ABSTRACT
In addition to fertilisers, plant protection products are essential in today's agricultural production. The increase in the human population leads to the need to optimise agricultural production, with an increasing demand for plant protection products. Historically, there have been serious fires at plant protection product storage facilities with devastating consequences for the environment. For this reason, it is worth investigating what risks arise for people and the environment during a fire at storage sites for these substances. In this article, tests were carried out for three plant protection products containing azoxystrobin as the active substance, in order to investigate the effects of the additives on combustion processes. Tests of combustion parameters were performed using a cone calorimeter. A tube furnace with asphyxiating and irritant gas analysers and gas chromatography with a mass spectrometer were used to analyse the resulting gas products. The Plant Protection Products tested achieved high values for combustion parameters. Analysis of the substances produced during their combustion showed that large amounts of asphyxiating and irritating gases (CO, N2O, NO, SO2, NH3, HCl, CH2O, HCN) were generated.
Subject(s)
Fires , Gases , HumansABSTRACT
This study provides valuable data on the specific toxic products that could be released from the commercially used, flexible polyurethane foams (FPUFs) during a fire. The steady-state tube furnace (Purser furnace) was used to generate combustion and thermal degradation products under different fire conditions. The concentrations of asphyxiates and irritant gases were determined using a Fourier transform infrared spectroscopy gas analyser. The volatile and semi-volatile organic compounds released in the fire effluents were collected using the solid-phase microextraction technique and identified by gas chromatography with a mass selective detector. In addition, the thermal stability of the FPUFs was evaluated by simultaneous thermal analysis. The cone calorimetry test was used to determine the flame retardancy of the selected materials. The obtained results show that the emission of carbon monoxide and hydrogen cyanide during the thermal degradation and combustion of the tested foams exceeded the permissible values and pose a serious threat to human life and health. Moreover, substituted benzenes, aldehydes, and polycyclic hydrocarbons were found in the released gases during all of the test conditions.
ABSTRACT
The influence of plant fillers on the flammability and smoke emission of natural composites was investigated. Epoxy composites with 15, 25, and 35 wt % of walnut and hazelnut shell, as well as sunflower husk, were prepared and examined. The ground organic components were characterized by grain size distribution, thermogravimetric analysis (TGA) and microstructure observations (SEM). The composite materials were subjected to dynamic mechanical analysis (DMA) and structural evaluation with scanning electron microscopy. Cone calorimeter tests and TGA determined the influence of plant waste filler addition on thermal stability and flammability. Moreover, the semi-volatile and volatile compounds that evolved during the thermal decomposition of selected samples were identified using a steady state tube furnace and a gas chromatograph with a mass spectrometer. The intensity of the degradation reduced as a function of increasing filler content, while the yield of residue corresponded to the amount of lignin that is contained in the tested plants. Moreover, the incorporation of agricultural waste materials resulted in the formation of a char layer, which inhibits the burning process. The yield of char depended on the amount and type of the filler. The composites containing ground hazelnut shell formed swollen char that was shaped in multicellular layers, similar to intumescent fire retardants.
