ABSTRACT
Constructing stable and efficient photocatalysts for H2O2 production is of great importance and is challenging. In this study, the synthesis of three photoactive cyclooctatetrathiophene (COTh)-based porous aromatic frameworks (COTh-PAFs) in an alternating donor-acceptor (D-A) fashion is presented. In combination with a triazine-derived electron acceptor, PAF-363 exhibits high efficiency for the photosynthesis of H2O2 with production rates of 11733â µmol g-1 h-1(with sacrificial agent) and 3930â µmol g-1 h-1 (without sacrificial agent) from water and oxygen under visible light irradiation. Experimental results and theoretical calculations reveal that the charge transfer positions and the O2 adsorption sites in PAF-363 are both concentrated on COTh fragments, which facilitate the H2O2 production through the oxygen reduction reaction (ORR) pathway. This work highlights that the rational design of COTh-PAFs with consideration of D-A direction, charge transfer positions, and O2 adsorption sites provides a feasible access to efficient H2O2 production photocatalysts.
ABSTRACT
Atom economy is one of the main concerns for material synthesis. Here, the facile synthesis of Lewis acidic boron-containing porous organic polymers (B-POPs) via hydroboration polymerization reaction of commercially available borane dimethyl sulfide complex (BH3 âSMe2 ) with multi-alkynes under mild reaction conditions is presented. This new synthetic method for B-POPs has the advantage of high atom economy. The resulted porous alkenyl borane polymers (PABPs) have unique features such as high boron content, strong Lewis acidity, and high surface areas. Owing to the strong Lewis acid-base interactions, PABPs exhibit excellent adsorptive capacity toward triethylamine (up to 841 mg g-1 ) and pyridine (up to 1396 mg g-1 ) vapor.
