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Ultrason Sonochem ; 15(4): 289-293, 2008 Apr.
Article in English | MEDLINE | ID: mdl-18065254

ABSTRACT

Asymmetric transfer hydrogenation of ketones using Ru(II)arene/amino alcohol catalyst system proceeds with significant rate enhancement by ultrasound promotion. Comparison of the silent reactions carried out at 25 degrees C with reactions under sonochemical activation at 25 degrees C clearly showed enhancement in catalytic activity by 5-10 times without significantly affecting the enantioselectivity.


Subject(s)
Amino Alcohols/chemistry , Ketones/chemistry , Ketones/radiation effects , Ruthenium Compounds/chemistry , Catalysis , Chromatography, High Pressure Liquid , Gas Chromatography-Mass Spectrometry , Hydrogenation/radiation effects , Indicators and Reagents , Kinetics , Stereoisomerism
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