Exploring the abundance and characteristics of litter in Lithuanian riversides: a citizen science approach.

To gain a better understanding of the sources and ecological effects of plastic contamination in Lithuanian rivers, as well as to provide guidance for mitigation, monitoring is necessary. This is a logistically and financially demanding endeavor, particularly in the case of microplastics. Citizen science provides a viable option for sampling sites that are accessible, thus enabling the monitoring of wide areas. In Lithuania, a citizen science approach was employed, with schoolchildren examining litter at riversides and identifying potential sources at 24 sampling sites in Autumn 2022 and 32 in Spring 2023, covering both large and small rivers. The maximum amount of 220 items per location was registered in Autumn 2022, whereas 111 items per location were registered in Spring 2023. The two main types of microlitter discovered were plastic (34-42%) and cigarette butts (17-22%), with glass, paper, and metal also present, which suggests that recreational visitors are the main source of litter. By K-means clustering analysis, all locations were divided into four clusters according to litter composition. To sum up, the findings of this study illustrate the importance of citizen science in providing insight into the contamination of Lithuanian rivers, which can be used to inform the development of conservation strategies.

Characteristics and removal efficiency of microplastics at secondary wastewater treatment plant in Lithuania.

Wastewater treatment plants (WWTPs) are the most significant barrier between anthropogenic microplastics and environmental ecosystems. The distribution and characteristics of microplastics in WWTPs remain uncertain and incompletely understood, particularly in northeastern Europe (Baltic States), where there is a lack of data on microplastic pollution and distribution. This study presents the removal efficiency and variation in characteristics of microplastics in different stages of the secondary WWTP during a 3-month sampling campaign in Lithuania. The abundance, size, shape, color, and chemical composition of microplastics in the wastewater at different treatment stages were thoroughly examined, in a size range from 20 to 1000 µm. On average, 2962 ± 25 particles/L of microplastic enter the studied WWTP. The obtained microplastic removal efficiency was 55.4% ± 3.9%, highlighting the necessity to enhance wastewater treatment strategies focusing on microplastic removal. Fragment-type microplastics smaller than 100 µm were removed from wastewater samples with the highest removal efficiency. Furthermore, our study includes recommendations to improve microplastic removal efficiency and contribute to mitigating microplastic pollution. PRACTITIONER POINTS: A large number of MPs in the size range of 20-1000 µm enter Lithuanian WWTP. Small-sized MPs within a range of 20-50 µm and 50-100 µm were removed with the highest efficiency of 54.07 ± 1.68% and 56.4 ± 2.43%, respectively. The shape and size of MPs have a major impact on the efficiency of their removal. Future research should prioritize the development of economical and energy-efficient systems, specifically designed for the removal of MPs in WWTPs.

Long term observations of biomass burning aerosol over Warsaw by means of multiwavelength lidar.

High quality lidar measurements of PollyXT operating at the University of Warsaw in the years 2013-2022 were analyzed to present a comprehensive optical characterization of biomass burning aerosols over Warsaw. The directions of the aerosol inflows were analyzed by dividing advection cases into four types, according to the area of origin: Western Europe, Eastern Europe, the Iberian Peninsula, and North America. It was shown that optical properties of smoke vary in each of these types, and emphasized that aerosol aging processes are important. It was found that as aerosol's age increases, there is more backscattering and less extinction at 355 nm in relation to 532 nm. The analysis of the lidar ratio demonstrated that the main changes of the aging process were observed in the UV spectra.

New evidence of the presence of micro- and nanoplastic particles in bronchioalveolar lavage samples of clinical trial subjects.

This is the first study reporting the presence of airborne nano-sized plastic particles in the bronchoalveolar lavage fluid (BALF) samples of patients undergoing diagnostic bronchoscopy. The results represent the plastic pollution content in the lower airways of the residents of Northern Europe. Airborne micro- and nanoplastic particles (MP/NPs) are widely dispersed worldwide and intrude on human organisms to various extents, with the respiratory tract being the first line of exposure. The amounts of inhaled MP/NPs, their fate in the human respiratory tract, and the effects on the health of human airways and other exposed organs remain largely unknown. In this clinical study, human BALF samples were assessed by means of optical and transmission electron microscopy coupled with energy-dispersive X-ray spectroscopy (TEM-EDX). Results show that MP/NPs levels vary in the interval of 0.14-12.8 particles per 100 ml of BALF and are present in all samples tested, mainly in a fragmented form. External pollution by MP/NPs was excluded by carefully choosing methodology and equipment. This finding is a timely addition of valuable information and stimulates further research into the biological effects of inhaled MP/NPs.

Impact of long-range transport on black carbon source contribution and optical aerosol properties in two urban environments.

Urban areas, as major sources of aerosol black carbon emissions, contribute to increased pollution levels in surrounding regions by air mass long-range transport, which should be taken into account in implementation of emission-reduction strategies. Properties of light-absorbing aerosol particles and a novel approach to assess the impact of long-range transport on black carbon (BC) pollution in two under-investigated urban environments: Warsaw (Poland, Central Europe) and Vilnius (Lithuania, North-Eastern Europe) are presented. During the warm season of May-August 2022, BC mass concentration and aerosol optical properties: the scattering Ångström exponent (SAE), absorption Ångström exponent (AAE), and single scattering albedo (SSA) were investigated. Generally, the mean BC mass concentration was higher at the more polluted site in Warsaw (1.07 µg/m3) than in Vilnius (0.77 µg/m3). The BC source apportionment to biomass burning (BCBB) and fossil fuel combustion (BCFF) showed similar contributions for both sites with BCBB (13-19%) being significantly lower than BCFF (81-87%). A uniform flow of air masses transporting aerosol particles over long distances to both sites was observed for 42% of the days. It affected BC mass concentration as follows: BC decrease was found similar at both sites (42% in Warsaw, 50% in Vilnius) but increase was twice higher in Vilnius (64%) than in Warsaw (30%). Despite variations in BC mass concentration, both sites exhibited a comparable abundance (90%) of submicron (SAE<1.3), BC-dominated (AAE<1.5) particles. The mean SSA was very low (0.69 ± 0.1 in Warsaw, 0.72 ± 0.1 in Vilnius), which indicates a very strong contribution of light-absorbing aerosol particles in both environments. The local episodes of biomass burning due to celebrations of May Days on 1st - 3rd May in Warsaw and Midsummer on 24th June in Vilnius showed similar aerosol properties in both cities (1.5

Source apportionment for indoor air pollution: Current challenges and future directions.

Source apportionment (SA) for indoor air pollution is challenging due to the multiplicity and high variability of indoor sources, the complex physical and chemical processes that act as primary sources, sinks and sources of precursors that lead to secondary formation, and the interconnection with the outdoor environment. While the major indoor sources have been recognized, there is still a need for understanding the contribution of indoor versus outdoor-generated pollutants penetrating indoors, and how SA is influenced by the complex processes that occur in indoor environments. This paper reviews our current understanding of SA, through reviewing information on the SA techniques used, the targeted pollutants that have been studied to date, and their source apportionment, along with limitations or knowledge gaps in this research field. The majority (78 %) of SA studies to date focused on PM chemical composition/size distribution, with fewer studies covering organic compounds such as ketones, carbonyls and aldehydes. Regarding the SA method used, the majority of studies have used Positive Matrix Factorization (31 %), Principal Component Analysis (26 %) and Chemical Mass Balance (7 %) receptor models. The indoor PM sources identified to date include building materials and furniture emissions, indoor combustion-related sources, cooking-related sources, resuspension, cleaning and consumer products emissions, secondary-generated pollutants indoors and other products and activity-related emissions. The outdoor environment contribution to the measured pollutant indoors varies considerably (<10 %- 90 %) among the studies. Future challenges for this research area include the need for optimization of indoor air quality monitoring and data selection as well as the incorporation of physical and chemical processes in indoor air into source apportionment methodology.

Global research hotspots and trends on microplastics: a bibliometric analysis.

In recent years, microplastics have become an integral part of the terrestrial and aquatic environments, which is one of the major concerns of communities around the world. Therefore, it is necessary to know the current status of studies and feasible potentials in the future. This study, conducted an in-depth bibliometric analysis of publications from 1990 to 2022 to present the influential countries, authors, institutes, papers, and journals on microplastics. Findings reveal that there has been a steady increase in microplastic publications and citations in recent years. And, the number of publications and citations has increased 19 and 35 times since 2015. Besides, we performed a comprehensive keyword analysis to show the significant keywords and clusters in this field. In particular, this study used the TF-IDF method as a text-mining analysis to extract the new keywords used in recent years (i.e., 2020-2022). New keywords can draw the attention of scholars to important issues and provide a basis for future research directions.

Evaluation of Work-Related Personal Exposure to Aerosol Particles.

The effects of air pollution on the general public received much attention recently. Personal exposure and deposition fraction of aerosol particles were studied in Vilnius, Lithuania, focusing on individuals working in an office and driving to work. Aerosol monitoring in the urban background was found to give an indication of the minimum concentrations of particulate matter (PM) expected at urban roads, as these correspond to the lowest PM concentrations measured there. In March 2021, PM2.5 concentrations at the urban background monitoring station reached values above the annual limit of 5 µg/m3 the World Health Organization in 50% of cases. Our study shows significant differences in exposure to air pollution in a car cabin and in a modern office. According to the multiple-path particle dosimetry model, the exposure of the person in the office is about 14 times lower than driving a car, where the minute deposition dose for PM1 is 0.072 µg/min for the period when the PM2.5 concentration in the urban background reaches 10 µg/m³. Compared to the PM2.5 mass concentration at the urban background station, the mean PM2.5 concentration in the vehicle reaches values that are 2-3 times higher. During the working day, when driving takes less than 10% of the time considered (commuting plus working), PM exposure during driving accounts for about 80% of the PM exposure caused by PM concentration in the office.

Evaluation of the anthropogenic black carbon emissions and deposition on Norway spruce and silver birch foliage in the Baltic region.

This study investigates potential influence of urban trees on black carbon (BC) removal by Norway spruce and silver birch along with the BC formation, mass concentration in air, and source apportionment. The main sources of BC in urban areas are transport, household and industry. BC concentrations monitored in urban background station in Vilnius (Lithuania) showed that biomass burning was a significant contributor to BC emissions even during warm period of the year. Therefore, BC emission levels were determined for the most common biomass fuels (mixed wood pellets, oak, ash, birch and spruce firewood) and two types of agro-biomass (triticale and rapeseed straw pellets) burned in modern and old heating systems. The highest emissions were obtained for biomass fuels especially birch firewood. BC aerosol particles produced by the condensation mechanism during the combustion processes were found in all samples taken from the leaf surface. The short-term effect of BC exposure on photosynthetic pigments (chlorophyll a and b; and carotenoids) in the foliage of one-year-old Norway spruce and silver birch seedlings was evaluated by the experiment carried out in the phytotron greenhouse. The seedlings showed different short-term responses to BC exposure. All treatments applied in the phytotron greenhouse resulted in lower chlorophyll content in spruce foliage compared to natural conditions but not differed for birch seedlings. However, the exposure of BC particles on the spruce and birch seedlings in the phytotron increased the content of photosynthetic pigments compared to the control seedlings in the phytotron. Overall, urban trees can help improve air quality by reducing BC levels through dry deposition on tree foliage, and needle-like trees are more efficient than broad-leaved trees in capturing BC. Nevertheless, a further study could assess the longer-term effects of BC particles on tree biochemical and chemical reactions.

Distribution of polycyclic aromatic hydrocarbons and heavy metals in soil following a large tire fire incident: A case study.

In October 2019, a fire occurred in a tire-recycling facility in Alytus (Lithuania), where around 5000 t of tires had been stored. Only after 10 days was the fire completely extinguished, and the potential contamination of the surrounding environment has raised a large public concern. With an aim to assess the pollution level and pollutants distribution in the surrounding area, we conducted a study on polycyclic aromatic hydrocarbons (PAHs) and heavy metals. High concentrations of total PAHs were found inside the fire zone (315-5872 ng g-1 dw), whereas those detected in the surrounding soils were significantly lower (1.9-72 ng g-1 dw). Some areas with higher anthropogenic impact were found to contain PAH concentrations as high as 70198 ng g-1 dw. Concentrations of Cr, Zn, Ni, Cu, Pb were in the range of 1.1-93.9; 20.7-227.5; 0.2-35.7; 0.9-21.3; 0.9-102.9 µg g-1, respectively. Zn was the prevailing metal in the fire zone, elevated concentrations of Cr, Ni and Cu were also detected in this area. Principal component analysis (PCA) revealed several locations affected by the fire. The one located the closest to the fire zone was found to be highly contaminated with the heavy metals, just like the whole fire zone. Increase of the carcinogenic risk was observed in the fire zone, but no significant risk was detected in the fire-affected stations. The highest carcinogenic risk was detected in the zones with high anthropogenic loading (traffic and urban activities).

Characteristics of black carbon aerosol mass concentration over the East Baltic region from two-year measurements.

Continuous measurements of black carbon (BC) aerosol mass concentration were performed at a background site Preila (55°55'N, 21°00'E, 5 m a.s.l., Lithuania) during the period 2008-2009. The data were used to characterize the BC mass concentration distribution over the East Baltic region. High increase in aerosol BC concentration was associated with the change in air mass characteristics and biomass burning during the winter heating season and spring wildfires. Monthly means of BC concentration ranged from 212 to 1268 ng m(-3) and the highest hourly means of concentration were from 4800 to 6300 ng m(-3), predominantly in spring and winter months. During the October-April period the BC mass concentrations were about twice as high as those in the summertime. The BC diurnal pattern in winter was typically different from that in spring indicating the seasonal variation of the atmospheric boundary layer height. The weekday/weekend difference was not strongly pronounced because the BC concentrations in Preila are mainly affected by long-range transport or local sources. Typical periodicities caused by anthropogenic and meteorological influences have been identified using Fourier analysis. It was shown that domestic heating appears as a 365 day periodicity; traffic slightly contributes 5-7 day peaks in the spectrum and elevated long-range BC can be identified as characteristic peaks with periodicities in the range from 16 to 29 days.Temporal evolution and transport of BC aerosols were interpreted by the air mass backward trajectory analysis in conjunction with the examination of the wavelength dependence on the aethalometer data. Air masses originated from the North Atlantic Ocean and Scandinavia were favourable for lower BC concentrations (350 ng m(-3)), while the BC level associated with the Western Europe airflows was significantly higher (970 ng m(-3)). The mean values of Ångström exponent of the absorption coefficient (monthly means 1.45 ± 0.25 and 0.84 ± 0.50 over January and June, respectively) revealed that the BC concentration observed over the East Baltic is influenced by submicron sized particles as a result of incomplete biomass combustion during the winter season.

Ambient ozone concentration and its impact on forest vegetation in Lithuania.

Continuous ozone concentration measurements at rural sites in Lithuania have been performed since 1982. Long-term ozone data show an increasing trend 0.4 ppb y(-1) in annual mean concentrations during the period 1982-2008, although ozone peak values show an insignificant tendency to decrease. Several studies were performed to evaluate the ozone effect on the main plant species of Lithuanian forests. A strong positive correlation was found between values for the accumulated doses over a threshold of 40 ppb index and the defoliation of Fraxinus excelsior trees in Lithuanian forests during 1991-2008. A strong correlation was found between ozone exposure and the proportion of healthy F. excelsior, Betula sp., and Alnus incana, trees indicating that in Lithuania the deciduous species are more sensitive to ozone than conifers and that healthier trees may be better indicators of the changing environment. The results of the studies suggest that the observed levels of ozone are sufficiently high to have negative effects on the vegetation in Lithuania.