Investigation of non-precious metal cathode catalysts for direct borohydride fuel cells.

Borohydride crossover in anion exchange membrane (AEM) based direct borohydride fuel cells (DBFCs) impairs their performance and induces cathode catalyst poisoning. This study evaluates three non-precious metal catalysts, namely LaMn0.5Co0.5O3 (LMCO) perovskite, MnCo2O4 (MCS) spinel, and Fe-N-C, for their application as cathode catalysts in DBFCs. The rotating disk electrode (RDE) testing shows significant borohydride tolerance of MCS. Moreover, MCS has exhibited exceptional stability in accelerated durability tests (ADTs), with a minimal reduction of 10 mV in half-wave potential. DFT calculations further reveal that these catalysts predominantly adsorb over , unlike commercial Pt/C which preferentially adsorbs . In DBFCs, MCS can deliver a peak power density of 1.5 W cm-2, and a 3% voltage loss after a 5 hours durability test. In contrast, LMCO and Fe-N-C have exhibited significantly lower peak power density and stability. The analysis of the TEM, XRD, and XPS results before and after the single-cell stability tests suggests that the diminished stability of LMCO and Fe-N-C catalysts is due to catalyst detachment from carbon supports, resulting from the nanoparticle aggregation during the high-temperature preparation process. Such findings suggest that MCS can effectively mitigate the fuel crossover challenge inherent in DBFCs, thus enhancing its viability for practical application.

Design and verification of a backward wave oscillation suppression circuit for the Ka-band gyrotron travelling-wave tube.

Backward wave oscillation seriously degrades the stability of gyrotron travelling-wave tubes (gyro-TWTs), especially during high average/continuous wave operation. To solve this problem, a selective mode suppression structure (SMSS) based on the mode coupling principle is proposed and applied in the nonlinear beam-wave interaction region to suppress the parasitic TE11 mode. It is capable of obtaining a high power and improving the tube stability. Simulation results demonstrate that the SMSS can raise the starting current from 10 to 18 A and the starting pitch factor from 1.2 to 1.6. Based on this proposed circuit, a Ka-band TE01 mode gyro-TWT was designed, and the particle-in-cell simulation shows that it can achieve a saturated output power of over 150 kW from 29.7 to 31.7 GHz with a velocity spread of 2.2%. For verification, a SMSS is manufactured and cold tested. The measurement of S-parameters reveals that it can effectively suppress the parasitic TE11 mode.