Efficient removal of Cr (VI) and Co (II) from aqueous solution by activated carbon from Manihot esculenta Crantz agricultural bio-waste.

Heavy metals are one of the most dangerous and critical threats to human and environment. In this study, the adsorption efficiency of activated carbon from cassava peels considered as agricultural waste (CPR) was evaluated for removal of heavy metals Cr (VI) and Co (II) from aqueous media. Cassava peel carbon (CPC) was obtained by acid treatment. Structural and morphological properties were investigated using Fourier Transform Infra-Red (FTIR), Scanning Electron Microscopy (SEM), Brunauer-Emmet-Teller surface area (BET) and X-Ray Diffraction (XRD). The adsorption experiments were conducted in batch mode under natural solution pH and complexation of the heavy metals, which allows the use of UV-Visible spectroscopy technique. CPC adsorbent exhibited a high adsorption capacity, according to Langmuir model, for Cr (VI) (166.35 mg/g) and Co (II) (301.63 mg/g) at 25 °C. Kinetic and adsorption isotherms followed the pseudo second-order and Langmuir isotherm models for both metals, respectively. Thermodynamic study confirmed the spontaneity and endothermic nature of both metals adsorption onto CPC surface.

Low-level environmental exposure to lead and renal adverse effects: a cross-sectional study in the population of children bordering the Mbeubeuss landfill near Dakar, Senegal.

This study deals with the health effects within a child population, neighbouring a landfill. After detecting metals in soil and air samples collected in the surroundings of the landfill and in a control site, we have studied: (i) levels of lead (Pb) and exposure biomarkers in blood and urine, (ii) oxidative stress biomarkers and (iii) renal injury by applying a set of early effect biomarkers. Levels of Pb were higher in the exposed site (i.e. 1129 mg/kg and 640 ng/m(3) in soil and air samples, respectively) versus those in the control site (i.e. 14.3 mg/kg and 9.3 ng/m(3) in soil and air samples, respectively). Pb impregnation and levels of delta-aminolevulinic acid in urine were influenced by the living site that shows the prevailingly alarming situation in the Mbeubeuss landfill. Malondialdehyde changes indicated Pb-induced excessive production of reactive oxygen species. Lactate dehydrogenase activities and proteinuria were found to be higher in the children living in the exposed site. These evidences may reveal the usefulness of these two effect biomarkers to monitor the kidney injury entailed by relatively low-environmental exposure to Pb. Overall, these results show that the Mbeubeuss landfill constitutes a real source of environmental and health risk, be it living or working on site, of the surrounding population, predominantly for children.