Chitosan-based foam composites for hexavalent chromium remediation: Effect of microcellulose and crosslinking agent content.

Potentially toxic metal ions, such as hexavalent chromium (Cr6+), present in water concern the population's health due to their persistence, bioaccumulation potential, and high toxicity. Highly porous materials based on polysaccharides are promising technologies for metal removal due to their high surface area, biodegradability, and low toxicity. This study evaluated the effect of concentrations of microcellulose (0.5, 1, and 1.5 %) and glutaraldehyde (1, 2, and 3 %) in the adsorption capacity and mechanical properties of chitosan foams. The developed foams exhibited a three-dimensional structure with interconnected pores. Compared to foams without microcellulose, adding 1.5 % microcellulose increased up to 180 % in maximum stress supported by the foams and up to 135 % in Young's modulus. However, Cr6+ sorption capacity decreased with increasing microcellulose and crosslinking agent content due to the occupation of amino groups. Still, the foams exhibited a highly favorable sorption behavior, and the Sips isotherm model provided the best fit to the experimental data. The maximum sorption capacity reached approximately 1.4 mmol·g-1 at pH 4.0 and 25 °C. The foam structural integrity, enhanced mechanical properties, and efficient sorption capacity make them viable alternatives for environmentally friendly and cost-effective treatment of water contaminated with Cr6+ ions.

Thermoplastic starch nanocomposites using cellulose-rich Chrysopogon zizanioides nanofibers.

Green thermoplastic starch (TPS) nanocomposite films aided by cellulose nanofibers (CNFs) from Chrysopogon zizanioides roots were developed and characterized. When compared to other lignocellulosic fibers, Chrysopogon zizanioides roots revealed exceptionally high cellulose content (~48%). CNFs were separated using an environmentally friendly acid isolation technique that included three stages: (i) alkali treatment; (ii) bleaching; and (iii) mild acid hydrolysis using oxalic acid in an autoclave. Following that, green nanocomposite films were made from potato starch using the solution casting process, by which we used glycerol (30 wt%) to make thermoplastic starch. Then, cellulose nanofibers in different concentrations (0, 1, 2, 3, 4 wt%) were added to the thermoplastic starch matrix. The isolated CNFs had diameters in the range of 17-27 nm. Besides, these nanostructures presented a very high crystallinity index (~65%), thereby enhanced the thermal stability. TPS/CNF green nanocomposites containing 3 wt% CNFs had exceptional tensile strength (~161%), tensile modulus (~167%), thermal stability, and crystallinity. As a result, nanocomposite films made of starch and cellulose nanofibers (3 wt%) extracted from Chrysopogon zizanioides roots would be alternatives for sustainable packaging. It can be concluded that Chrysopogon zizanioides roots have high potential for polymer industry.

Assessing the efficiency of essential oil and active compounds/poly (lactic acid) microcapsules against common foodborne pathogens.

Essential oils' active compounds present great potential as a bactericidal agent in active packaging. The encapsulation in polymeric walls promotes their protection against external agents besides allowing controlled release. This work produced PLA capsules with three different active compounds, Cinnamomum cassia essential oil (CEO), eugenol (EEO), and linalool (LEO), by emulsion solvent evaporation method. Characterizations included SEM, Zeta potential, FTIR, TGA, and bactericidal activity against E. coli, S. aureus, L. monocytogenes, and Salmonella. The active compounds showed microbiological activity against all pathogens. CEO capsules showed superior colloidal stability. The active compounds' presence in all capsules was confirmed by FTIR analysis, with possible physical interaction between CEO, EEO, and the polymeric matrix, while LEO had a possible chemical interaction with PLA. TGA analysis showed a plasticizing effect of active compounds, and the loading efficiency was 39.7%, 50.7%, and 22.3% for CEO-PLA, EEO-PLA, and LEO-PLA, respectively. The capsules presented two release stages, sustaining activity against pathogens for up to 28 days, indicating a satisfactory internal morphology. This study presented methodology for encapsulation of antimicrobial compounds that can be suitable for active food packaging. CEO-PLA capsules regarding stability and antibacterial activity achieved the best results.