A novel chitosan and polyferric sulfate composite coagulant for biogas slurry pretreatment by simultaneous flocculation and floatation: Performance and underlying mechanisms.

Biogas slurry from anaerobic digestion is rich in nutrients but has not been fully utilized due to a high content of suspended solids (SS) causing clogging during agricultural irrigation. This study aimed to evaluate the performance of a novel chitosan and polyferric sulfate (CTS-PFS) composite coagulant for simultaneous flocculation and floatation to enhance SS removal while preserving nutrients in biogas slurry. Orthogonal method was used for experimental design to determine the optimal synthesis and operational conditions of CTS-PFS. Results show that CTS-PFS outperformed individual CTS and PFS coagulant in terms of SS removal and nutrient (nitrogen, phosphorus, and potassium) preservation. Compared to individual CTS and PFS coagulation, the combination of CTS and PFS at the mass ratio of 1:6 showed significantly higher performance by 41.5 % increase in SS removal and 5.2 % reduction in nutrient loss. The improved performance of CTS-PFS was attributed to its formation of polynuclear hydroxyl complexes with ferric oxide groups (e.g. Fe-OH, Fe-O-Fe, Fe-OH-Fe and COO-Fe) to strengthen charge neutralization and adsorption bridging. Data from this study further confirm that CTS-PFS enhanced the removal of small suspended particles and dissolved organic matter in the molecular weight range of 0.4-2.0 kDa and preserved ammonia and potassium better in biogas slurry. Bubbles were generated as hydrogen ions from coagulant hydrolysis interacted with bicarbonate and carbonate in biogas slurry for removing the produced flocs by floatation. Floc flotation was more effective in CTS-PFS coagulation due to the significant production of uniform bubbles, evidenced by the reduction in the viscosity of biogas slurry.

Occurrence and transformation of heavy metals during swine waste treatment: A full scale study.

This study tracked the fate of nine detected heavy metals in an industrial swine farm with integrated waste treatment, including anoxic stabilization, fixed-film anaerobic digestion, anoxic-oxic (A/O), and composting. Results show that heavy metals exhibited different transformation behaviors in the treatment streamline with Fe, Zn, Cu and Mn as the most abundant ones in raw swine waste. The overall removal of water-soluble heavy metals averaged at 30 %, 24 % and 42 % by anoxic stabilization, anaerobic digestion and A/O unit, respectively. In particular, anoxic stabilization could effectively remove Cu, Mn and Ni; while A/O unit was highly effective for Fe, Cr and Zn elimination from water-soluble states. As such, the environmental risk of liquid products for agricultural irrigation decreased gradually to the safe pollution level in swine waste treatment. Furthermore, heavy metals in the solid (slurry) phase of these bioprocesses could be immobilized with the passivation rate in the range of 42-70 %. Nevertheless, heavy metals preferably transformed from liquid to biosolids to remain their environmental risks when biosolids were used as organic fertilizer in agriculture, thereby requiring effective strategies to advance their passivation in all bioprocesses, particularly composting as the last treatment unit.