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Int J Biol Macromol ; 179: 366-376, 2021 May 15.
Article in English | MEDLINE | ID: mdl-33647339

ABSTRACT

A new alternative aerogel was prepared from low-cost chitin and psyllium biopolymers to adsorb crystal violet (CV) dye from liquid media and possibly treat effluents containing other dyes. The aerogel was characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM), which demonstrated that aerogel has a typical structure of amorphous materials and presented a randomly interconnected porous structure that resembles an open pore network. 2.5 g L-1 of aerogel was able to remove 86.00% of CV from solutions, and the natural pH of the CV solution was considered the more adequate for adsorption. The pseudo-second-order (PSO) model satisfactorily described the adsorption kinetics, and the Freundlich model was suitable to represent the adsorption equilibrium. The maximum experimental capacity achieved was 227.11 mg g-1, which indicates that aerogel is very efficient and competitive with several adsorbents. Tests using a simulated effluent showed that aerogel has excellent potential to treat real colored effluents.


Subject(s)
Chitin/chemistry , Coloring Agents/chemistry , Gentian Violet/isolation & purification , Psyllium/chemistry , Water Pollutants, Chemical/isolation & purification , Water Purification/methods , Adsorption , Kinetics , Porosity , Thermodynamics , Water/chemistry
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