Review on lignocellulose valorization for nanocarbon and its composites: Starting from laboratory studies to business application.

This study concerns a scoping and literature review of nanocarbon and its composites with details on specific propositions, including nanocarbon history, nanocarbon types, and lignocellulose nanocarbon types, properties, applications, toxicity, regulation, and business model for commercialization. The review brings novelties, comprehensively expounding on laboratory studies and industrial applications of biomass or lignocellulose materials-derived nanocarbon and its composites. Since its first discovery in the form of Buckyball in 1985, nanocarbon has brought interest to scientists and industries for applications. From the previous studies, it is discovered that many types of nanocarbon are sourced from lignocellulose materials. With their excellent properties of nanomaterials, nanocarbon has been harnessed for such as reinforcing and filler agents for nanocomposites or direct use of individual nanocarbon for specific purposes. However, the toxicological properties of nanocarbon have delivered a level of concern in its use and application. In addition, with the radically growing increase in the use of nanocarbon, policies have been enacted in several countries that rule on the use of nanocarbon. The business model for the commercialization of lignocellulose-based nanocarbon was also proposed in this study. This study can showcase the importance of both individual nanocarbon and nanocarbon-based composites for industrial implementations by considering their synthesis, properties, application, country legislations/regulations, and business model. The studies also can be the major references for researchers to partner with industries and governments in investing in lignocellulose-sourced nanocarbon potential research, development, and policies.

Enhancement of the Mechanical, Self-Healing and Pollutant Adsorption Properties of Mortar Reinforced with Empty Fruit Bunches and Shell Chars of Oil Palm.

This study aims to produce mortar through the addition of oil palm shells (OPS)-activated charcoal and oil palm empty fruit bunch (OPEFB) hydrochar, which has high mechanical properties, self-healing crack capabilities, and pollutant adsorption abilities. The cracking of mortar and other cementitious materials is essential in anticipating and reducing building damages and ages due to various reasons, such as chemical reactions, foundation movements, climatic changes, and environmental stresses. This leads to the creation of self-healing mortar, which is produced by adding reductive crack size materials to form calcium carbonate (CaCO3) and silicate hydrate (3CaO.2SiO2.2H2O, CSH). One of these materials is known as activated charcoal, which is obtained from oil palm shells (OPS) and oil palm empty fruit bunches (OPEFB) fibres. This is because the OPS-activated charcoal minimizes crack sizes and functions as a gaseous pollutant absorber. In this study, activated charcoal was used as fine aggregate to substitute a part of the utilized sand. This indicated that the utilized content varied between 1-3 wt.% cement. Also, the mortar samples were tested after 28 days of cure, including the mechanical properties and gaseous pollutant adsorption abilities. Based on this study, the crack recovery test was also performed at specific forces and wet/dry cycles, respectively, indicating that the mortar with the addition of 3% activated charcoal showed the best characteristics. Using 3% of the cement weight, OPEFB hydrochar subsequently varied at 1, 2, and 3% of the mortar volume, respectively. Therefore, the mortar with 3 and 1% of OPS-activated charcoal and OPEFB hydrochar had the best properties, based on mechanical, self-healing, and pollutant adsorption abilities.