A 35-year monitoring of an Italian landfill: Effect of recirculation of reverse osmosis concentrate on leachate characteristics.

"Fossetto" landfill (Monsummano Terme - Tuscany, Italy) started operation in 1988 as a controlled landfill accepting mixed municipal solid waste collected without any attempt of recycling. Then, progressively, following the evolution of the state-of-the-art, it adopted biogas extraction and valorisation systems and mechanical-biological treatment for incoming waste (both since 2003). Finally, since 2006, in the plant is performed on-site reverse osmosis leachate treatment with the concentrated leachate being recirculated back into the landfill body. Recently a new landfill cell, separate from the others, was put in operation adding a capacity of 200,000 m3 to the already available 1,095,000 m3. This plant can provide long term leachate composition data to study the evolution and impact of changing landfill technology and waste composition on various parameters. The rise in leachate production (+84 % in 2018-2022 respect to the period before recirculation) cannot be totally attributable to recirculation but could be also linked to the increase in the amount of landfilled waste. The concentration of certain parameters (NH4+, Cl- and to a less extent of COD) increased (+60 %, +58 %, +17 % respectively in the last five years with respect to the period before recirculation); however, this increase did not influence the performance of the treatment plant. Nevertheless, the overall leachate management would benefit from an optimized reinjection system.

Preliminary evaluation of the anaerobic biodegradability of three biobased materials used for the production of disposable plastics.

Biodegradable plastics have been introduced to the market to substitute "traditional", non-biodegradable, petro-based plastics to alleviate plastic pollution. Biochemical methane potential tests were carried out on compostable bags made of MaterBi®, biodegradable bottle wine corks and cellulosic plates to examine the anaerobic biodegradability of those materials. The impact of four factors: type of pretreatment (predigestion, mechanical, alkaline, predigestion and alkaline), digestion duration, type of inoculum and temperature were statistically evaluated through regression modeling. Anaerobic tests on compostable and polyethylene bags (control) were carried out in mesophilic (35 °C) and thermophilic (55 °C) conditions, while tests on bottle wine corks and cellulosic plates were carried out in mesophilic conditions only. After 15 days of digestion, a dry mass reduction of 22.8 ±â€¯6.2 % and 27.6 ±â€¯14.0 % for mesophilic and thermophilic tests respectively was recorded for MaterBi®. Chemical pretreatment with NaOH led to a mass reduction of 78.2 ±â€¯7.2 % and was the only statistically significant factor to affect both methane yields and dry mass loss. A higher digestion temperature led to an increased mass loss without a concurrent increase in methane production. The cellulosic plates were completely degraded (99.9 ±â€¯0.03 % mass reduction), while the wine bottle corks weight did not change.

Valorisation of citrus processing waste: A review.

This study analyses the quantitative and qualitative characteristics of citrus peel waste and discusses the systems for its valorisation. Citrus peel waste (CPW) is the main residue of the citrus processing industries and is characterised by a seasonal production (which often requires biomass storage) as well as high water content and concentration of essential oils. The disposal of CPW has considerable constraints due to both economic and environmental factors. Currently this residue is mainly used as food for animals, thanks to its nutritional capacity. If enough agricultural land is available close to the processing industries, the use of CPW as organic soil conditioner or as substrate for compost production is also possible, thus improving the organic matter content of the soil. Recently, the possibility of its valorisation for biomethane or bioethanol production has been evaluated by several studies, but currently more research is needed to overcome the toxic effects of the essential oils on the microbial community. Considering the high added value of the compounds that can be recovered from CPW, it has promising potential uses: in the food industry (for production of pectin, dietary fibres, etc.), and in the cosmetic and pharmaceutic industries (extraction of flavonoids, flavouring agents and citric acid). However, in many cases, these uses are still not economically sustainable.

Effect of the recirculation of a reverse osmosis concentrate on leachate generation: A case study in an Italian landfill.

"Fossetto" landfill has been operating in the municipality of Monsummano Terme (Pistoia Province, Italy) since 1988; the authorized volume for landfilling is about 1,000,000 m3; at the moment the plant is being mainly used to dispose of mechanically and biologically treated residual municipal solid waste. Since September 2006, an in-situ reverse osmosis leachate treatment plant has been operating to treat leachate. The treated water is being discharged into a small nearby stream while the concentrated leachate is being recirculated back into the landfill body following Italian Regulations and an authorization from the local authority (Pistoia Province). This paper presents monitoring results on leachate generation rates and composition for the past fifteen years. A moderate increase of the concentration of some of the monitored parameters occurred (e.g. ammonium, chlorides) and a decrease for most heavy metals. The increase of concentrations for Cl- and NH4+ was more evident in the leachate coming from the wells closer to reinjection area. However, the change in leachate composition did not affect the quality of the effluent from the leachate treatment plant. The annual volume of the generated leachate increased significantly right after the recirculation started.

Strategies for the sustainable management of orange peel waste through anaerobic digestion.

The processing of oranges is a major industry worldwide and leads to the production of large amounts of orange peel waste (OPW). Energy production through anaerobic digestion of OPW is a promising option; however, the high content of essential oil, mainly composed of d-limonene, a well-known antioxidant, can cause the inhibition of the biological activity. In this paper, different pretreatment methods were tested (e.g. ensiling, aeration, thermal and alkaline treatments) to optimize the anaerobic digestion of OPW focusing on d-limonene removal. The raw and pretreated substrates were characterized and their biochemical methane production was measured. The results demonstrated the ability of some of the treatments to reduce d-limonene content up to 80%. A relatively high biomethane potential production of OPW (up to about 500 NmL CH4 g-1VS) was measured. The importance of the acclimation of inoculum and the risk connected to the accumulation of inhibiting substances in the reactor is discussed.

Effect of three pretreatment techniques on the chemical composition and on the methane yields of Opuntia ficus-indica (prickly pear) biomass.

Opuntia ficus-indica (OFI) is an emerging biomass that has the potential to be used as substrate in anaerobic digestion. The goal of this work was to investigate the effect of three pretreatment techniques (thermal, alkaline, acidic) on the chemical composition and the methane yield of OFI biomass. A composite experimental design with three factors and two to three levels was implemented, and regression modelling was employed using a total of 10 biochemical methane potential (BMP) tests. The measured methane yields ranged from 289 to 604 NmL/gVSadded; according to the results, only the acidic pretreatment (HCl) was found to significantly increase methane generation. However, as the experimental values were quite high with regards to the theoretical methane yield of the substrate, this effect still needs to be confirmed via further research. The alkaline pretreatment (NaOH) did not noticeably affect methane yields (an average reduction of 8% was recorded), despite the fact that it did significantly reduce the lignin content. Thermal pretreatment had no effect on the methane yields or the chemical composition. Scanning electron microscopy images revealed changes in the chemical structure after the addition of NaOH and HCl. Modelling of the cumulated methane production by the Gompertz modified equation was successful and aided in understanding kinetic advantages linked to some of the pretreatments. For example, the alkaline treatment (at the 20% dosage) at room temperature resulted to a µmax (maximum specific methane production rate [NmLCH4/(gVSadded·d)]) equal to 36.3 against 18.6 for the control.

Effect of the concentration of essential oil on orange peel waste biomethanization: Preliminary batch results.

The cultivation of orange (Citrus×sinensis) and its transformation is a major industry in many countries in the world, it leads to the production of about 25-30Mt of orange peel waste (OPW) per year. Until now many options have been proposed for the management of OPW but although they are technically feasible, in many cases their economic/environmental sustainability is questionable. This paper analyse at lab scale the possibility of using OPW as a substrate for anaerobic digestion. Specific objectives are testing the possible codigestion with municipal biowaste, verifying the effect on methane production of increasingly high concentration of orange essential oil (EO, that is well known to have antioxidant properties that can slower or either inhibit biomass activity) and obtaining information on the behaviour of d-limonene, the main EO component, during anaerobic digestion. The results indicate that OPW can produce up to about 370LnCH4/kgVS in mesophilic conditions and up to about 300LnCH4/kgVS in thermophilic conditions. The presence of increasingly high concentrations of EO temporary inhibits methanogenesis, but according to the results of batch tests, methane production restarts while d-limonene is partially degraded through a pathway that requires its conversion into p-cymene as the main intermediate.

Estimate of the optimum weight ratio in zero-valent iron/pumice granular mixtures used in permeable reactive barriers for the remediation of nickel contaminated groundwater.

This paper presents the results of laboratory column tests aimed at defining the optimum weight ratio of zero-valent iron (ZVI)/pumice granular mixtures to be used in permeable reactive barriers (PRBs) for the removal of nickel from contaminated groundwater. The tests were carried out feeding the columns with aqueous solutions of nickel nitrate at concentrations of 5 and 50 mg/l using three ZVI/pumice granular mixtures at various weight ratios (10/90, 30/70 and 50/50), for a total of six column tests; two additional tests were carried out using ZVI alone. The most successful compromise between reactivity (higher ZVI content) and long-term hydraulic performance (higher Pumice content) seems to be given by the ZVI/pumice granular mixture with a 30/70 weight ratio.

Impact of mechanical street cleaning and rainfall events on the quantity and heavy metals load of street sediments.

The paper presents and analyses the results of a street sediments monitoring campaign carried out during dry weather in order to quantify the impact of mechanical street cleaning and rainfall events on the quantity and heavy metals load of street sediments. The study has been carried out in an experimental catchment in a medium traffic street of a residential/commercial area in the city of Reggio Calabria (Italy). Thanks to acquired data, it was possible to assess the amount and the degree of pollution of street sediments, the efficiency of mechanical street cleaning in terms of sediments and pollutants removal, the wash-off of street sediments during rainfall events and the related potential impact on receiving water bodies. The results obtained confirm that street sweeping is generally scarcely effective as a practice for urban storm run-off quality control and that run-off is, on the contrary, quite effective in street sediments removal especially for smaller particles. Moreover, chemical analyses indicate that, although the concentration of heavy metals is higher in sediments particles having a diameter lower than 0.075 mm, the greatest part of the pollutants load is associated to larger particles.

In sewer processes: mathematical model development and sensitivity analysis.

Until now the majority of sewer networks in Italy have been built and managed considering small as well as local wastewater treatment plants (WWTPs). However, pushed by Italian and EU regulations, centralised and large WWTPs are becoming more common in Italy. One major technical aspect caused by the changing from local to centralised WWTPs is the development of significant in-sewer processes. These processes are also emphasized by the building of long interceptor sewers characterized by high hydraulic retention times and absence of tributary sewers. In this paper a model derived from the well known WATS model (Wastewater Aerobic/anaerobic Transformation in Sewers) has been set up and applied to an Italian case study located in Palermo. To assure a good degree of reliability the model needs a number of parameters that can be measured or calibrated by the combined use of field data and laboratory analyses. To support the planning of the experimental activity a sensitivity analysis to assess the influence of each model parameter has been carried out. Indeed, the sensitivity analysis allowed identifying the most significant model parameters. As a matter of the fact, by means of sensitivity analysis it was possible not only to pin down the most important model parameters but also to address the field survey towards the most sensitive model parameters in order to optimize the model application. The results are interesting and enabled to reduce the number of parameters to be calibrated from 24 to 14. More specifically, COD fractions, Y(Hw) and mu(H) showed a strong influence on the model results addressing the field campaign to an accurate evaluation of their value.