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1.
J Agric Food Chem ; 64(44): 8273-8281, 2016 Nov 09.
Article in English | MEDLINE | ID: mdl-27690423

ABSTRACT

The performance of FeHBED in preventing Fe deficiency chlorosis in soybean (Glycine max (L.) Merr.) in comparison to FeEDDHA and FeEDDHMA was studied, as well as the importance of the ortho-ortho and ortho-para/rest isomers in defining the performance. To this end, chlorophyll production (SPAD), plant dry matter yield, and the mass fractions of important mineral elements in the plant were quantified in a greenhouse pot experiment. All three Fe chelates increased SPAD index and dry matter yield compared to the control. The effect of FeHBED on chlorophyll production was visible over a longer time span than that of FeEDDHA and FeEDDHMA. Additionally, FeHBED did not suppress Mn uptake as much as the other Fe chelates. Compared to the other Fe chelates, total Fe content in the young leaves was lower in the FeHBED treatment; however, total Fe content was not directly related to chlorophyll production and biomass yield. For each chelate, the ortho-ortho isomer was found to be more effective than the other isomers evaluated.


Subject(s)
Fertilizers , Glycine max/metabolism , Iron Chelating Agents/pharmacology , Iron/metabolism , Plant Diseases/prevention & control , Chlorophyll/metabolism , Edetic Acid/analogs & derivatives , Edetic Acid/chemistry , Edetic Acid/pharmacology , Ethylenediamines/chemistry , Ethylenediamines/pharmacology , Iron Chelating Agents/chemistry , Manganese/metabolism , Soil/chemistry , Glycine max/drug effects , Glycine max/growth & development , Spain
2.
J Agric Food Chem ; 58(24): 12833-9, 2010 Dec 22.
Article in English | MEDLINE | ID: mdl-21090566

ABSTRACT

FeEDDHA (iron(3+) ethylenediamine-N,N'-bis(hydroxyphenylacetic acid) products are commonly applied to mend and prevent Fe deficiency chlorosis in soil-grown crops. Plants mainly take up Fe in the progressed vegetative and in the reproductive stages. This study examined which of the principal constituents of FeEDDHA products (the isomers racemic o,o-FeEDDHA, meso o,o-FeEDDHA, and o,p-FeEDDHA), most effectively meets the Fe requirements of soybean plants (Glycine max (L.) Merr.) grown on calcareous soil in the aforementioned growth stages. FeEDDHA isomers were applied once, separately or in mixtures, at t = 0, in the progressed vegetative stage or in the reproductive stage. o,p-FeEDDHA did not significantly contribute to Fe uptake in either growth stage. Both racemic and meso o,o-FeEDDHA were effective in supplying plants with Fe, approximately to the same extent. The moment of application had a significant effect on yield and FeEDDHA pore water concentrations at harvest, but not on Fe uptake. To optimize yield while minimizing FeEDDHA dosage, FeEDDHA is best applied to soybean plants prior to the onset of chorosis.


Subject(s)
Ethylenediamines/chemistry , Glycine max/metabolism , Iron Chelating Agents/chemistry , Iron/metabolism , Soil/analysis , Fertilizers/analysis , Isomerism , Glycine max/growth & development
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