ABSTRACT
A common approach to assess the nature of energy conversion in a classical fluid or plasma is to compare power densities of the various possible energy conversion mechanisms. A leading research area is quantifying energy conversion for systems that are not in local thermodynamic equilibrium (LTE), as is common in a number of fluid and plasma systems. Here we introduce the "higher-order nonequilibrium term" (HORNET) effective power density, which quantifies the rate of change of departure of a phase space density from LTE. It has dimensions of power density, which allows for quantitative comparisons with standard power densities. We employ particle-in-cell simulations to calculate HORNET during two processes, magnetic reconnection and decaying kinetic turbulence in collisionless magnetized plasmas, that inherently produce non-LTE effects. We investigate the spatial variation of HORNET and the time evolution of its spatial average. By comparing HORNET with power densities describing changes to the internal energy (pressure dilatation, Pi-D, and divergence of the vector heat flux density), we find that HORNET can be a significant fraction of these other measures (8% and 35% for electrons and ions, respectively, for reconnection; up to 67% for both electrons and ions for turbulence), meaning evolution of the system towards or away from LTE can be dynamically important. Applications to numerous plasma phenomena are discussed.
ABSTRACT
Anisotropic electron heating during electron-only magnetic reconnection with a large guide magnetic field is directly measured in a laboratory plasma through in situ measurements of electron velocity distribution functions. Electron heating preferentially parallel to the magnetic field is localized to one separatrix, and anisotropies of 1.5 are measured. The mechanism for electron energization is identified as the parallel reconnection electric field because of the anisotropic nature of the heating and spatial localization. These characteristics are reproduced in a 2D particle-in-cell simulation and are also consistent with numerous magnetosheath observations. A measured increase in the perpendicular temperature along both separatrices is not reproduced by our 2D simulations. This work has implications for energy partition studies in magnetosheath and laboratory reconnection.
ABSTRACT
Weakly collisional and collisionless plasmas are typically far from local thermodynamic equilibrium (LTE), and understanding energy conversion in such systems is a forefront research problem. The standard approach is to investigate changes in internal (thermal) energy and density, but this omits energy conversion that changes any higher-order moments of the phase space density. In this Letter, we calculate from first principles the energy conversion associated with all higher moments of the phase space density for systems not in LTE. Particle-in-cell simulations of collisionless magnetic reconnection reveal that energy conversion associated with higher-order moments can be locally significant. The results may be useful in numerous plasma settings, such as reconnection, turbulence, shocks, and wave-particle interactions in heliospheric, planetary, and astrophysical plasmas.
ABSTRACT
Non-Maxwellian electron velocity distribution functions composed of a warm bulk population and a cold beam are directly measured during electron-only reconnection with a strong out-of-plane (guide) magnetic field in a laboratory plasma. Electron heating is localized to the separatrix, and the electron temperature increases continuously along the separatrix. The measured gain in enthalpy flux is 70% of the incoming Poynting flux. The electron beams are oppositely directed on either side of the X point, and their velocities are comparable to, and scale with, the electron Alfvén speed. Particle-in-cell simulations are consistent with the measurements. The experimental results are consistent with, and go beyond, recent observations in the magnetosheath.
ABSTRACT
Gas-phase structural parameters for ferrocenecarboxaldehyde have been determined using Fourier transform microwave spectroscopy. Rotational transitions due to a-, b-, and c-type dipole moments were measured. Eighteen rotational constants were determined by fitting the measured transitions of various isotopomers using a rigid rotor Hamiltonian with centrifugal distortion constants. Least-squares fit and Kraitchman analyses have been used to determine the gas-phase structural parameters and the atomic coordinates of the molecule using the rotational constants for various isotopomers. Structural parameters determined from the least-squares fit are the Fe-C bond lengths to the cyclopentadienyl rings, r(Fe-C)=2.047(4) A, and the distance between the carbon atoms of the cyclopentadienyl rings, r(C-C)=1.430(2) A and r(C1-C1')=1.46(1) A of ring carbon and aldehyde carbon atom. Structural parameters were also obtained using density-functional theory calculations, and these were quite helpful in resolving ambiguities in the structural fit analysis, and providing some fixed parameters for the structural analysis. The results of the least squares and the calculations indicate that the carbon atoms of the Cp groups for ferrocenecarboxaldehyde are in an eclipsed conformation in the ground vibrational state.
ABSTRACT
Rotational spectra for two isotopomers of chloroferrocene were measured using pulsed-beam Fourier transform microwave spectroscopy. Transitions were observed for (35)Cl and (37)Cl isotopomers in the 4-10 GHz range. Chlorine quadrupole coupling strengths and rotational constants were obtained from the data. The rotational constants and quadrupole coupling strengths for (35)Cl are A = 1370.009(8) MHz, B = 767.342(1) MHz, C = 634.8834(6) MHz, eQq(aa)() = -9.06(4) MHz, and eQq(bb)() = -28.43(6) MHz and for (37)Cl are A = 1362.23(2) MHz, B = 751.623(2) MHz, C = 622.324(1) MHz, eQq(aa)() = -8.78(18) MHz, and eQq(bb)() = -20.76(9) MHz. These measured rotational constants were used to determine the following structural parameters of chloroferrocene: r(Fe-(C(5)H(5))) = 1.594(20) Å, r(Fe-(C(5)H(4)Cl)) = 1.699(13) Å, r(C-Cl) =1.7204(9) Å, and r(C-C) = 1.4329(7) Å. No evidence for internal rotation was observed in the microwave spectrum.
