Groundwater quality: Global threats, opportunities and realising the potential of groundwater.

Groundwater is a critical resource enabling adaptation due to land use change, population growth, environmental degradation, and climate change. It can be a driver of change and adaptation, as well as effectively mitigate impacts brought about by a range of human activities. Groundwater quality is key to assessing groundwater resources and we need to improve our understanding and coverage of groundwater quality threats if we are to use groundwater sustainably to not further burden future generations by limiting resources and/or increasing treatment or abstraction costs. Good groundwater quality is key to progress on a range of Sustainable Development Goals, but achievement of those goals most affected by groundwater contamination is often hindered by of a lack of resources to enable adaptation. A range of threats to groundwater quality exist, both natural and anthropogenic, which may constrain groundwater use. However, groundwater often provides good quality water for a range of purposes and is the most important water resource in many settings. This special issue explores some of the key groundwater quality challenges we face today as well as the opportunities good groundwater quality and treatment solutions bring to enhance safe groundwater use. Legacy anthropogenic contaminants and geogenic contaminants may be well documented in certain places, such as N America, Europe and parts of Asia. However, there is a real issue of data accessibility in some regions, even for more common contaminants. This paucity of information can restrict our understanding and ability to manage and protect groundwater sources. Compared to surface water quality, large scale assessments for groundwater quality are still scarce and often rely on inadequate data sets. Better access to existing data sets and more research is needed on many groundwater quality threats. Identification and quantification of these threats will support the wise use and protection of this subsurface resource, allow society to adequately address future challenges, and help communities realise the full potential of groundwater.

Peroxone activated persulfate oxidation of 1,4-Dioxane under column scale conditions.

The research presented herein investigates a peroxone activated persulfate (PAP) oxidant, commercialized under the trade name OxyZone®, and its effects on 1,4-Dioxane (dioxane) contaminated water under column scale conditions in the presence of porous material. There is a limited understanding of the underlying processes that govern PAP oxidation, including the oxidation rates in the presence of aquifer material, and how these reactions proceed once the oxidant is injected into a contaminant plume. Initial batch experiments with porous material (e.g. sand) provided data on the reaction rates of dioxane oxidation as a function of the oxidant: contaminant ratio. The observed degradation rates were approximately 4 times lower than those reported for aqueous solutions containing no porous media. Subsequent column experiments simulated two PAP injections schemes along the flowpath of a dioxane plume to study if the injection of one oxidant slug may yield different results than injecting the same oxidant volume at two separate locations. The injection of one oxidant slug was found more effective, resulting in near complete destruction of dioxane over a prolonged time at a rate more than an order of magnitude greater than in the two-slug injection scenario. Tracer test results suggest that the prolonged oxidant reactivity was in part caused by the high density of the injected oxidant solution. Overall, the results underline the importance of accounting for the properties of both the oxidant solution and the porous material when considering the injection of PAP oxidant into an impacted aquifer.

Pulse UV light effect on microbial biomolecules and organic pollutants degradation in aqueous solutions.

This study present assessed the effect of UV pulsed light (PL) on microbial and organic pollutants using two spiral lamps were used, i.e., PL1 and PL2 lamps, with wavelength cut-offs of 190 and 240 nm, respectively. Overall, our study demonstrated that pulsed UV light impacts several microbial biomolecules and degrades polycyclic aromatic hydrocarbons (PAHs) in aqueous solution. In microbial inactivation by PL2, temporary changes of bacterial cellular components, specifically proteins, were observed, but the compositional changes of bacteria that were exposed to PL1 were permanent due to ozonolysis. PL1 irradiation caused greater deactivation of the bacteria than PL2 irradiation due to the generation of ozone. The higher efficacy of PL1 in terms of membrane disruption, reduction of respiration rate, and reduction of growth rate was due to the production of ozone during the irradiation period. The bacteria that were irradiated with both PL lamps regrew due to photoreactivation, such as an enzymatic DNA-repair mechanism. The PAH degradation kinetics indicate that higher molecular weights degraded faster than those with lower molecular weights. For both lamps, the degradation of naphthalene and fluorene was first order, whereas second order for pyrene and anthracene. Any effect of ozonolysis on the PAH degradation rates was not apparent, which indicated that photolysis was the primary degradation pathway. PAH solutions treated with both pulsed UV lamps did not result in a toxicity effect on the bacteria.

Hydraulic and hydrogeochemical characteristics of a riverbank filtration site in rural India.

A riverbank filtration (RBF) system was tested along the Kali River in rural part of the state of Karnataka in India. The polluted river and water from open wells served the local population as their principal irrigation water resource and some used it for drinking. Four RBF wells (up to 25 m deep) were installed. The mean hydraulic conductivity of the well field is 6.3 x 10(-3) cm/s and, based on Darcy's law, the water travel time from the river to the principal RBF well (MW3) is 45.2 days. A mixing model based on dissolved silica concentrations indicated that, depending on the distance from the river and closeness to irrigated rice fields, approximately 27 to 73% of the well water originated from groundwater. Stable isotopic data indicates that a fraction of the water was drawn in from the nearby rice fields that were irrigated with river water. Relative to preexisting drinking water sources (Kali River and an open well), RBF well water showed lower concentration of dissolved metals (60.1% zinc, 27.8% cadmium, 83.9% lead, 75.5% copper, 100% chromium). This study demonstrates that RBF technology can produce high-quality water from low-quality surface water sources in a rural, tropical setting typical for many emerging economies. Further, in parts of the world where flood irrigation is common, RBF well water may draw in infiltrated irrigation water, which possibly alters its geochemical composition. A combination of more than one mixing model, silica together with stable isotopes, was shown to be useful explaining the origin of the RBF water at this study site.

Hindered gas-phase partitioning of trichloroethylene from aqueous cyclodextrin systems: implications for treatment and analysis.

Chemically enhanced flushing has shown great promise for attenuating subsurface nonaqueous phase liquid (NAPL) contamination. One particular chemically enhanced remediation technology is cyclodextrin enhanced flushing (CDEF). CDEF has been demonstrated as a viable alternative to conventional and innovative remediation methods. However, the presence of cyclodextrin (CD) in solution complicates the treatment and analysis of volatile organic compounds, such as trichloroethylene (TCE). The principal reason for the complications is the presence of TCE in three compartments instead of two, i.e., the aqueous solution, the vapor phase, and complexed inside the soluble CD molecule. Aqueous TCE-CD systems were examined at various concentration and temperature conditions and their respective Henry's law constants were measured. The presence of CD significantly decreased Henry's law constant of TCE. On the basis of these results, a quantitative model was developed to predict the additional effort that becomes necessary when air-stripping TCE from CDEF flushing solution. The modeling results demonstrate that the presence of CD requires significantly higher gas flow rates or longer residence times of the flushing solution inside an air stripper. Similarly, current gas chromatographic purge-and-trap methods for TCE analysis in CD solution appear to underestimate the aqueous phase TCE concentration if the CD concentration of the sample is not accounted for. Although this model was developed specifically for CD-TCE systems, it is likely that these results have implications for other VOCs and other solubilization enhancing agents, such as surfactants or cosolvents.

Tracer diffusion coefficients in sedimentary rocks: correlation to porosity and hydraulic conductivity.

Matrix diffusion is an important transport process in geologic materials of low hydraulic conductivity. For predicting the fate and transport of contaminants, a detailed understanding of the diffusion processes in natural porous media is essential. In this study, diffusive tracer transport (iodide) was investigated in a variety of geologically different limestone and sandstone rocks. Porosity, structural and mineralogical composition, hydraulic conductivity, and other rock properties were determined. The effective diffusion coefficients were measured using the time-lag method. The results of the diffusion experiments indicate that there is a close relationship between total porosity and the effective diffusion coefficient of a rock (analogous to Archie's Law). Consequently, the tortousity factor can be expressed as a function of total porosity. The relationship fits best for thicker samples (> 1.0 cm) with high porosities (> 20%), because of the reduced influence of heterogeneity in larger samples. In general, these correlations appear to be a simple way to determine tortuosity and the effective diffusion coefficient from easy to determine rock porosity values.