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1.
A short route to (-)-mintlactone by thallium(III)-mediated cyclization of (-)-isopulegol.
Ferraz, H M; Grazini, M V; Ribeiro, C M; Brocksom, U; Brocksom, T J.
J Org Chem ; 65(8): 2606-7, 2000 Apr 21.
Article in English | MEDLINE | ID: mdl-10789485

Subject(s)
Lactones/chemical synthesis , Terpenes/chemical synthesis , Thallium/chemistry , Carboxylic Acids/chemistry , Cyclization , Cyclohexane Monoterpenes , Magnetic Resonance Spectroscopy , Mentha piperita , Plant Oils/chemistry , Spectrophotometry, Infrared
2.
An approach to the synthesis of C18 tri-insaturated fatty acids.
Petragnani, N; Brocksom, T J; Gato, A R.
Farmaco Sci ; 32(9): 627-34, 1977 Sep.
Article in English | MEDLINE | ID: mdl-902757

ABSTRACT

New approaches for the synthesis of cis, trans, trans, octadeca-9,11,13-trienoic acid (I) and its trans, trans, cis isomer (II), starting from the easily available propargyl alcohol are described.


Subject(s)
Fatty Acids, Unsaturated/chemical synthesis , Hydrolysis , Indicators and Reagents , Magnetic Resonance Spectroscopy
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