Synthesis and performance evaluation of zinc oxide tubes/alginate microfibre composites for photodegradation of methylene blue: a novel reporting approach.

This research investigates the efficacy of zinc oxide (ZnO) tubes in decontaminating polluted water using a substrate-free hydrothermal synthesis process for ZnO tubes. The synthesized tubes are impregnated into calcium alginate microfibres, strategically chosen for their high surface area to enhance photocatalytic degradation performance and for practical handling during decontamination and subsequent collection, thereby preventing secondary contamination. Structural and morphological analyses, conducted using Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD), thoroughly characterize the properties of the ZnO tubes and the composite material. The efficacy of this composite is demonstrated through the photocatalytic degradation of methylene blue (MB), as a representative organic pollutant, resulting in an 88% degradation of MB after 5 hours of irradiation by a sun simulator. Cyclic tests exhibit consistent degradation levels in the first four cycles (81-89%), followed by a subsequent decrease to 72% in the fifth cycle, coinciding with the breakdown of the microfibres into shorter fragments. Innovatively, this study introduces an approach to reporting photocatalytic degradation results, utilizing normalized pollutant concentration plotted against irradiated energy instead of time, as energy encompasses irradiated power, time, and surface area. This reveals that the 88% degradation of MB is achieved by irradiating the sample with an approximately 18 kJ. Additionally, a new metric, Specific Energy Efficiency (SEE), is introduced. It expresses the ratio of degraded pollutant mass to the mass of photocatalytic active material per unit of irradiated energy, with the maximum and cumulative SEE in this study being 1.044 µg g-1 J-1 and 326 ng g-1 J-1, respectively. This research not only contributes to the understanding of ZnO tubes' efficiency in polluted water decontamination but also introduces valuable insights for standardized reporting in photocatalytic degradation studies.

Design, microfabrication, and characterization of a moulded PDMS/SU-8 inkjet dispenser for a Lab-on-a-Printer platform technology with disposable microfluidic chip.

In this paper, we present a disposable inkjet dispenser platform technology and demonstrate the Lab-on-a-Printer concept, an extension of the ubiquitous Lab-on-a-Chip concept, whereby microfluidic modules are directly integrated into the printhead. The concept is demonstrated here through the integration of an inkjet dispenser and a microfluidic mixer enabling control over droplet composition from a single nozzle in real-time during printing. The inkjet dispenser is based on a modular design platform that enables the low-cost microfluidic component and the more expensive actuation unit to be easily separated, allowing for the optional disposal of the former and reuse of the latter. To limit satellite droplet formation, a hydrophobic-coated and tapered micronozzle was microfabricated and integrated with the fluidics to realize the dispenser. The microfabricated devices generated droplets with diameters ranging from 150-220 µm, depending mainly on the orifice diameter, with printing rates up to 8000 droplets per second. The inkjet dispenser is capable of dispensing materials with a viscosity up to ∼19 mPa s. As a demonstration of the inkjet dispenser function and application, we have printed type I collagen seeded with human liver carcinoma cells (cell line HepG2), to form patterned biological structures.

Photonic metal-polymer resin nanocomposites with chiral nematic order.

Mesoporous resins with chiral nematic order were used as scaffolds to construct novel iridescent metal-polymer composites. Gold, silver and palladium nanoparticles were formed by an in situ reduction reaction. We have investigated the effects of concentration and time on the deposition. As a proof-of-concept, we demonstrate that this process can be extended to patterning photonic resins by inkjet printing.

Photonic patterns printed in chiral nematic mesoporous resins.

Chiral nematic mesoporous phenol-formaldehyde resins, which were prepared using cellulose nanocrystals as a template, can be used as a substrate to produce latent photonic images. These resins undergo swelling, which changes their reflected color. By writing on the films with chemical inks, the density of methylol groups in the resin changes, subsequently affecting their degree of swelling and, consequently, their color. Writing on the films gives latent images that are revealed only upon swelling of the films. Using inkjet printing, it is possible to make higher resolution photonic patterns both as text and images that can be visualized by swelling and erased by drying. This novel approach to printing photonic patterns in resin films may be applied to anti-counterfeit tags, signage, and decorative applications.