Internal Vibrations of Pyridinium Cation in One-Dimensional Halide Perovskites and the Corresponding Halide Salts.

We investigate vibrations of the pyridinium cation PyH+ = C5H5NH+ in one-dimensional lead halide perovskites PyPbX3 and pyridinium halide salts PyHX (X- = I-, Br-), combining infrared absorption and Raman scattering methods at room temperature. Internal vibrations of the cation were assigned based on density functional theory modeling. Some of the vibrational bands are sensitive to perovskite or the salt environment in the solid state, while halide substitution has only a minor effect on them. These findings have been confirmed by 1H, 13C and 207Pb solid-state nuclear magnetic resonance (NMR) experiments. Narrower vibrational bands in perovskites indicate less disorder in these materials. The splitting of NH-group vibrational bands in perovskites can be rationalized the presence of nonequivalent crystal sites for cations or by more exotic phenomena such as quantum tunneling transition between two molecular orientations. We have shown how organic cations in hybrid organic-inorganic crystals could be used as spectators of the crystalline environment that affects their internal vibrations.

Ab Initio Insight into Mechanisms of Ozone Interaction with a Surface of Dehydrated Nanocrystalline TiO2.

Density functional theory (DFT) study of ozone adsorption on dehydrated nanocrystalline TiO2 is presented. Singlet and triplet binding modes of ozone to the oxide's titanium cations are considered. In both the modes, monodentate and bidentate ozone complexes are formed. According to DFT, the triplet monodentates are the most stable species. The formation of monodentate ozone adsorption complexes is in-line with an earlier interpretation of infrared (IR) spectroscopic data on ozone adsorption on an anatase surface. However, the computed difference in the fundamental vibrational frequencies (ν1 - ν3) of ozone in the triplet monodentates is significantly larger than the corresponding IR value. This discrepancy is resolved by demonstrating that the triplet monodentates readily decompose, realizing molecular oxygen that is consistent with published experimental data. The predicted energy barrier of the dissociative adsorption is less than 2 kcal/mol. In contrast, the computed difference in the fundamental vibrational frequencies (ν1 - ν3) of adsorbed ozone in the singlet bidentates perfectly agrees with the experiment.

Spectroscopic studies of ozone in cryosolutions: FT-IR spectra of 16O3 in liquid nitrogen, oxygen, argon and krypton.

We have measured and interpreted the IR spectra of ozone dissolved in liquid nitrogen, oxygen, argon, and krypton in the 650-4700cm-1 spectral region at 79-117K. Frequency shifts, band intensities and bandshapes of 22 spectral features of soluted ozone were analyzed. The bands of the А1 symmetry have a complex contour and possess an excess intensity with respect to the value of the purely vibrational transition moment. It was found that this effect is related to the manifestation of the Coriolis interaction. The bandshape distortion manifests itself as an additional intensity from the side of the В1 symmetry band being an intensity source in the case of the Coriolis interaction.