The U fractionation data was obtained in the samples representing the saprolite and the superficial and subsuperficial soil horizons. The results showed a significant and positive correlation between U and the Total Organic Carbon (TOC). Soil organic matter has accumulated in soil due to hydromorphy. There is no evidence of positive correlation between U and Fe, as expected in lateritic soils. The advance of the hydromorphy on Ferralsol changes the weathering rates, and the ages of weathering are discussed as a function of the advance of waterlogged soil conditions from downslope. Also, the bioturbation could represent the other factor responsible to construct a more recent soil horizon.

Natural radionuclides in plants, soils and sediments affected by U-rich coal mining activities in Brazil.

Mining activities can increase the mobility of metals by accelerating the dissolution and leaching of minerals from the rocks and tailing piles to the environment and, consequently, their availability for plants and subsequent transfer to the food chain. The weathering of minerals and the disposal of coal waste in tailing piles can accelerate the generation of acid mine drainage (AMD), which is responsible for the higher dissolution of metals in mining areas. In this context, the behavior of U, Th and K in soils and sediment, and the transfer factor (TF) of 238U, 234U and 210Po for soybean, wheat, pine and eucalyptus cultivated around a coal mine in southern Brazil was evaluated. Alpha and gamma spectrometry were used for the measurements of the activity concentration of the radioelements. 210Po was the radionuclide that is most accumulated in the plants, especially in the leaves. When comparing the plant species, pine showed the highest TF values for 234U (0.311 ± 0.420) for leaves, while eucalyptus showed the highest TF for 238U (0.344 ± 0.414) for leaves. In general, TF were higher for the leaves of soybean and wheat when compared to the grains, and grains of wheat showed higher TF for 210Po and 238U than grains of soybean. Deviations from the natural U isotopic ratio were recorded at all investigated areas, indicating possible industrial and mining sources of U for the vegetables. A safety assessment of transport routes and accumulation of radionuclides in soils with a potential for cultivation is important, mainly in tropical areas contaminated with solid waste and effluents from mines and industry.

Mobility indices and doses from 210Po and 210Pb activity concentrations data in Brazilian spas groundwaters.

210Po and 210Pb activity concentrations in spas groundwaters occurring at São Paulo (SP) and Minas Gerais (MG) states, Brazil, have been reported in this paper with a dual purpose: to compare different indices for evaluating the radionuclides mobility into waters and to evaluate the drinking water quality from dose calculations. The waters (75 sampling points) are extensively used for drinking in public places, bottling and bathing purposes, among other. The samples were taken from springs and wells drilled at different aquifer systems inserted in Paraná and Southeastern Shield hydrogeological provinces. The WHO guideline reference value for 210Pb and 210Po of 0.1 Bq/L in drinking water was not reached for 210Pb but the 210Po levels were equal or above it in four spas groundwaters from MG State. The maximum WHO guidance dose level of 0.1 mSv/yr was also reached or surpassed in them. The 210Pb "mobility index" taking into account the ratio of the weight of the dissolved 210Pb per unit volume of solution to its weight per unit weight of the rock matrix yielded values in the range of 0.01-5.2 kg/m3. Another "mobility index" (Preference Ratio) expressing the ratio of 210Pb and 238U in the waters divided by the ratio of 210Pb and 238U in the rock matrices provided values between 0.004 and 7994. The 210Pb/238U activity ratios of some spas groundwaters suggested preferential 238U transport relative to 210Pb into the liquid phase, whereas the ratio of the 210Pb to 238U mobility indices indicated the opposite. Such finding showed a better usefulness of the mobility indices for evaluating processes affecting the radionuclides release into the liquid phase during the water/rock interactions.

The dissolved uranium concentration and 234U/238U activity ratio in groundwaters from spas of southeastern Brazil.

This paper describes the natural radioactivity due to 238U and 234U in 75 water sources from spas located in 14 municipalities in São Paulo and Minas Gerais states, Brazil. These waters are extensively utilized for drinking in public places, bottling and bathing purposes, among other uses. The water samples were taken from springs and pumped tubular wells drilled into different aquifer systems in the Paraná and Southeastern Shield hydrogeological provinces. The measurements of alpha-emitting radionuclides were also accompanied by the monitoring of temperature, pH, Eh, electrical conductivity, dissolved gases (O2, CO2, H2S, radon, thoron) and major constituents. The dissolved U concentration data were lognormally distributed. The median and mean values corresponded to 0.02 and 0.09 µg/L, respectively. Significant relationships were found among the 234U/238U activity ratio (AR) of dissolved uranium, the total dissolved solids (TDS) and dissolved bicarbonate contents, and also between the AR and dissolution rate in the monitored sites. The logU versus AR diagram used for the hydrogeochemical prospecting of concealed U deposits indicated that the water sources were mainly from reduced environments. The possibility of using the reciprocal of the dissolved U concentration and AR data to determine mixing volumes of different groundwater masses was demonstrated. The highest dissolved U concentration (4.82 µg/L) was well below the maximum allowed by WHO.

Weathering processes and dating of soil profiles from São Paulo State, Brazil, by U-isotopes disequilibria.

This study reports the use of the U-series radionuclides 238U and 234U for dating two soil profiles. The soil horizons developed over sandstones from Tatuí and Pirambóia formations at the Paraná sedimentary basin, São Paulo State, Brazil. Chemical data in conjunction with the 234U/238U activity ratios (AR's) of the soil horizons allowed investigating the U-isotopes mobility in the shallow oxidizing environment. Kaolinization and laterization processes are taking place in the profiles sampled, as they are especially common in regions characterized by a wet and dry tropical climate and a water table that is close to the surface. These processes are implied by inverse significant correlations between silica and iron in both soil profiles. Iron oxides were also very important to retain uranium in the two sites investigated, helping on the understanding of the weathering processes acting there. 238U and its progeny 234U permitted evaluating the processes of physical and chemical alteration, allowing the suggestion of a possible timescale corresponding to the Middle Pleistocene for the development of the more superficial soil horizons.

Natural radionuclides in lichens, mosses and ferns in a thermal power plant and in an adjacent coal mine area in southern Brazil.

The radio-elements 234U, 235U, 238U, 230Th, 232Th and 210Po were characterized in lichens, mosses and ferns species sampled in an adjacent coal mine area at Figueira City, Paraná State, Brazil, due to their importance for the assessment of human exposure related to the natural radioactivity. The coal is geologically associated with a uranium deposit and has been used as a fossil fuel in a thermal power plant in the city. Samples were initially prepared at LABIDRO (Isotopes and Hydrochemistry Laboratory), UNESP, Rio Claro (SP), Brazil. Then, alpha-spectrometry after several radiochemical steps was used at the Applied Nuclear Physics Laboratories, University of Seville, Seville, Spain, for measuring the activity concentration of the radionuclides. It was 210Po the radionuclide that most bio-accumulates in the organisms, reaching the highest levels in mosses. The ferns species were less sensitive as bio-monitor than the mosses and lichens, considering polonium in relation to other radionuclides. Fruticose lichens exhibited lower polonium content than the foliose lichens sampled in the same site. Besides biological features, environmental characteristics also modify the radio-elements absorption by lichens and mosses like the type of vegetation covering these organisms, their substrate, the prevailing wind direction, elevation and climatic conditions. Only 210Po and 238U correlated in ferns and in soil and rock materials, being particulate emissions from the coal-fired power plant the most probable U-source in the region. Thus, the biomonitors used were able to detect atmospheric contamination by the radionuclides monitored.

Hydrogeochemical features of surface water and groundwater contaminated with acid mine drainage (AMD) in coal mining areas: a case study in southern Brazil.

Effects of acid mine drainage (AMD) were investigated in surface waters (Laranjinha River and Ribeirão das Pedras stream) and groundwaters from a coal mining area sampled in two different seasons at Figueira city, Paraná State, Brazil. The spatial data distribution indicated that the acid effluents favor the chemical elements leaching and transport from the tailings pile into the superficial water bodies or aquifers, modifying their quality. The acid groundwaters in both sampling periods (dry: pH 2.94-6.04; rainy: pH 3.25-6.63) were probably due to the AMD generation and infiltration, after the oxidation of sulfide minerals. Such acid effluents cause an increase of the solubilization rate of metals, mainly iron and aluminum, contributing to both groundwater and surface water contamination. Sulfate in high levels is a result of waters' pollution due to AMD. In some cases, high sulfate and low iron contents, associated with less acidic pH values, could indicate that AMD, previously generated, is nowadays being neutralized. The chemistry of the waters affected by AMD is controlled by the pH, sulfide minerals' oxidation, oxygen, iron content, and microbial activity. It is also influenced by seasonal variations that allow the occurrence of dissolution processes and the concentration of some chemical elements. Under the perspective of the waters' quality evaluation, the parameters such as conductivity, dissolved sodium, and sulfate concentrations acted as AMD indicators of groundwaters and surface waters affected by acid effluents.

(210)Pb and compositional data of sediments from Rondonian lakes, Madeira River basin, Brazil.

Gold exploration has been intensive in Brazilian Amazon over the last 40 years, where the use of mercury as an amalgam has caused abnormal Hg concentrations in water bodies. Special attention has been directed to Madeira River due to fact it is a major tributary of Amazon River and that since 1986, gold exploration has been officially permitted along a 350km sector of the river. The (21)(0)Pb method has been used to date sediments taken from nine lakes situated in Madeira River basin, Rondônia State, and to verify where anthropogenic Hg might exist due to gold exploitation in Madeira River. Activity profiles of excess (21)(0)Pb determined in the sediment cores provided a means to evaluate the sedimentation rates using a Constant Flux: Constant Sedimentation (CF:CS) and Constant Rate of Supply (CRS) of unsupported/excess (21)(0)Pb models. A significant relationship was found between the CF:CS sedimentation rates and the mean values of the CRS sedimentation rates (Pearson correlation coefficient r=0.59). Chemical data were also determined in the sediments for identifying possible relationships with Hg occurring in the area. Significant values were found in statistical correlation tests realized among the Hg, major oxides and Total Organic Carbon (TOC) content in the sediments. The TOC increased in the sediment cores accompanied by a loss on ignition (LOI) increment, whereas silica decreased following a specific surface area raising associated to the TOC increase. The CRS model always provided ages within the permitted range of the (21)(0)Pb-method in the studied lakes, whereas the CF:CS model predicted two values above 140 years.

Uranium isotopes in groundwater occurring at Amazonas State, Brazil.

This paper reports the behavior of the dissolved U-isotopes (238)U and (234)U in groundwater providing from 15 cities in Amazonas State, Brazil. The isotope dilution technique accompanied by alpha spectrometry were utilized for acquiring the U content and (234)U/(238)U activity ratio (AR) data, 0.01-1.4µgL(-1) and 1.0-3.5, respectively. These results suggest that the water is circulating in a reducing environment and leaching strata containing minerals with low uranium concentration. A tendency to increasing ARs values following the groundwater flow direction is identified in Manaus city. The AR also increases according to the SW-NE directions: Uarini→Tefé; Manacapuru→Manaus; Presidente Figueiredo→São Sebastião do Uatumã; and Boa Vista do Ramos→Parintins. Such trends are possibly related to several factors, among them the increasing acid character of the waters. The waters analyzed are used for human consumption and the highest dissolved U content is much lower than the maximum established by the World Health Organization. Therefore, in view of this radiological parameter they can be used for drinking purposes.

Dissolved uranium, radium and radon evolution in the Continental Intercalaire aquifer, Algeria and Tunisia.

Natural, dissolved (238)U-series radionuclides (U, (226)Ra, (222)Rn) and activity ratios (A.R.s: (234)U/(238)U; (228)Ra/(226)Ra) in Continental Intercalaire (CI) groundwaters and limited samples from the overlying Complexe Terminal (CT) aquifers of Algeria and Tunisia are discussed alongside core measurements for U/Th (and K) in the contexts of radiological water quality, geochemical controls in the aquifer, and water residence times. A redox barrier is characterised downgradient in the Algerian CI for which a trend of increasing (234)U/(238)U A.R.s with decreasing U-contents due to recoil-dominated (234)U solution under reducing conditions allows residence time modelling ∼500 ka for the highest enhanced A.R. = 3.17. Geochemical modelling therefore identifies waters towards the centre of the Grand Erg Oriental basin as palaeowaters in line with reported (14)C and (36)Cl ages. A similar (234)U/(238)U trend is evidenced in a few of the Tunisian CI waters. The paleoage status of these waters is affirmed by both noble gas recharge temperatures and simple modelling of dissolved, radiogenic (4)He-contents both for sampled Algerian and Tunisian CI and CT waters. For the regions studied these waters therefore should be regarded as "fossil" waters and treated effectively as a non-renewable resource.

(222)Rn, (220)Rn and other dissolved gases in mineral waters of southeast Brazil.

This paper describes the natural radioactivity due to (222)Rn and (220)Rn in mineral waters occurring at São Paulo and Minas Gerais states, Brazil, that are extensively used for drinking in public places, bottling and bathing purposes, among other. The measurements of these alpha-emitting radionuclides were also accompanied by the monitoring of temperature and some dissolved gases (O2, CO2 and H2S) in 75 water sources located in 14 municipalities of those states. Eight water sources yielded (220)Rn activity concentration values below the detection limit of 4 mBq/L. On other hand, (222)Rn activity concentration values exceeding the WHO guidance level of 100 Bq/L in drinking-water for public water supplies were found in two springs, named Villela and Dona Beja, whose discharge occurs in areas characterized by the presence of enhanced levels of natural radioelements in rocks. The obtained results were compared with the guidelines of the Brazilian Code of Mineral Waters (BCMW) that was established in 1945 and is still in force in the country. The (222)Rn and (220)Rn activity concentration data allowed perform dose radiation calculations based on the potential alpha energy concentration (PAEC), whose implications for health risk have been also considered in this paper.

Natural radionuclides in major aquifer systems of the Paraná sedimentary basin, Brazil.

This paper describes the natural radioactivity of groundwater occurring in sedimentary (Bauru and Guarani) and fractured rock (Serra Geral) aquifer systems in the Paraná sedimentary basin, South America that is extensively used for drinking purposes, among others. The measurements of gross alpha and gross beta radioactivity as well the activity concentration of the natural dissolved radionuclides 4°K, ²³8U, ²³4U, ²²6Ra, ²²²Rn, ²¹°Po and ²¹°Pb were held in 80 tubular wells drilled in 21 municipalities located at São Paulo State and its border with Mato Grosso do Sul State in Brazil. Most of the gross alpha radioactivity data were below 1 mBq/L, whereas values exceeding the gross beta radioactivity detection limit of 30 mBq/L were found. The radioelement solubility in the studied systems varied according to the sequence radon>radium>other radionuclides and the higher porosity of sandstones relatively to basalts and diabases could justify the enhanced presence of dissolved radon in the porous aquifer. The implications of the data obtained in terms of standards established for defining the drinking water quality have also been discussed. The population-weighted average activity concentration for these radionuclides was compared to the guideline value of 0.1 mSv/yr for the total effective dose and discussed in terms of the choice of the dose conversion factors.