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1.
J Environ Manage ; 348: 119305, 2023 Dec 15.
Article in English | MEDLINE | ID: mdl-37866189

ABSTRACT

The application of biochar in soil provides various benefits that can vary in intensity as the pyrolysis temperature increases. However, its low density makes this material easily transportable and prone to being removed from the system. The objective of this study was to investigate the pyrolysis temperatures and compression pressure of densified biochar carrier capsules on the physiological quality of Schizolobium parahyba var. amazonicum seeds. Produced at three final pyrolysis temperatures (300, 600, and 900 °C), the biochar was characterized through bulk and true density analyses, immediate composition, pH, electrical conductivity, cation exchange capacity, water-soluble carbon, characterization of organic structures by FTIR, and PAH analysis. Subsequently, the biochar was compacted by briquetting at two compression pressures (50 and 200 psi) with one seed per capsule, and germination, emergence, and quality of generated seedlings were evaluated. After verifying residue normality and variance homogeneity, analysis of variance was conducted following a completely randomized design in a 3 × 2 factorial arrangement, with four replications per treatment and two additional control treatments. Upon identifying significant differences, regression model adjustments were performed. Cluster-based multivariate analysis was used to identify similarities among the studied treatments, both for capsules and controls. Pyrolysis temperature and compression pressure influenced seed germination, emergence, and initial seedling growth. Lower pressure favored shoot development, while higher pressure favored root development and generated seedlings of higher quality. The benefits of biochar to soil, combined with the implementation of seeds, make the production of densified biochar capsules an alternative to conventional seedings, potentially reducing high energy and financial costs and enabling the recovery of degraded areas, even in difficult-to-access regions.


Subject(s)
Carbon , Charcoal , Charcoal/chemistry , Soil/chemistry , Temperature , Seedlings
2.
Environ Sci Pollut Res Int ; 30(19): 56161-56173, 2023 Apr.
Article in English | MEDLINE | ID: mdl-36917377

ABSTRACT

The interest of biofuel producers in Neotropical species that have high growth rates, slight wood density variability, and elemental composition that does not compromise the environment has increased in recent decades. We investigated the density and chemical characteristics of wood of Schizolobium parahyba var. amazonicum (Huber × Ducke) Barneby as a source for the generation of bioenergy. Apparent radial wood density profiles (X-ray densitometry (XRD)) and the elemental distribution (X-ray fluorescence (XRF)) of Cl, S, K, and Ca in the wood of nine S. parahyba var. amazonicum trees, divided into three diameter classes (I = 15.5, II = 19.5, and III = 23.5 cm) were analyzed. The high heating value (HHV) of the wood samples was determined, and the energy density was estimated by the product of the HHV and the apparent density. Trees that grew better (classes II and III) produced wood with higher density. These trees showed higher concentrations of K and S, and lower concentrations of Ca and Cl. The highest Cl concentrations were observed in classes with smaller diameters. The chlorine levels met the standards for use of this wood as fuel, but the sulfur levels were higher than the threshold recommended by the ISO 17225-3:2021 guidelines, which can limit the use of the species for certain energy uses. The wood of S. parahyba var. amazonicum had interesting characteristics for the production of bioenergy due to its low density, so it can be used in the production of solid biofuels such as pellets and briquettes. Monitoring chlorine and sulfur is important, since during the combustion of biomass they are released into the atmosphere and can negatively contribute to the effects of climate change.


Subject(s)
Fabaceae , Wood , Wood/chemistry , Chlorine/analysis , Trees , Biofuels/analysis , Biomass , Halogens/analysis
3.
Environ Sci Pollut Res Int ; 30(7): 18078-18090, 2023 Feb.
Article in English | MEDLINE | ID: mdl-36205870

ABSTRACT

Tannins are polyphenols that can be extracted from different parts of the plant and have different known commercial applications. The extraction of tannins generates a significant amount of low-density wastes. An alternative that can be applied to ensure energy reuse of this low-density waste is a densification process, such as briquetting. Thus, this research work aimed to assess the energy potential of the residue from the extraction of tannins of different forest species, aiming at its energy reuse in the form of briquettes. Stem barks of 6 forest species (Acacia mangium, AM; Anacardium occidentale, AO; Anadenanthera colubrina, AC; Azadirachta indica, AI; Mimosa caesalpiniaefolia, MC; Mimosa tenuiflora, MT) were used after tannin extraction. Bulk density, energy (higher, lower, and net heating value) and thermal (TG/DTG) properties, and chemical constitution (extractives, lignin, and holocellulose) of the materials were determined. In addition, briquette compaction ratio, apparent density, volumetric expansion, and water adsorption over the days were evaluated. The highest bulk densities were found in the barks of Anadenanthera colubrina (0.529 g.cm-3) and Mimosa tenuiflora (0.407 g.cm-3), whereas the species that showed the best result of higher heating value was Acacia mangium (20.44 MJ.kg-1), followed by Azadirachta indica (19.39 MJ.kg-1) and Mimosa caesalpiniifolia (18.85 MJ.kg-1). Briquetting increased the density of the evaluated material by 2.3 to 4.9 times. All briquettes produced with wastes from tannin extraction evaluated in this work showed potential for energy production. With more information on the quantification of waste generated and data on the economic viability of production, these tannin-producing industries can benefit both environmentally and economically, by reusing these wastes for energy production.


Subject(s)
Acacia , Fabaceae , Waste Management , Tannins/chemistry , Lignin
4.
Estud. av ; 21(59): 185-193, jan.-abr. 2007. mapas, tab, graf
Article in Portuguese | LILACS | ID: lil-450088

ABSTRACT

Uma importante retomada de crescimento, observada nos últimos dez anos, vem tomando conta da tendência de declínio do consumo de madeira para energia no Brasil, iniciada na metade do século passado. Diante desse fato, o uso energético continua representando o maior consumo de madeira para um fim específico no país, atingindo 61 por cento do volume total. Em que pese tal aspecto, há ainda muito a ser conquistado, quanto à definição e à implantação de ações pragmáticas, para a real valorização desse uso no país. Neste trabalho são debatidos os aspectos quantitativos relacionado a tal aplicação, seu espaço estratégico e as demandas de definições e de ações a ela relacionadas. É ainda mostrado que antigas necessidades ainda não foram devidamente contempladas, no sentido da consolidação dessa importante e fundamental forma de aplicação da madeira, considerando-se os dias atuais, em que a utilização de fontes fósseis de energia está sendo fortemente questionada.


In the last ten years, an important restoration of wood consumption for energy production purposes in Brazil has been taking place, going against a decline tendency initiated in the mid 1900s. For that reason, energy production still represents the greatest demand of wood for a determined application: 61 percent of the total volume. However, there is still a lot to conquer in the definition and implantation of pragmatic actions for the valorization of this practice in the country. In this paper, quantitative aspects of this application will be discussed, as well as its strategic scope and the request for the definition of actions and plans. Long-felt needs for the consolidation of this important and fundamental application of wood that havenÆt been fulfilled are also pointed out, considering the current debate in which the use of fossil energy sources is being challenged.


Subject(s)
Conservation of Energy Resources , Wood , Brazil
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