1.
Chem Commun (Camb)
; 55(64): 9440-9443, 2019 Aug 07.
Article
in English
| MEDLINE
| ID: mdl-31328206
ABSTRACT
The molecular catalyst diacetyl-bis(N-4-methyl-3-thiosemi-carbazonato)nickel(ii) (NiATSM) was integrated with Si for light-driven hydrogen evolution from water. Compared to an equivalent loading of Ni metal, the NiATSM/p-Si electrode performed better. Durability of the surface-bound catalyst under operation in acid was achieved without covalent attachment by using Nafion binding.