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A concise asymmetric synthesis of torcetrapib.
Guinó, Meritxell; Phua, Pim Huat; Caille, Jean-Claude; Hii, King Kuok Mimi.
J Org Chem ; 72(16): 6290-3, 2007 Aug 03.
Article in English | MEDLINE | ID: mdl-17625891

ABSTRACT

Optically active torcetrapib was synthesized in seven steps from achiral precursors without the need for protecting groups, utilizing an enantioselective aza-Michael reaction to achieve asymmetry.


Subject(s)
Chemistry, Organic/methods , Quinolines/chemistry , Quinolines/chemical synthesis , Amino Acids/chemistry , Carbamates/chemistry , Catalysis , Models, Chemical , Molecular Conformation , Molecular Structure , Stereoisomerism , Time Factors
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