1.
Chem Commun (Camb)
; (30): 3201-3, 2007 Aug 14.
Article
in English
| MEDLINE
| ID: mdl-17653388
ABSTRACT
Reaction of [5]lithiotrovacene (TVC-Li) with tin dichloride affords the triradical complex (THF)(3)Li(+)[(TVC)(3)SnCl(2)](-) which was characterized by X-ray crystallography, cyclic voltammetry, EPR spectroscopy and magnetic susceptometry; redox splittings deltaE(1/2) ("electrocommunication") and the exchange parameters J(EPR) and J(chi) ("magnetocommunication") attest to inter vanadium interactions mediated by the central tin atom.