Thermodynamic evidence of giant salt deposit formation by serpentinization: an alternative mechanism to solar evaporation.

The evaporation of seawater in arid climates is currently the main accepted driving mechanism for the formation of ancient and recent salt deposits in shallow basins. However, the deposition of huge amounts of marine salts, including the formation of tens of metres of highly soluble types (tachyhydrite and bischofite) during the Aptian in the South Atlantic and during the Messinian Salinity Crisis, are inconsistent with the wet and warm palaeoclimate conditions reconstructed for these periods. Recently, a debate has been developed that opposes the classic model of evaporite deposition and argues for the generation of salt by serpentinization. The products of the latter process can be called "dehydratites". The associated geochemical processes involve the consumption of massive amounts of pure water, leading to the production of concentrated brines. Here, we investigate thermodynamic calculations that account for high salinities and the production of soluble salts and MgCl2-rich brines through sub-seafloor serpentinization processes. Our results indicate that salt and brine formation occurs during serpentinization and that the brine composition and salt assemblages are dependent on the temperature and CO2 partial pressure. Our findings help explain the presence and sustainability of highly soluble salts that appear inconsistent with reconstructed climatic conditions and demonstrate that the presence of highly soluble salts probably has implications for global tectonics and palaeoclimate reconstructions.

The non-cylindrical crustal architecture of the Pyrenees.

We exploit the data from five seismic transects deployed across the Pyrenees to characterize the deep architecture of this collisional orogen. We map the main seismic interfaces beneath each transect by depth migration of P-to-S converted phases. The migrated sections, combined with the results of recent tomographic studies and with maps of Bouguer and isostatic anomalies, provide a coherent crustal-scale picture of the belt. In the Western Pyrenees, beneath the North Pyrenean Zone, a continuous band of high density/velocity material is found at a very shallow level (~10 km) beneath the Mauleon basin and near Saint-Gaudens. In the Western Pyrenees, we also find evidence for northward continental subduction of Iberian crust, down to 50-70 km depth. In the Eastern Pyrenees, these main structural features are not observed. The boundary between these two domains is near longitude 1.3 °E, where geological field studies document a major change in the structure of the Cretaceous rift system, and possibly a shift of its polarity, suggesting that the deep orogenic architecture of the Pyrenees is largely controlled by structural inheritance.