Transport and retention of porous silicon-coated zero-valent iron in saturated porous media.

Porous silicon-coated zero-valent iron (Fe0@p-SiO2) is a promising material for in-situ contaminated groundwater remediation. However, investigations of factors that affect the transport of Fe0@p-SiO2 remain incomplete. In the present study, Fe0@p-SiO2 composites were prepared by a SiO2-coated technology, and a series of column experiments were conducted to examine the effects of media size, ionic strength, and injection velocity and concentration on retention and transport in saturated porous media. Results showed that the obtained Fe0@p-SiO2 is a core-shell composite with zero-valent iron as the core and porous silicon as the shell. Media size, injection velocity, Fe0 concentration, and ionic strength had a significant impact on the transport of Fe0@p-SiO2. Fe0@p-SiO2 effluent concentrations decreased with a smaller media size. Increasing initial particle concentration and ionic strength led to a decrease in particle transport. High particle retention was observed near the middle of the column, especially with high injection concentration. That was also observable in the condition of lower injection velocity or finer media. The results indicated that two transport behaviors during particles transport, which were "agglomeration-straining" and "detachment-re-migration". Moreover, the dominated mechanisms for Fe0@p-SiO2 transport and retention in saturated porous media are hydrodynamic dispersion and interception. Given the results, in practical engineering applications, proper injection velocity and concentration should be selected depending on the pollution status of groundwater and the geochemical environment to ensure an effective in-situ reaction zone.

Mechanisms of mass transfer enhancement by phase-transfer catalysis for permanganate oxidizing dense non-aqueous phase liquid (DNAPL) TCE.

Phase transfer catalysts (PTCs) have been shown to be effective in lowering the limitation of mass transfer between aqueous oxidant MnO4- and NAPLs in in-situ chemical oxidation (ISCO) technologies for remediation of NAPLs. This work researched the effects of pentyltriphenylphosphonium bromide (PTPP, used as the representative PTC) for the enhancement of TCE oxidation, the extent of different treatment effects contributions and generalizability of phase transfer. Experimental results revealed that MnO4- exchanged with Br- in PTPP by ion exchange mechanism and then transferred to NAPL phase due to biphasic nature of PTPP-MnO4-. PTPP enhanced TCE dissolution in aqueous phase but had no significant effect on TCE solubilization. Enhanced TCE dissolution gradually weakened after 2.0 h and disappeared after 5.5 h, while the percentage of MnO4- in phase transfer was 14.8% at 7.5 h, which indicated that dissolution acceleration was only effective at initial stage of reaction (0-2.5 h). Therefore, persistent phase transfer process played the leading role in TCE remediation enhancement. Moreover, for different NAPL phase, more effective phase transfer could be achieved in NAPLs with higher solubility and weaker hydrophobicity. The best-fit polynomial relationship (R2 = 0.992) existed between the percentage amount of MnO4- transferred and the solubility of NAPL.

Effective stabilization and distribution of emulsified nanoscale zero-valent iron by xanthan for enhanced nitrobenzene removal.

The reactivity and delivery of remediants and treatment of organic contaminants in heterogeneous aquifer are particularly challenging issues for injection-based remedial treatments. Our objective was to enhance the reactivity and delivery of nanoscale zero-valent iron (nZVI) and improve the sweeping efficiency of nZVI into low permeable zones (LPZs) to reduce nitrobenzene (NB). This was accomplished by conducting batch and transport experiments that quantified NB degradation by different modified nZVI and the ability of emulsified nZVI (EZVI) or xanthan carried EZVI (XG-EZVI) to penetrate and cover a lens. By incorporating the xanthan and emulsified oil with nZVI, it possessed higher stability and stronger reactivity to reduce NB. Results showed that the stability of EZVI was improved by xanthan, and there were no adverse effects on NB removal in use of XG-EZVI at limited xanthan addition of ≦100 mg L-1. By the injection of XG-EZVI in 2D-tank experiments, the degradation of NB was 8 times that of EZVI added, while NB adsorption on media was only 1/50 of initial NB. 1205 mg of NB totally entered into the tank, the quality of aniline in effluent was approximately 90.0 mg in addition of XG-EZVI at 40 h, but not detected in presence of EZVI. The greater NB reduction by XG-EZVI resulted from higher sweeping efficiency in LPZ. These observations support the couple use of xanthan and emulsified oil for modifying nZVI as a means of achieving greater stability and reactivity and enhancing nZVI delivery into LPZs for the treatment of NB.