ABSTRACT
Pure and Au-decorated sub-micrometer ZnO spheres were successfully grown on glass substrates by simple chemical bath deposition and photoreduction methods. The analysis of scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images, energy-dispersive X-ray spectroscopy (EDS), UV-vis absorption, and photoluminescence (PL) spectra results were used to verify the incorporation of plasmonic Au nanoparticles (NPs) on the ZnO film. Time-resolved photoluminescence (TRPL) spectra indicated that a surface plasmonic effect exists with a fast rate of charge transfer from Au nanoparticles to the sub-micrometer ZnO sphere, which suggested the strong possibility of the use of the material for the design of efficient catalytic devices. The NO2 sensing ability of as-deposited ZnO films was investigated with different gas concentrations at an optimized sensing temperature of 120 °C. Surface decoration of plasmonic Au nanoparticles provided an enhanced sensitivity (141 times) with improved response (τRes = 9 s) and recovery time (τRec = 39 s). The enhanced gas sensing performance and photocatalytic degradation processes are suggested to be attributed to not only the surface plasmon resonance effect, but also due to a Schottky barrier between plasmonic Au and ZnO structures.
ABSTRACT
This article is aimed at presenting (i) a fundamental research on the efficiency of photocatalysis in water disinfection and (ii) the efficiency of a photocatalytic prototype, developed by Buxair firm, to remove avian influenza virus in air. In water disinfection, two model strains of Escherichia coli (K12 PHL849 and K12 PHL1273) were selected and a comparison of the efficiencies of TiO2 Degussa P-25 versus TiO2 Millennium PC500 were estimated. A more important inactivation of E. coli PHL1273 was obtained on TiO2 Millennium PC500, in line with its better adherence on this solid. An experimental study was performed using a dialysis membrane to investigate the impact of the contact between the microorganisms and the photocatalyst and to determine the role of H2O2 generated in situ. In air disinfection, a total inactivation of virus A/H5N2, close to avian influenza virus A/H5N2, was obtained in a single pass in the Buxair® gas phase dynamic photoreactor using a contaminated air flow rate of 40 m3/h.
Dans cette publication, nous rapportons une étude fondamentale sur l'efficacité du procédé photocatalytique pour éliminer les bactéries présentes en solution aqueuse ainsi qu'une étude préliminaire concernant l'efficacité d'un prototype photocatalytique, développé par la société Buxair, pour éliminer le virus de la grippe aviaire présent dans l'air. En phase aqueuse, deux souches de E. coli ont été sélectionnées (la souche K12 PHL849 et la souche K12 PHL1273) et inactivées en présence de deux photocatalyseurs. Une inactivation beaucoup plus importante de la souche adhérente (PHL1273) se produit en présence du photocatalyseur TiO2 PC500. L'importance du contact entre photocatalyseur et bactérie et le rôle du peroxyde d'hydrogène susceptible d'être produit lors du procédé photocatalytique sont étudiés en utilisant une membrane de dialyse.
