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1.
Phys Rev Lett ; 107(2): 027001, 2011 Jul 08.
Article in English | MEDLINE | ID: mdl-21797633

ABSTRACT

The electrical transport properties of ultrathin YBa2Cu3O(7-x) films have been modified using an electric double layer transistor configuration employing an ionic liquid. A clear evolution from superconductor to insulator was observed in nominally 7 unit-cell-thick films. Using a finite size scaling analysis, curves of resistance versus temperature, R(T), over the temperature range from 6 to 22 K were found to collapse onto a single scaling function, which suggests the presence of a quantum critical point. However, the scaling fails at the lowest temperatures indicating the possible presence of an additional phase between the superconducting and insulating regimes.

2.
ACS Nano ; 5(2): 1253-8, 2011 Feb 22.
Article in English | MEDLINE | ID: mdl-21271739

ABSTRACT

We report a new, simple, hydrazine-free, high-yield method for producing single-layer graphene sheets. Graphene sheets were formed from graphite oxide by reduction with simple deionized water at 95 °C under atmospheric pressure. Over 65% of the sheets are single graphene layers; the average sheet diameter is 300 nm. We speculate that dehydration of graphene oxide is the main mechanism for oxygen reduction and transformation of C-C bonds from sp(3) to sp(2). The reduction appears to occur in large uniform interconnected oxygen-free patches so that despite the presence of residual oxygen the sp(2) carbon bonds formed on the sheets are sufficient to provide electronic properties comparable to reduced graphene sheets obtained using other methods.

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