High-sensitivity cassette for reducing limit of detection for diesel particulate matter sampling.

NIOSH researchers designed a high-sensitivity (HS) cassette to improve the limit of detection of the National Institute for Occupational Safety and Health's (NIOSH) method 5040 and the Airtec near real-time diesel particulate matter (DPM) monitor. This was achieved by reducing the size of the diesel particulate matter deposition spot from 8.0 cm2 (NIOSH method 5040 mining samples) and 7.6 cm2 (Airtec samples) to 0.5 cm2. When compared with the standard cassette, the new high-sensitivity cassette improves the limit of detection of NIOSH method 5040 by approximately five times, and the differences between the elemental carbon results from the HS cassette and the standard three-piece cassette were within statistical error. The limit of detection for Airtec measurements improved by approximately 15 times, and the elemental carbon results with the HS cassette between the Airtec and NIOSH method 5040 were within statistical agreement. When used in the Airtec monitor, the high-sensitivity cassette showed promise for measuring short-duration spot checks of ambient concentrations but was limited when performing some long-term sampling due to the resultant loss of dynamic range. Only up to 7 µg of elemental carbon was collected onto the HS cassette before the increase in pump backpressure caused the flow fluctuations to exceed targeted values by unacceptable levels. The HS cassette shows promise for effective engineering evaluations of control technologies and strategies and near real-time diesel particulate matter measurements for a variety of occupations.

Effects of FAME biodiesel and HVORD on emissions from an older-technology diesel engine.

The results of laboratory evaluations were used to compare the potential of two alternative, biomass-derived fuels as a control strategy to reduce the exposure of underground miners to aerosols and gases emitted by diesel-powered equipment. The effects of fatty acid methyl ester (FAME) biodiesel and hydrotreated vegetable oil renewable diesel (HVORD) on criteria aerosol and gaseous emissions from an older-technology, naturally aspirated, mechanically controlled engine equipped with a diesel oxidation catalytic converter were compared with those of widely used petroleum-derived, ultralow-sulfur diesels (ULSDs). The emissions were characterized for four selected steady-state conditions. When fueled with FAME biodiesel and HVORD, the engine emitted less aerosols by total particulate mass, total carbon mass, elemental carbon mass and total number than when it was fueled with ULSDs. Compared with ULSDs, FAME biodiesel and HVORD produced aerosols that were characterized by single modal distributions, smaller count median diameters, and lower total and peak concentrations. For the majority of test cases, FAME biodiesel and HVORD favorably affected nitric oxide (NO) and adversely affected nitrogen dioxide (NO2) generation. Therefore, the use of these alternative fuels appears to be a viable tool for the underground mining industry to address the issues related to emissions from diesel engines, and to transition toward more universal solutions provided by advanced engines with integrated exhaust after treatment technologies.

Mutagenicity of diesel exhaust particles from an engine with differing exhaust after treatments.

This study was conducted to investigate the effects of engine operating conditions and exhaust aftertreatments on the mutagenicity of diesel particulate matter (DPM) collected directly in an underground mine environment. A number of after-treatment devices are currently used on diesel engines in mines, but it is critical to determine whether reductions in DPM concentrations result in a corresponding decrease in adverse health effects. An eddy-current dynamometer was used to operate naturally aspirated mechanically controlled engine at several steady-state conditions. The samples were collected when the engine was equipped with a standard muffler, a diesel oxidation catalytic converter, two types of uncatalyzed diesel particulate filter systems, and three types of disposable diesel particulate filter elements. Bacterial gene mutation activity of DPM was tested on acetone extracts using the Ames Salmonella assay. The results indicated strong correlation between engine operating conditions and mutagenic activity of DPM. When the engine was fitted with muffler, the mutagenic activity was observed for the samples collected from light-load, but not heavy-load operating conditions. When the engine was equipped with a diesel oxidation catalyst, the samples did not exhibit mutagenic activity for any of four engine operating conditions. Mutagenic activity was observed for the samples collected when the engine was retrofitted with three types of disposable filters and sintered metal diesel particulate filter and operated at light load conditions. However, those filtration systems substantially reduced the concentration-normalized mutagenic activity from the levels observed for the muffler.

Relationship between elemental carbon, total carbon, and diesel particulate matter in several underground metal/non-metal mines.

Elemental carbon (EC) is currently used as a surrogate for diesel particulate matter (DPM) in underground mines since it can be accurately measured at low concentrations and diesels are the only source of submicrometer EC in underground mines. A disadvantage of using EC as a surrogate for DPM is that the fraction of EC in DPM is a function of various engine parameters and fuel formulations, etc. In order to evaluate how EC predicts DPM in the underground mining atmosphere, measurements of total carbon (TC; representing over 80% of the DPM) and EC were taken away from potential interferences in four underground metal/non-metal mines during actual production. In a controlled atmosphere, DPM mass, TC, and EC measurements were also collected while several different types of vehicles simulated production with and without different types of control technologies. When diesel particulate filters (DPFs) were not used, both studies showed that EC could be used to predict DPM mass or TC. The variability of the data started to increase at TC concentrations below 230 microg/m3 and was high (> +/- 20%) at TC concentrations below 160 microg/m3, probably due to the problem with sampling organic carbon (OC) at these concentrations. It was also discovered that when certain DPFs were used, the relationship between DPM and EC changed at lower DPM concentrations.