The formation of impact coesite.

Coesite in impact rocks is traditionally considered a retrograde product formed during pressure release by the crystallisation of an amorphous phase (either silica melt or diaplectic glass). Recently, the detailed microscopic and crystallographic study of impact ejecta from Kamil crater and the Australasian tektite strewn field pointed in turn to a different coesite formation pathway, through subsolidus quartz-to-coesite transformation. We report here further evidence documenting the formation of coesite directly from quartz. In Kamil ejecta we found sub-micrometric single-coesite-crystals that represent the first crystallization seeds of coesite. Coesite in Australasian samples show instead well-developed subeuhedral crystals, growing at the expenses of hosting quartz and postdating PDF deformation. Coesite (010) plane is most often parallel to quartz {10-11} plane family, supporting the formation of coesite through a topotactic transformation. Such reaction is facilitated by the presence of pre-existing and shock-induced discontinuities in the target. Shock wave reverberations can provide pressure and time conditions for coesite nucleation and growth. Because discontinuities occur in both porous and non-porous rocks and the coesite formation mechanism appears similar for small and large impacts, we infer that the proposed subsolidus transformation model is valid for all types of quartz-bearing target rocks.

Boom boom pow: Shock-facilitated aqueous alteration and evidence for two shock events in the Martian nakhlite meteorites.

Nakhlite meteorites are ~1.4 to 1.3 Ga old igneous rocks, aqueously altered on Mars ~630 Ma ago. We test the theory that water-rock interaction was impact driven. Electron backscatter diffraction demonstrates that the meteorites Miller Range 03346 and Lafayette were heterogeneously deformed, leading to localized regions of brecciation, plastic deformation, and mechanical twinning of augite. Numerical modeling shows that the pattern of deformation is consistent with shock-generated compressive and tensile stresses. Mesostasis within shocked areas was aqueously altered to phyllosilicates, carbonates, and oxides, suggesting a genetic link between the two processes. We propose that an impact ~630 Ma ago simultaneously deformed the nakhlite parent rocks and generated liquid water by melting of permafrost. Ensuing water-rock interaction focused on shocked mesostasis with a high density of reactive sites. The nakhlite source location must have two spatially correlated craters, one ~630 Ma old and another, ejecting the meteorites, ~11 Ma ago.

A unique CO-like micrometeorite hosting an exotic Al-Cu-Fe-bearing assemblage - close affinities with the Khatyrka meteorite.

We report the discovery of a unique micrometeorite, containing an exotic Al-Cu-Fe alloy composed of two intermixed phases: khatyrkite (CuAl2) and stolperite (CuAl) and both containing minor Fe (<1.4 wt%). These phases are dendritic and rapidly co-crystallized at the binary system's peritectic (~550 °C). The host micrometeorite is an otherwise typical S-type micro-porphyritic cosmic spherule containing relict olivine (Fo76-90, Cr2O3: 0.01-0.56 wt%, MnO: 0.03-0.32 wt% and CaO: 0.09-0.22 wt%) and a cumulate layered texture. These properties suggest the micrometeorite is derived from a carbonaceous chondrite (best matched to a CO chondrite) and entered the atmosphere a high speed (~16 kms-1), implying an origin from a highly eccentric orbit. This particle represents the second independent discovery of naturally occurring intermetallic Al-Cu-Fe alloys and is thus similar to the previously reported Khatyrka meteorite - a CV chondrite containing near-identical alloys and the only known natural quasicrystals. We did not observe quasicrystalline phases in this micrometeorite, likely due to the low amounts of Fe in the alloy, insufficient to stabilize quasicrystals. Our discovery confirms the existence of Al-Cu-Fe intermetallic alloys on chondritic parent bodies. These unusual phases require a currently unexplained formation process, we tentatively suggest this could represent the delivery of exotic interstellar material to the inner solar system via impact.

Epidemiological and clinical features of HEV infection: a survey in the district of Foggia (Apulia, Southern Italy).

In this study we assessed the seroprevalence of hepatitis E virus (HEV) infection in both the Italian population and immigrants from developing countries in Foggia (Apulia, Southern Italy). The seroprevalence of HEV was determined in 1217 subjects [412 (34%) immigrants and 805 Italian subjects (blood donors, general population, HIV-positive, haemodialysis patients)]. Serum samples were tested for anti-HEV and confirmed by Western blot assay; in positive patients HEV RNA and genotype were also determined. There were 8·8% of patients that were positive to anti-HEV, confirmed by Western blot. The prevalence in immigrants was 19·7%, and in Italians 3·9% (blood donors 1·3%, general population 2·7%, HIV-positive patients 2·0%, haemodialysis patients 9·6%). Anti-HEV IgM was found in 38/107 (35·5%) of the anti-HEV-positive serum samples (34 immigrants, four Italians). This study indicates a higher circulation of HEV in immigrants and Italian haemodialysis patients, whereas a low prevalence of HEV antibodies was seen in the remaining Italian population.